Impacts of both temperature and condensation on the band gap of photonic crystals around the freezing point

Abstract This work investigated the phenomena and cause of photonic band gap (PBG) shift under an open environment at −10 °C ∼ 20 °C for the three-dimensional (3D) photonic crystals (PCs). The 3D PCs were composed of polystyrene spheres using the self-assembly method. The reflective gloss of 3D PC sample underwent non-monotonous color change within the temperature region. PBG of PCs first red-shifted during the cooling from room temperature. Later, the PBG blue-shifted when the temperature decreased from about 0 °C. The average transmittance through the PC sample within the visible range also increased first and then decreased with ambient temperature reduction. Influences from structure dimension, optical constants of involved materials, condensation and its phase change on PBG were all quantitatively investigated.