X-ray induced luminescence properties of (Y,Eu)AlO3 single crystals

Abstract We investigated photoluminescence, scintillation and dosimeter properties of (Y 1- x Eu x )AlO 3 ( x = 0.001, 0.5 and 1) single crystals (hereafter denoted as Eu:YAP for x = 0.001, EYAP for x = 0.5 and EAP for x = 1). The samples were prepared by the Floating Zone method. In photoluminescence (PL), we observed a broad emission around 300–400 nm due to host under excitation of 280 nm, and emissions due to the 4f state transitions of Eu 3+ appeared around 590 nm and 615 nm. Scintillation spectra also show emission peaks around 590 and 615 nm due to the 4f state transitions of Eu 3+ in all the samples. In addition, emissions around 300–400 nm due to YAP host and around 550–700 nm due to 5d-4f transitions of Eu 2+ appeared in Eu:YAP. The PL and scintillation decay time profiles consisted of several exponential decay components. The fast (ns) component group was possibly due to host emission, and especially Eu:YAP demonstrated a very fast PL decay time of 16 ns. The intermediate (μs) component group was due to the 5d-4f transitions of Eu 2+ . The slow (ms) component group was ascribed to the 4f state transitions of Eu 3+ ion. The Eu:YAP sample showed intense thermally-stimulated luminescence (TSL) with peaks at 46, 155, 255 and 443 °C. The intensity was much higher than those of EAP and EYAP. In particular, the peak at 254 °C, which showed the highest intensity, was due to doping with Eu. The TSL dose response function showed a good linearity (R 2 > 0.99) over a wide dose range from 0.1 mGy to 100 mGy for Eu:YAP, which showed the highest sensitivity among the present samples.