journal article·2023-11Open access

Enhancing efficiency and decelerating degradation in bulk heterojunction solar cells with N,N-Dimethylformamide cosolvent for poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)

Fernando Rodríguez-Mas, Susana Fernández de Ávila, Juan Carlos Ferrer, José Luis Alonso, David Valiente

Optical Materials· Volume 145

Abstract

Focused on the improvement of hole transport layer of organic solar cells based on poly(3-hexylthiophene) (P3HT)/6,6-phenil C61-butyric acid methyl ester (PCBM) blend, we studied the possibility of extending the lifetime of these devices. Thus, influence of N,N-dimethylformamide (DMF) added to poly(3,4-ethylenedioxythiofene):poly(styrenesulfonate) (PEDOT:PSS) hole transport layer was analyzed. We report that DMF causes an increase in the power conversion efficiency (PCE) of organic solar cells. A likely reason for this improvement might be a reduced intermolecular distance between the poly(3,4-ethylenedioxythiofene): (PEDOT) and poly(styrenesulfonate) (PSS) chains. The optimal volume of DMF in PEDOT:PSS was studied: two parts of DMF to one part of PEDOT:PSS increases PCE by 47%. Furthermore, PEDOT:PSS layer with DMF generated a reduction in the degradation of PCE, extending the lifetime of bulk heterojunction solar cells.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Organic solar cells10.1002/adma.19910030303 ↗
2. Single-junction organic solar cells with over 19% efficiency enabled by a refined double-fibril network morphology10.1038/s41563-022-01244-y ↗
3. Solution-processed metal-oxide based hole transport layers for organic and perovskite solar cell: a review
4. Concurrently improved jsc, Fill factor, and stability in a ternary organic solar cell enabled by a C-shaped non-fullerene acceptor and its structurally similar third component10.1021/acsami.1c13035 ↗
5. Study of a new composite based on SnO2 nanoparticles — P3HT:PC71BM co-polymer blend, used as potential absorber in bulk heterojunction photovoltaic cells
6. Ag nanoparticle-based efficiency enhancement in an inverted organic solar cell10.1051/epjap/2020200112 ↗
7. Examination of band bending at buckminsterfullerene (C60)/metal interfaces by the Kelvin probe method10.1063/1.1504495 ↗
8. Morphology, conductivity, and wetting characteristics of PEDOT:PSS thin films deposited by spin and spray coating10.1016/j.apsusc.2015.02.128 ↗
9. Advanced development of sustainable PECVD semitransparent photovoltaics: a review10.3389/fmats.2021.762030 ↗
10. Polymer photovoltaic cells: enhanced efficiencies via a network of internal donor-acceptor heterojunctions10.1126/science.270.5243.1789 ↗
11. Conductivity, morphology, interfacial chemistry, and stability of poly(3,4-ethylene dioxythiophene)–poly(styrene sulfonate): a photoelectron spectroscopy study10.1002/polb.10659 ↗
12. New architecture for high-efficiency polymer photovoltaic cells using solution-based titanium oxide as an optical SpacerAdv
13. High-efficiency solution processable polymer photovoltaic cells by self-organization of polymer blends10.1038/nmat1500 ↗
14. Reappraising the need for bulk heterojunctions in Polymer−Fullerene photovoltaics: the role of carrier transport in all-solution-processed P3HT/PCBM bilayer solar cells10.1021/jp9050897 ↗
15. Effects of postproduction treatment on plastic solar cells
16. Immiscible solvents enabled nanostructure formation for efficient polymer photovoltaic cells10.1088/0957-4484/25/29/295401 ↗
17. Enhanced efficiency of bilayer polymer solar cells by the solvent treatment method10.1016/j.synthmet.2014.12.013 ↗
18. Roughening conjugated polymer surface for enhancing the charge collection efficiency of sequentially deposited polymer/fullerene photovoltaics10.3390/polym7081466 ↗
19. Controlling hierarchy in solution-processed polymer solar cells based on crosslinked P3HT10.1002/aenm.201200394 ↗
20. A strong regioregularity effect in self-organizing conjugated polymer films and high-efficiency polythiophene:fullerene solar cells10.1038/nmat1574 ↗
21. A poly-(3-hexylthiophene) (P3ht)/[6,6]-phenyl-C61-butyric acid methyl ester (PCBM) bilayer organic solar cell fabricated by airbrush spray deposition10.1088/0256-307X/29/7/078801 ↗
22. Flexible efficient top-emitting organic light-emitting devices on a silk substrate10.1109/JPHOT.2017.2740618 ↗
23. Laminated aluminum thin-films as low-cost opaque moisture ultra-barriers for flexible organic electronic devices10.1016/j.orgel.2017.04.022 ↗
24. Enhancement of electrical conductivity of poly(3,4-ethylenedioxythiophene)/poly(4-styrenesulfonate) by a change of solvents10.1016/S0379-6779(01)00576-8 ↗
25. PEDOT:PSS films with significantly enhanced conductivities induced by preferential solvation with cosolvents and their application in polymer photovoltaic cellsJ10.1039/c0jm04177g ↗
26. High-conductivity poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) film for use in ITO-free polymer solar cells10.1039/b813079e ↗
27. Polymer-Fullerene bulk-heterojunction solar cells10.1002/adma.200801283 ↗
28. Highly efficient and stable inverted polymer solar cells integrated with a cross-linked fullerene material as an interlayer10.1021/ja100236b ↗
29. Dual, microscopical investigations of PEDOT:PSS thin films10.1002/adfm.200801258 ↗
30. Significant conductivity enhancement of conductive poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) films by adding anionic surfactants into polymer solution10.1021/ma8012459 ↗
31. High yield synthesis of Ni-BTC metal–organic framework with ultrasonic irradiation: role of polar aprotic DMF solvent10.1016/j.ultsonch.2015.12.007 ↗
32. Quiroz · 2011
33. Effects of ZnO nanoparticles on P3HT:PCBM organic solar cells with DMF-modulated PEDOT:PSS buffer layers10.1021/am4046475 ↗
34. Degradation of organic solar cells due to air exposure10.1016/j.solmat.2006.06.041 ↗
35. Macroscopic modeling of water uptake behavior of PEDOT:PSS films10.1021/acsomega.9b02866 ↗