journal article·2020-09

Near infrared scintillation based on core/dual-shell fluoride nanocrystals

Jiangcong Zhou, Xinling Liu, Yiqing Lai, Yu Chen, Congcong Qiu, Lei Lei

Optical Materials· Volume 107
Publisher page

Abstract

Abstract Up to now, most of the emisison wavelengths of the reported scintillators are located in ultra-violet (UV) or visible range. Herein, to further expand the X-ray excited fluorescence emission spectrum, an active core/dual-shell nanocrystal (NC) architecture is used to actualize near-infrared scintillation. Specifically, under the X-ray excitation, near-infrared emission from Nd3+ ions at ~1064 and Yb3+ ions at 980 nm are achieved. The active outer shell with the incorporation of Ce3+ sensitizer ions benefited the enhancement of X-ray excited NIR fluorescence emission intensity owing to the enhanced energy transfer efficiency from Ce3+ to Nd3+ or Yb3+ emission centers. The present studied near-infrared NC scintillator have deeper penetration depth than that of UV and visible, which might be useful for X-ray imaging with improved sensitivity.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Atomic and Subatomic Physics Research · Radiation Detection and Scintillator Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Photosynergetic amplification of radiation input: from efficient UV induced cycloreversion to sensitive X-ray detection10.1039/C9SC05380H ↗
2. 2D hybrid perovskite ferroelectric enables highly sensitive X-Ray detection with low driving voltage
3. Exploring lead-free hybrid double perovskite crystals of (BA)2CsAgBiBr7 with large mobility-lifetime product toward X-ray detection10.1002/anie.201909815 ↗
4. Hot-pressed CsPbBr3 quasi-monocrystalline film for sensitive direct X-ray detection10.1002/adma.201904405 ↗
5. High-sensitivity X-ray imaging of a lead halide perovskite single-crystal scintillator10.1364/OL.45.000355 ↗
6. X-ray imaging of functional three-dimensional nanostructures on massive substrates10.1021/acsnano.9b05519 ↗
7. Inorganic scintillators: today and tomorrow10.1016/S0022-2313(02)00423-4 ↗
8. Rodnyi · 1997 · vol. 14
9. Scintillation properties of YAP:Ce10.1016/0168-9002(95)00016-X ↗
10. X-ray imaging with scintillator-sensitized hybrid organic photodetectors10.1038/nphoton.2015.216 ↗
11. Flexible, printable soft-X-ray detectors based on all-inorganic perovskite quantum dots
12. All-inorganic perovskite nanocrystal scintillators10.1038/s41586-018-0451-1 ↗
13. Advances in highly doped upconversion nanoparticles10.1038/s41467-018-04813-5 ↗
14. Inverse thermal quenching effect in lanthanide-doped upconversion nanocrystals for anti-counterfeiting10.1039/C8TC01433G ↗
15. Lanthanide-doped upconversion nano-bioprobes: electronic structures, optical properties, and biodetection10.1039/C4CS00178H ↗
16. A strategy to achieve effi cient dual-mode luminescence of Eu3+ in lanthanides doped multifunctional NaGdF4 nanocrystals10.1002/adma.201000128 ↗
17. Manipulating energy transfer in lanthanide-doped single nanoparticle for highly enhanced upconverting luminescence10.1039/C7SC01393K ↗
18. Controlling upconversion nanocrystals for emerging applications10.1038/nnano.2015.251 ↗
19. Highly bright multicolor tunable ultrasmall β-Na(Y,Gd)F4:Ce,Tb,Eu/β-NaYF4 core/shell nanocrystals10.1039/c3nr02591h ↗
20. Broadband Ce(III)-sensitized quantum cutting in core-shell nanoparticles: mechanistic investigation and photovoltaic application10.1021/acs.jpclett.7b02245 ↗
21. Energy migration upconversion in Ce(III)-doped heterogeneous core-shell-shell nanoparticles10.1002/smll.201701479 ↗
22. Modulation of surface energy transfer cascade for reversible photoluminescence pH sensing10.1021/acs.chemmater.9b02857 ↗
23. Mechanical properties and machinability of GYGAG: Ce ceramic scintillators10.1016/j.ceramint.2019.10.183 ↗
24. Electronic band modification for faster and brighter Ce, Mg: Lu3-xYxAl5O12 ceramic scintillators10.1016/j.jlumin.2019.116545 ↗
25. Scintillation properties of YAlO3 doped with Lu and Nd perovskite single crystals10.1016/j.optmat.2018.04.013 ↗
26. Optical and scintillation properties of Nd-doped complex garnet10.1016/j.optmat.2014.10.020 ↗
27. Yanagida · Opt. Mater. · 2014 · 36 · 104410.1016/j.optmat.2014.01.022 ↗
28. Optical and scintillation properties of Nd-doped SrAl2O4 crystals10.1016/S1002-0721(16)60090-X ↗
29. Enhancing negative thermal quenching effect via low-valence doping in two-dimensional confined core–shell upconversion nanocrystals10.1039/C8TC04392B ↗
30. Simultaneous phase and size control of upconversion nanocrystals through lanthanide doping10.1038/nature08777 ↗
31. The active-core/active-shell approach: a strategy to enhance the upconversion luminescence in lanthanide-doped nanoparticles10.1002/adfm.200900234 ↗
32. Confining excitation energy in Er3+-sensitized upconversion nanocrystals through Tm3+-mediated transient energy trapping10.1002/anie.201703012 ↗
33. Sub-10 nm lanthanide-doped CaF2 nanoprobes for time-resolved luminescent biodetection10.1002/anie.201302481 ↗
34. Intense near-infrared-II luminescence from NaCeF4: Er/Yb nanoprobes for in vitro bioassay and in vivo bioimaging10.1039/C8SC00927A ↗
35. Broadband Ce (III)-sensitized quantum cutting in core–shell nanoparticles: mechanistic investigation and photovoltaic application10.1021/acs.jpclett.7b02245 ↗