journal article·2016-02

Phase equilibria diagrams, crystal growth peculiarities and Raman investigations of lead and sodium-bismuth tungstate–molybdate solid solutions

Andrei V. Lebedev, Samvel A. Avanesov, Tyliay M. Yunalan, Valeriy A. Klimenko, Boris V. Ignatyev, Vladislav A. Isaev

Optical Materials· Volume 52
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Abstract

Abstract In this paper a comprehensive study of lead and sodium-bismuth tungstate–molybdate solid solutions was carried out, including the clarification of their structural peculiarities and phase diagrams of PbMoO 4 –PbWO 4 and NaBi(MoO 4 ) 2 –NaBi(WO 4 ) 2 systems, the study of spontaneous Raman spectra of these compounds, as well as preliminary experiments on single crystals growth of lead tungstate–molybdate. The linewidths, peak and integral intensities of the totally symmetric Raman vibrations of solid solutions were estimated in comparison with known SRS-active crystals. The conditions of the Czochralski growth of optically transparent lead tungstate–molybdate mixed crystals were found and SRS effect was observed in these crystals when pumping by 12 ns 1064 nm laser pulses.
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Research context

OpenAlex topics: Solid State Laser Technologies · Luminescence Properties of Advanced Materials · Optical and Acousto-Optic Technologies

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