journal article·2025-12-12

Bacterial Cellulose Nanopapers for Document Restoration

Cristian López Rey, Oriana D’ Alessandro, Celina R. Bernal, Ana Morales, María Laura Foresti

ACS Applied Nano Materials· Volume 8· Issue 49
Publisher page

Abstract

The conservation of heritage documents and books requires the use of appropriate materials that ensure effective and durable restoration. In this study, innovative transparent and mechanically robust nanopapers were developed using bacterial nanocellulose (BNC) combined with various commercial cellulose ethers. The developed nanopapers were thoroughly characterized in terms of morphology, porosity, optical properties, barrier performance, mechanical properties, and accelerated aging behavior. The results showed that the incorporation of cellulose ethers significantly enhanced the transparency, barrier properties, and mechanical performance of the nanopapers. Moreover, accelerated aging tests demonstrated excellent chromatic stability. The nanopapers developed were used in the restoration of 18th and 19th century documents, demonstrating their potential as innovative conservation materials. BNC/cellulose ether nanopapers emerge as promising alternatives to conventional restoration papers, offering also superior performance compared to pure BNC nanopapers.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Advanced Cellulose Research Studies · Cultural Heritage Materials Analysis · Building materials and conservation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Universidad de Buenos Aires. Facultad de Ingeniería

CONICET–Universidad de Buenos Aires. Instituto de Tecnología en Polímeros y Nanotecnología (ITPN)

CIDEPINT (CICPBA-CONICET-UNLP). La Plata

Universidad Nacional de La Plata. Facultad de Ciencias Exactas

Departamento de Química. La Plata

Museo Histórico Nacional

Centro Tarea- Centro de Estudios Sobre Patrimonios y Ambiente. Escuela de Arte y Patrimonio (TAREA-CEPyA-EAyP-UNSAM). San Martín

Funding

Consejo Nacional de Investigaciones Cient?ficas y T?cnicas · Universidad de Buenos Aires

References (70)

Show source-provided references
1. 10.1016/j.carpta.2024.10057310.1016/j.carpta.2024.100573 ↗
2. 10.1557/PROC-185-79910.1557/PROC-185-799 ↗
3. 10.1080/19455224.2021.201731410.1080/19455224.2021.2017314 ↗
4. 10.3390/molecules2916395910.3390/molecules29163959 ↗
5. 10.1016/j.ijbiomac.2023.12825410.1016/j.ijbiomac.2023.128254 ↗
6. 10.1021/acsami.3c1905010.1021/acsami.3c19050 ↗
7. 10.1016/j.jcis.2020.05.01810.1016/j.jcis.2020.05.018 ↗
8. 10.1007/s10570-021-03989-210.1007/s10570-021-03989-2 ↗
9. 10.1038/s41598-025-05812-510.1038/s41598-025-05812-5 ↗
10. 10.1016/B978-0-12-813351-4.00005-510.1016/B978-0-12-813351-4.00005-5 ↗
11. 10.1021/bm800038n10.1021/bm800038n ↗
12. 10.1021/bm100490s10.1021/bm100490s ↗
13. 10.1007/s10570-018-2044-410.1007/s10570-018-2044-4 ↗
14. Dreyfuss-Deseigne R. · Book Pap. Group Annu. · 2017 · 36 · 108
15. 10.3390/app12241284610.3390/app122412846 ↗
16. 10.3390/polym1609122710.3390/polym16091227 ↗
17. 10.1016/j.carbpol.2014.03.06410.1016/j.carbpol.2014.03.064 ↗
18. 10.1007/s10853-015-9476-010.1007/s10853-015-9476-0 ↗
19. 10.1007/s10853-015-9477-z10.1007/s10853-015-9477-z ↗
20. 10.1080/18680860.2021.193367710.1080/18680860.2021.1933677 ↗
21. 10.1515/res-2022-003110.1515/res-2022-0031 ↗
22. 10.1016/j.carpta.2021.10005010.1016/j.carpta.2021.100050 ↗
23. 10.1186/s40494-017-0134-510.1186/s40494-017-0134-5 ↗
24. 10.1016/j.culher.2019.02.00610.1016/j.culher.2019.02.006 ↗
25. 10.1016/j.culher.2016.10.00710.1016/j.culher.2016.10.007 ↗
26. 10.52292/j.laar.2024.283710.52292/j.laar.2024.2837 ↗
27. TAPPI/ANSI T 402 sp-21. Standard conditioning and testing atmospheres for paper, board, pulp handsheets, and related products , 2021.
28. ISO 187:2022. Paper, board, and pulps ─ standard atmosphere for conditioning and testing and procedure for monitoring the atmosphere and conditioning of samples , 2022.
29. TAPPI/ANSI T 410 om-23. grammage of paper and paperboard (weight per unit area) , 2023.
30. 10.1023/A:101370380996410.1023/A:1013703809964 ↗
31. 10.1021/acsami.5b0830810.1021/acsami.5b08308 ↗
32. ISO 5636/5. Paper and Board ─ Determination of air permeance (medium range) ─ Part 5: gurley method , 2013.
33. ISO 14782:2021. Plastics ─ determination of haze for transparent materials , 2021.
34. ASTM E96/E96M-22. Standard test methods for gravimetric determination of water vapor transmission rate of materials , 2022.
35. TAPPI/ANSI T 494 om-06. Tensile properties of paper and paperboard (using constant rate of elongation apparatus) . 2006.
36. TAPPI/ANSI T 529 om-04. Surface pH measurement of paper . 2004.
37. 10.1016/j.carbpol.2022.11985610.1016/j.carbpol.2022.119856 ↗
38. 10.1002/adma.20200121510.1002/adma.202001215 ↗
39. 10.1016/j.compositesa.2020.10577910.1016/j.compositesa.2020.105779 ↗
40. 10.1007/s10570-013-0045-x10.1007/s10570-013-0045-x ↗
41. 10.1016/j.carbpol.2023.12091510.1016/j.carbpol.2023.120915 ↗
42. 10.15376/frc.2009.2.89910.15376/frc.2009.2.899 ↗
43. 10.15376/biores.15.1.1014-102510.15376/biores.15.1.1014-1025 ↗
44. 10.1016/0021-8502(88)90219-410.1016/0021-8502(88)90219-4 ↗
45. De Meis, D. Gas Transport Through Porous Membranes , 2017.10.13140/RG.2.2.25450.7264110.13140/RG.2.2.25450.72641 ↗
46. 10.1016/j.indcrop.2012.08.03010.1016/j.indcrop.2012.08.030 ↗
47. 10.1007/s10570-007-9136-x10.1007/s10570-007-9136-x ↗
48. 10.1021/bm201147a10.1021/bm201147a ↗
49. 10.15376/biores.6.4.5307-533710.15376/biores.6.4.5307-5337 ↗
50. Williams R. S. · Book Pap. Group Annu. · 2018 · 37 · 96
51. Dufresne A. · 201210.1515/9783110254600 ↗
52. 10.1039/C2EE23635D10.1039/C2EE23635D ↗
53. 10.1515/hfsg.1992.46.5.40310.1515/hfsg.1992.46.5.403 ↗
54. 10.1088/0957-0233/19/5/05571010.1088/0957-0233/19/5/055710 ↗
55. 10.1021/acssuschemeng.8b0081410.1021/acssuschemeng.8b00814 ↗
56. 10.3390/polym1503047910.3390/polym15030479 ↗
57. 10.1007/s10570-021-04343-210.1007/s10570-021-04343-2 ↗
58. Feller R. L. · 1990
59. Hoover J. E. · 1976
60. 10.1002/0471440264.pst04410.1002/0471440264.pst044 ↗
61. Rowe R. C. · 2009
62. 10.1186/s40494-022-00779-210.1186/s40494-022-00779-2 ↗
63. 10.1515/npprj-2021-003610.1515/npprj-2021-0036 ↗
64. 10.1007/s10570-010-9474-y10.1007/s10570-010-9474-y ↗
65. 10.13031/2013.1330010.13031/2013.13300 ↗
66. 10.3390/cosmetics903005210.3390/cosmetics9030052 ↗
67. Tacón Clavaín J. · 2009
68. 10.1007/s10570-014-0341-010.1007/s10570-014-0341-0 ↗
69. 10.1021/bm200890710.1021/bm2008907 ↗
70. 10.1021/acsanm.2c0296810.1021/acsanm.2c02968 ↗