journal article·2016-12

Luminescence behaviors and infrared-to-visible energy conversion in Er3+/Yb3+ -doped CaZr4O9 phosphors

M.S. Pathak, M. Seshadri, N. Singh, Vijay Singh, Jung-Kul Lee

Optical Materials· Volume 62
Publisher page

Abstract

Abstract Phosphor powders of CaZr4O9:Er3+ and CaZr4O9:Er3+,Yb3+ were prepared by the urea combustion route. The crystal structure was characterized by powder XRD measurement. The optical properties were studied using absorption and photoluminescence (PL) spectroscopy. Upon excitation at 978 nm, the upconversion (UC) luminescence properties of Er3+ and Er3+,Yb3+ co-doped CaZr4O9 phosphors were analyzed. Energy transfer mechanism was discussed to understand the UC luminescence process for the Er3+ and Er3+,Yb3+ co-doped CaZr4O9 phosphors. From the pump power dependent green and red luminescence intensity analysis, required number of photons to populate the excited emitting levels are estimated and observed that the green emission intensity exhibits faster increase rates than red emission as a function of pump power. Upon excitation at 978 nm, the UC mechanism was discussed in terms of the experimental results.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Radiation Detection and Scintillator Technologies · Luminescence and Fluorescent Materials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (41)

Show source-provided references
1. Protonic conduction in Rh-doped AZrO3 (A=Ba, Sr and Ca)10.1016/S0167-2738(02)00400-9 ↗
2. A wet-chemical method for the synthesis of In-doped CaZrO3 Ceramic Powders10.1016/S0955-2219(99)00045-X ↗
3. Anomalous penetration of implanted deuterium in proton conductive perovskite oxides10.1016/S0167-2738(97)00483-9 ↗
4. Solubility limits and microwave dielectric properties of Ca (ZrxTi1−x)O3 solid solution10.1016/j.jallcom.2012.08.076 ↗
5. The effect of natural dolomite admixtures on calcium zirconate–periclase materials microstructure evolution10.1016/j.ceramint.2009.09.025 ↗
6. Synthesis and luminescence study of BaZrO3:Eu3+ phosphor10.1016/j.spmi.2015.09.016 ↗
7. Dielectric characteristics and sintering behavior of Mg2TiO4–(Ca0.8Sr0.2)TiO3 ceramic system at microwave frequency10.1016/j.jallcom.2009.07.144 ↗
8. Synthesis and photoluminescence properties of Eu3+-doped AZrO3 (A = Ca, Sr, Ba) perovskite10.1016/j.jallcom.2007.04.259 ↗
9. Synthesis and luminescence properties of the red phosphor CaZrO3:Eu3+ for white light-emitting diode application
10. Synthesis of red phosphor CaZrO3:Eu3+ for white light-emitting diodes
11. Long afterglow in Pr3+ and Li+ co-doped CaZrO310.1016/j.optcom.2005.03.011 ↗
12. Up-conversion luminescence of Er3+/Yb3+ co-doped LiYF4 nanocrystals in sol–gel derived oxyfluoride glass-ceramics10.1016/j.jnoncrysol.2015.07.010 ↗
13. Bidirectional energy transfer induced single-band red upconversion emission of Ho3+ in KZnF3:Mn2+,Yb3+,Ho3+ nanocrystals10.1016/j.jallcom.2016.01.132 ↗
14. Tunable upconversion luminescence from the phosphors of Yb3+, Tm3+ and Ho3+ tri-doped Re2TeO6 (Re = La, Gd, and Lu)10.1016/j.jallcom.2016.02.157 ↗
15. Influence of Nd3+ concentration on up-conversion fluorescence colour in YVO4 co-doped with Ho3+, Yb3+ and Nd3+ ions10.1016/j.matlet.2012.08.026 ↗
16. Upconversion and color tenability in Tm3+/Ho3+/Yb3+ doped low phonon energy bismuth tellurite glasses10.1016/j.jlumin.2010.01.022 ↗
17. Up-conversion emission in triply-doped Ho3+/Yb3+/Tm3+ KGd(WO4)2 single crystals10.1016/j.optcom.2011.01.060 ↗
18. Upconversion nanophosphors for small-animal imaging10.1039/C1CS15187H ↗
19. Synthesis of UV/NIR photocatalysts by coating TiO2 shell on peanut-like YF3:Yb,Tm upconversion nanocrystals10.1016/j.matlet.2013.05.047 ↗
20. A Three-color, three-dimensional, solid-state display10.1002/adma.19970090121 ↗
21. Sensing using rare-earth-doped upconversion nano-particles10.7150/thno.5305 ↗
22. Probing a highly efficient dual mode: down – upconversion luminescence and temperature sensing performance of rare-earth oxide phosphors10.1039/C2DT32054A ↗
23. Optical characterization, absorption and upconversion luminescence in Er3+and Er3+/Yb3+doped In2O3 phosphor10.1016/j.jlumin.2016.04.006 ↗
24. Efficient oxide phosphors for light upconversion; green emission from Yb3+ and Ho3+ co-doped Ln2BaZnO5 (Ln = Y, Gd)10.1039/C0JM01652G ↗
25. Synthesis and upconversion luminescence of hexagonal-phase NaYF4: Yb, Er3+ phosphor of controlled size and morphology10.1002/adma.200402046 ↗
26. Power driven tunable white upconversion luminescence from Lu2TeO6 tri-doped with Yb3+, Tm3+ and Ho3+10.1039/C5CE01734C ↗
27. NIR to visible upconversion in Er3+/Yb3+ co-doped CaYAl3O7 phosphor obtained by solution combustion process10.1016/j.jlumin.2011.06.055 ↗
28. Visible upconversion in Er3+/Yb3+ co-doped LaAlO3 phosphors10.1016/j.saa.2016.08.001 ↗
29. Crystal structures of the fluorite-related phases CaHf4O9 and Ca6Hf19O4410.1016/0022-4596(75)90031-6 ↗
30. Stability of phases CaZrO3 and CaZr4O9 incorporated in the system CaO-ZrO210.1016/0022-4596(89)90269-7 ↗
31. Structural and spectroscopic behavior of Er3+:Yb3+ co-doped lithium telluroborate glasses10.1016/j.physb.2014.09.043 ↗
32. NIR to visible frequency upconversion in Er3+ and Yb3+ co-doped BaZrO3 phosphor10.1016/j.saa.2013.01.073 ↗
33. Spectroscopic characterizations of Er doped LaPO4 submicron phosphors prepared by homogeneous precipitation method10.1016/j.optmat.2016.01.015 ↗
34. Investigation of thermal stability and spectroscopic properties in Er3+/Yb3+-codoped TeO2–Li2O–B2O3–GeO2 glasses10.1016/j.saa.2004.07.026 ↗
35. Preparation and photoluminescence properties of SrY2O4:Yb3+, Er3+ powders10.1016/j.jallcom.2008.06.158 ↗
36. Upconversion fluorescence spectroscopy of Er3+/Yb3+-codoped lead oxyfluorosilicate glass10.1016/j.cplett.2003.12.104 ↗
37. Frequency upconversion in Er3+/Yb3+-codoped chalcogenide glass10.1063/1.120884 ↗
38. Luminescent characters of Er3+/Yb3+ co-doped ZrO2–Al2O3 phosphors10.1016/j.jlumin.2015.07.034 ↗
39. Anomalous power dependence of sensitized upconversion luminescence10.1103/PhysRevB.71.125123 ↗
40. Auzel · 1980 · 213
41. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems10.1103/PhysRevB.61.3337 ↗