journal article·2020-11

The effects of solution pH on structural, optical and electrical properties of KTiOPO4(KTP) nanoparticles synthesized by hydrothermal method

E. Gharibshahian, M. Jafar Tafreshi, M. Behzad

Optical Materials· Volume 109
Publisher page

Abstract

Abstract KTiOPO4 nanoparticles were synthesized by the hydrothermal method. The effects of solution pH on size, its distribution, structural, optical, dielectric, and morphological properties of products were investigated. The obtained nanoparticles were characterized by XRD, FT-IR, FE-SEM, TEM, UV–Vis analyses, and LCR measurement. The pH of the solution varied from 3.5 to 7.00. Only solution pH equal to 4.5 and 5.5 resulted in pure KTP nanoparticles. Smallest and biggest grain sizes were found to be 27.72 nm and 92.4 nm, respectively. Obtained KTP nanoparticles at pH = 5.5 showed the dielectric constant (1.68 × 104) with 3.36 times higher than that value for KTP single crystal (0.5 × 104). The best structural quality and the best optical properties were observed in this solution pH. Solution pH variation resulted in crystal lattice rotation of obtained KTP nanoparticles.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Ferroelectric and Piezoelectric Materials · Microwave Dielectric Ceramics Synthesis

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (32)

Show source-provided references
1. Electric properties of KTiOPO4 and NaTiOPO4 from temperature-dependent X-ray diffraction10.1107/S002188989800497X ↗
2. Fabrication and characterization of optical waveguides in KTiOPO410.1063/1.97913 ↗
3. KTiOPO4 single nanocrystal for second-harmonic generation microscopy
4. Synthesis and characterization of KTiOPO4 nanocrystals and their PMMA nanocomposites
5. Review on gray track effects on potassium titanyl phosphate single crystals
6. Single KTP nanocrystals as second-harmonic generation biolabels in cortical neurons10.1039/c3nr01251d ↗
7. Photostable second-harmonic generation from a single KTiOPO4 nanocrystal for nonlinear microscopy10.1002/smll.200701093 ↗
8. Preparation and performances of KTiOPO4 membranes10.1016/S0376-7388(96)00258-X ↗
9. Micro-Raman scattering of KTP (KTiOPO4) nanocrystallites synthesized by modified sol–gel Pechini method
10. Sol-gel synthesis of potassium titanyl phosphate: Solution chemistry and gelation10.1007/BF02439398 ↗
11. Synthesis and sintering of KTiOPO4 via mechanochemical mixing route10.1016/0925-8388(94)90113-9 ↗
12. LaPO4 and KTiOPO4 by flash combustion10.1016/0925-8388(93)90532-R ↗
13. Synthesis of nanocrystalline KTiOPO4 powder by method10.1111/j.1551-2916.2007.01591.x ↗
14. Effects of solution concentration and capping agents on properties of potassium titanyl phosphate nano particles synthesized using a co-precipitation method10.1016/j.jpcs.2018.01.015 ↗
15. Synthesis and characterization of one-dimensional CdSe by a novel reverse micelle assisted hydrothermal method10.1016/j.jcis.2008.01.048 ↗
16. Synthesis of ZnO nanoparticles by hydrothermal method
17. Optical and morphological properties of ZnO and TiO2 derived nanostructures synthesized via a microwave-assisted hydrothermal method10.1155/2012/189069 ↗
18. Solvothermal synthesis of perovskites and pyrochlores: Crystallization of functional oxides under mild conditions10.1039/b904702f ↗
19. Growth and optical properties of bulk KTP crystals by hydrothermal method
20. Bulk single crystal growth from hydrothermal solutions
21. Growth of KTP crystals with high damage threshold by hydrothermal method10.1016/j.jcrysgro.2006.04.036 ↗
22. Synthesis of KTiOPO4 nanoparticles by hydrothermal and coprecipitation methods and studies on their properties
23. Effect of particle morphology and contacts on particle breakage in a granular assembly studied using X-ray tomography
24. Estimation of lattice strain in ZnO nanoparticles: X-Ray peak profile analysis10.1007/s40094-014-0141-9 ↗
25. Restriction of particle size and lattice strain through X-ray diffraction peak broadening analysis of ZnO nanoparticles
26. Structural reasons for the nonlinear optical properties of KTP family single crystals
27. A cost-effective Co-precipitation method for synthesizing indium tin oxide nanoparticles without chlorine contamination10.1016/S1005-0302(10)60171-5 ↗
28. Raman and FTIR spectroscopic studies of potassium titanyl phosphate (KTiOPO4) doped with lanthanum and praseodymium
29. Kannan · 2002
30. Solvothermal synthesis and controlled self-assembly of monodisperse titanium-based perovskite colloidal nanocrystals10.1039/C5NR00737B ↗
31. Submicron Nano porous polyacrylamide beads with tunable size for verapamil imprinting10.1002/app.35426 ↗
32. Electro - optic and dielectric properties of KTiOPO410.1063/1.97483 ↗