journal article·2015-09

Temperature dependent infrared absorption, crystal-field and intensity analysis of Ce3+ doped LiYF4

Jon-Paul R. Wells, Sebastian P. Horvath, Michael F. Reid

Optical Materials· Volume 47
Publisher page

Abstract

Abstract Infrared absorption has been used to determine the crystal-field levels of the 2 F 7/2 excited multiplet of trivalent cerium doped into scheelite structure LiYF 4 single crystals. A crystal-field analysis well accounts for a total of six experimentally observed energy levels and the ground state g -values as previously determined by electron paramagnetic resonance, whilst intensity simulations confirm the experimentally assigned level symmetries. Temperature dependent spectral line broadening measurements highlight the importance of coupling to low frequency phonon modes of the YF 8 tetrahedron.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Inorganic Fluorides and Related Compounds · Glass properties and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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