Synthesis and spectral properties of new tetrakis-2,3-{5,7-bis[(E)-2-(4-methylphenyl)vinyl]pyrazino}porphyrazine metal complexes
Source abstract
Abstract
Abstract The new styryl substituted pyrazinoporphyrazine complex has been synthesised for the first time. The spectral properties of the ytterbium complex have been studied. The introduction of the styryl fragments in the cycle leads to bathochromatic shift of the Q-band. It can be explained by the stabilisation of LUMO.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Porphyrin and Phthalocyanine Chemistry · Magnetism in coordination complexes · Lanthanide and Transition Metal Complexes
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (10)
Show source-provided references
1. McKeown · 1998
2. Angeloni · J. Porphyr. Phthalocyan. · 2001 · 5 · 88110.1002/jpp.558 ↗
3. Shirai · Dyes Pigments · 2000 · 47 · 10710.1016/S0143-7208(00)00068-1 ↗
4. Tomachinskaya · Theor. Exp. Chem. · 2007 · 43 · 12510.1007/s11237-007-0018-y ↗
5. Godlewska · Struct. Chem. · 2010 · 21 · 46110.1007/s11224-009-9571-4 ↗
6. Gerasymchuk · J. Photochem. Photobiol. A: Chem. · 2010 · 214 · 12810.1016/j.jphotochem.2010.06.016 ↗
7. Kobayashi · J. Am. Chem. Soc. · 2001 · 123 · 1074010.1021/ja0113753 ↗
8. Ogunsipe · J. Mol. Struct. · 2003 · 650 · 13110.1016/S0022-2860(03)00155-8 ↗
9. Kasuga · Chem. Lett. · 2002 · 35210.1246/cl.2002.352 ↗
10. Donzello · J. Porphyr. Phthalocyan. · 2010 · 14 · 79310.1142/S1088424610002677 ↗