Cyclometalated iridium(III) complexes with acyl-pyrazolone ligands – towards tunable versatile building blocks and AIE emitters with external chelating fragments
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OpenAlex topics: Organic Light-Emitting Diodes Research · Magnetism in coordination complexes · Lanthanide and Transition Metal Complexes
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References (75)
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1. Phosphorescent organic light-emitting devices: iridium based emitter materials – an overview10.1016/j.ccr.2023.215100 ↗
2. Iridium(III) complexes for OLED application
3. Progress on benzimidazole-based iridium(III) complexes for application in phosphorescent OLEDs10.1016/j.orgel.2016.11.039 ↗
4. Asymmetric Tris -Heteroleptic cyclometalated phosphorescent Iridium(III) complexes: an emerging class of metallophosphors10.1021/accountsmr.2c00078 ↗
5. Engineering emissive excited states in organic electroluminescent materials10.1016/j.matt.2025.102142 ↗
6. Lifetime oxygen sensors based on block copolymer micelles and non-covalent human serum albumin adducts bearing phosphorescent near-infrared iridium(III) complex10.1016/j.eurpolymj.2021.110761 ↗
7. Phosphorescent Iridium(III) complexes with acyclic diaminocarbene ligands as chemosensors for Mercury10.1021/acs.inorgchem.9b02833 ↗
8. Luminescent chemosensors by using cyclometalated iridium(iii) complexes and their applications10.1039/C6SC04175B ↗
9. Phosphorogenic Iridium(III) bis ‐tetrazine complexes for bioorthogonal peptide stapling, bioimaging, photocytotoxic applications, and the construction of nanosized hydrogels10.1002/anie.202116078 ↗
10. Dual emissive Ir(III) complexes for photodynamic therapy and bioimaging10.3390/pharmaceutics13091382 ↗
11. Recent advances in the design of targeted Iridium(III) photosensitizers for photodynamic therapy10.1002/cbic.201800182 ↗
12. Photocatalytic aerobic dehydrogenation of N-Heterocycles with Ir(III) photosensitizers bearing the 2(2′-Pyridyl)benzimidazole scaffold10.1021/acs.inorgchem.2c00358 ↗
13. High triplet energy Iridium(III) Isocyanoborato Complex for photochemical upconversion, photoredox and energy transfer catalysis10.1021/jacs.1c11667 ↗
14. Hybrid cyclometalated iridium coumarin complex as a sensitiser of both n‐ and p‐type DSSCs10.1002/ejic.201600242 ↗
15. Bis-Cyclometalated Iridium complexes containing 4,4′-Bis(phosphonomethyl)-2,2′-bipyridine ligands: photophysics, electrochemistry, and high-voltage dye-sensitized solar cells10.1021/acs.inorgchem.0c00456 ↗
16. Iridium(III) 2‐Phenylbenzimidazole complexes: synthesis, structure, optical properties, and applications in dye‐sensitized solar cells10.1002/ejic.201501068 ↗
17. Tailoring the π-system of benzimidazole ligands towards stable light-harvesting cyclometalated iridium(III) complexes10.1039/D3DT00200D ↗
18. Ultrafast excited-state dynamics in cyclometalated Ir(III) complexes coordinated with perylenebisimide and its π-Radical anion ligands10.1021/acs.jpcc.7b06714 ↗
19. Conjugated, rigidified bibenzimidazole ancillary ligands for enhanced photoluminescence quantum yields of orange/red-emitting iridium(iii) complexes10.1039/C9DT00423H ↗
20. Rigid phenanthro[4,5-abc]phenazine-cored iridium(III) complexes for high-performance near-infrared emission at about 800 nm in solution-processed OLEDs10.1016/j.cej.2022.138956 ↗
21. 852 nm near-infrared emission from iridium (III) complex based on an enlarging rigid coordinated core of tribenzo[a,c]phenazine10.1016/j.dyepig.2022.110733 ↗
22. Highly efficient red-emitting bis-cyclometalated iridium complexes10.1021/jacs.8b04841 ↗
23. Blue-emitting Ir(iii) phosphors with 2-pyridyl triazolate chromophores and fabrication of sky blue- and white-emitting OLEDs10.1039/c3tc00919j ↗
24. External quantum efficiency exceeding 24% with CIE y value of 0.08 using a novel carbene‐based iridium complex in deep‐blue phosphorescent organic light‐emitting diodes10.1002/adma.202002120 ↗
25. Red absorbing cyclometalated Ir(III) diimine photosensitizers competent for hydrogen photocatalysis10.1021/acs.inorgchem.1c03727 ↗
26. Construction of robust Iridium(III) complex-based photosensitizer for boosting hydrogen evolution10.1021/acs.inorgchem.2c04471 ↗
27. Green light promoted Iridium(III)/Copper(I)‐Catalyzed addition of alkynes to aziridinoquinoxalines through the intermediacy of azomethine ylides10.1002/anie.202318876 ↗
28. Iridium(III) sensitisers and energy upconversion: the influence of ligand structure upon TTA‐UC performance10.1002/chem.202004146 ↗
29. Tuning excited State character in Iridium(III) photosensitizers and its influence on TTA-UC10.1021/acs.inorgchem.4c01003 ↗
30. Cyclometallated Iridium complexes as sensitizers for dye-sensitized solar cells10.1002/asia.200900429 ↗
31. Organometallic ir(iii) complexes: post-synthetic modification, photophysical properties and binuclear complex construction10.1039/D3DT00901G ↗
32. Color‐Tunable luminescence of eu‐doped LaF 3 particles sensitized by d–f energy transfer from a Two‐Photon absorbing Ir(III) complex10.1002/adom.202302954 ↗
33. Heterobimetallic iridium III –europium III complex: the role of donor energy on sensitising the Eu III ion10.1039/D3NJ03161F ↗
34. Energy‐Transfer mechanisms in Ir III –Eu III bimetallic complexes10.1002/cplu.201300107 ↗
35. Synthesis and photophysical properties of IrIII-LnIII (ln = Nd, Yb, Er) bimetallic complexes containing bipyrimidines as bridging ligands10.1007/s11426-009-0269-7 ↗
36. Near-infrared (NIR) emitting Nd/Yb(iii) complexes sensitized by MLCT states of ru(ii)/Ir(iii) metalloligands in the visible light region10.1039/C5DT00545K ↗
37. Sensitized Near-Infrared Emission from Ir III -Ln III (ln = Nd, Yb, Er) Bimetallic Complexes with a (N ∧ O)(N ∧ O) Bridging Ligand10.1021/om401110k ↗
38. Design and synthesis of a luminescent cyclometalated Iridium(III) complex having N , N -Diethylamino Group that stains acidic intracellular organelles and induces cell death by photoirradiation10.1021/ic301310q ↗
39. Highly selective detection of H + and OH – with a single-emissive Iridium(III) complex: a mild approach to conversion of Non-AIEE to AIEE complex10.1021/acs.organomet.5b00447 ↗
40. pH-Responsive N∧C-Cyclometalated Iridium(III) complexes: synthesis, photophysical properties, computational results, and bioimaging application10.3390/molecules27010232 ↗
41. Organoplatinum complex exhibiting aggregation-enhanced emission (AEE) and dual-channel ion-sensing properties by terminating the Molecular Configuration Transformation (MCT) and excited-state intramolecular proton transfer (ESIPT)10.1021/acs.inorgchem.4c01357 ↗
42. Dual‐emissive Iridium(III) complexes as phosphorescent probes with orthogonal responses to analyte binding and oxygen quenching10.1002/anie.202309178 ↗
43. Iridium-lanthanide complexes: structures, properties and applications10.1016/j.ccr.2021.214367 ↗
44. Rare Earth Acylpyrazolonates‐Synthesis, structure, luminescent properties and applications
45. Recent advances in acylpyrazolone metal complexes and their potential applications10.1016/j.ccr.2015.05.003 ↗
46. Acylpyrazolone ligands: synthesis, structures, metal coordination chemistry and applications10.1016/j.ccr.2005.03.013 ↗
47. The synthesis of 1-Phenyl-3-methyl-4-acyl-pyrazolones-510.3891/acta.chem.scand.13-1668 ↗
48. Novel composite plastics containing Silver(I) Acylpyrazolonato additives display potent antimicrobial activity by contact10.1002/chem.201404812 ↗
49. Synthesis, crystal structures and luminescent properties of the copper(I) pyrazolonate complexes10.1016/j.ica.2014.10.014 ↗
50. Self-Assembly of a two-dimensional coordination polymer based on silver and lanthanide Tetrakis-Acylpyrazolonates: an efficient new strategy for suppressing ligand-to-metal charge transfer quenching of Europium luminescence10.3390/polym15040867 ↗
51. Synthesis, structure, protolytic properties, alkylating and cytotoxic activity of novel Platinum(II) and Palladium(II) complexes with pyrazole‐derived ligands10.1002/ejic.200700139 ↗
52. Cingolani · Inorg. Chem. · 2004 · 43 · 438710.1021/ic0497376 ↗
53. Polyaryl ether dendrimer with a 4-Phenylacetyl-5-pyrazolone-based Terbium(III) complex as core: synthesis and photopysical properties10.1021/ic052148v ↗
54. Efficient green OLEDs achieved by a terbium(III) complex with photoluminescent quantum yield close to 100%10.1007/s11426-021-1036-0 ↗
55. Room-temperature fluorescence, phosphorescence and crystal structures of 4-acyl pyrazolone lanthanide complexes: Ln(L)3·2H2O10.1016/S0277-5387(96)00382-8 ↗
56. Tuning the triplet energy levels of pyrazolone ligands to match the5 D0 level of Europium(III)10.1021/ic050844p ↗
57. Synthesis and photoluminescence properties of novel lanthanide complexes based on pyrazolone schiff bases10.1016/j.synthmet.2012.04.035 ↗
58. The influence of triplet energy levels of bridging ligands on energy transfer processes in Ir(iii)/Eu(iii) dyads10.1039/c1dt10968e ↗
59. A cyclometalated iridium(iii) complex with enhanced phosphorescence emission in the solid state (EPESS): synthesis, characterization and its application in bioimaging10.1039/c0dt01366h ↗
60. Design and synthesis of heteroleptic Iridium(III) phosphors for efficient organic light-emitting devices10.1021/acs.inorgchem.7b02872 ↗
61. Efficient and exclusively NIR-emitting (λem = 780 nm) [Ir(C∧N)2(O∧O)]-heteroleptic complexes with β-diketonate- or pyrazolonate-typed O∧O-chelate ancillary10.1016/j.jlumin.2019.116983 ↗
62. Oxochlorin frameworks confining a β-hydroxyketone moiety10.1039/D4DT01386G ↗
63. Variable nuclearity in lanthanoid coordination chemistry10.1002/ejic.201402115 ↗
64. Hydrogen atom behaviour imaged in a short intramolecular hydrogen bond using the combined approach of X-ray and neutron diffraction10.1039/b908915b ↗
65. Kiseleva
66. Enriching calixarene functionality with 1,3-diketone groups10.1039/D3QO00759F ↗
67. Tuning the emission of cationic iridium (III) complexes towards the red through methoxy substitution of the cyclometalating ligand10.1038/srep12325 ↗
68. Rational design of efficient photosensitizers based on cyclometalated iridium(iii) complexes with 2-arylbenzimidazole and aromatic 1,3-diketone ligands
69. Inkable CF3-functionalized benzothiazole/benzimidazole-Ir(III) complexes for efficient bilayer-inkjet-printed OLEDs10.1016/j.jorganchem.2021.122157 ↗
70. Archetypal Iridium(III) compounds for optoelectronic and photonic applications: photophysical properties and synthetic methods
71. Deep NIR-I emissive Iridium(III) complex bearing D-A ligand: synthesis, photophysical properties and DFT/TDDFT calculation10.3390/cryst11091038 ↗
72. Efficient near-infrared luminescence from bis-cyclometalated iridium(iii) complexes with rigid quinoline-derived ancillary ligands10.1039/D0CC02745F ↗
73. Lessons learned in tuning the optoelectronic properties of phosphorescent iridium(III) complexes10.1039/C6CC06729H ↗
74. Bis-Heteroleptic cationic Iridium(III) complexes featuring cyclometalating 2-Phenylbenzimidazole ligands: a combined experimental and theoretical Study10.1021/acs.inorgchem.1c02968 ↗
75. Tuning the emission maxima of iridium systems using benzimidazole-based cyclometallating framework10.1016/j.molliq.2021.118446 ↗