journal article·2024-01Open access

Equal proportion of donor/acceptor active layer for reduced dark current in visible organic photodiode

Suraya Annissa Roslan, Amirul Ashraf Md Sabri, Nur Adilah Roslan, Tahani M. Bawazeer, Mohammad S. Alsoufi, Fakhra Aziz, Azzuliani Supangat

Optical Materials· Volume 147

Abstract

The present study investigates a visible organic photodiode with low dark current of 0.002 mA/cm2. The active layer is a bulk heterojunction (BHJ) binary blended film composed of PolyN-9′-heptadecanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole) (PCDTBT) as a donor material along with (6,6)-Phenyl C71 butyric acid methyl ester (PC71BM) as an acceptor material. The device was fabricated using a facile spin coating technique with the structure of ITO/PEDOT:PSS/PCDTBT:PC71BM/Al. The composition of PCDTBT and PC71BM has significantly improved the absorption of the UV–visible spectrum, especially between 300 and 650 nm. The optimized device of the blended film (1:1 blend ratio) showed a good photoresponsivity of 114 mA/W, with a fast response-recovery time of 733 ms and 597 ms, respectively. It is found that the specific detectivity obtained is 1.79×109 Jones and external quantum efficiency (EQE) is 29.13 %. The results manifested the optimized device can be employed in the fabrication of a cost-effective and highly sensitive visible organic photodiode.
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Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Organic Light-Emitting Diodes Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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