Impact of the nature of oxide host matrices on the thermometric luminescence properties of Nd3+- Yb3+ codoped nanocrystals
Source abstract
Abstract
International audience ; This work illustrates how the relative thermal sensitivity is impacted by properties of oxide host matrices codoped by lanthanide ions from non-classic Boltzmann thermometers. This study showed that nanothermometers constituted of inorganic matrices with lower phonon energy such as Y2O3 and Y3Al5O12 present better thermometric performance compared to those matrices with higher phonon energy such as YBO3 and Y3BO6. In addition, we explored the influence of lattice symmetry and chemical environment around the dopant ions Nd3+ and Yb3+ in photoluminescent spectra and took into account the Stark effect of luminescent emission in nanothermometry studies of nanocrystals. Thus, we showed that the choice of appropriate host matrices aligned with codoping by proper Ln3+ ions can be a strategy to enhance the thermal response of nanothermometers and design thermal probes with higher relative thermal sensitivity.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Optical properties and cooling technologies in crystalline materials · Glass properties and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
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