journal article·2024-03

Up conversion luminescence in Er and Tm activated NaYF4 microparticles

Thi Kieu Van Le, Ba Tong Nguyen, Thi My Dung Cao, Thai Ngoc Uyen Nguyen, Giacomo Zanetti, Stefano Varas, Alessandro Chiasera, Thi Ngoc Lam Tran, T.T. Van Tran

Optical Materials· Volume 149
Publisher page

Abstract

A luminescence material with pure red emission under an excitation of 980 nm is suitable for bio-applications due to the high penetration depth in biological tissue and no cell damage. In this work, β-NaYF4:15Er,xTm (x = 0, 0.5, 1, 2) Up-conversion Micro-Particles were synthesized at 180 °C in 24 h using a hydrothermal method. The structural and morphological studies reveal pure hexagonal crystals and a branch structure with a size of several hundred nanometers. Most interestingly, depending on Tm doping concentrations UCMP exhibits an intense red emission with R/G ratio from 30 to 46. The emission mechanism of NaYF4:Er,Tm UCMP under 980 nm excitation was also suggested. The co-doping of Tm3+ ions into β-NaYF4:Er3+ leads to a decrease of green emission (Er3+:2H11/2/4S3/2 → 4I15/2) and enhances the red emission (Er3+:4F9/2 → 4I15/2). Besides, the UCMP modified with polyacrylic acid (PAA) shows a zeta potential as high as −56.6 mV. These findings demonstrate that the β-NaYF4:Er,Tm@PAA UCMP with high signal-to-background ratio are promising candidates for bio-applications.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Inorganic Fluorides and Related Compounds · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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