journal article·2019-09

Effect of thermal annealing and aging time on optical properties of alpha-sexithiophene thin films

H. Abd El-Khalek, Mohamed Abd- El Salam, Fatma M. Amin

Optical Materials· Volume 95
Publisher page

Abstract

Abstract This research work is dedicated to studying the optical properties of nanocrystalline alpha-sexithiophene (α-6T) thin films under the influence of thermal annealing. Alpha-sexithiophene thin films were deposited using thermal evaporation technique. The thermal treatment showed a significant influence on the structural, morphological and optical properties of α-6T thin films. The thermal annealing process induced an improvement in the crystallinity of the fabricated α-6T films as observed in X-ray diffraction patterns and Scanning electron microscopy. Moreover, the optical properties of films were studied using spectrophotometric data of transmittance and reflectance. The estimated values of indirect energy gap were 2.00 eV and 1.96 eV at 298 KK and 423 KK, respectively. The nonlinear optical susceptibility χ (3) was calculated at different temperatures. Finally, aging effect on the optical properties is discussed. The results show that the indirect band gap does not change with the aging time, this reflects the stability of α-6T prepared films.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Nonlinear Optical Materials Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (51)

Show source-provided references
1. Review on recent advances in polythiophene based photovoltaic devices10.1016/j.rser.2015.12.177 ↗
2. Growth of competing crystal phases of α-sexithiophene studied by real-time in situ X-ray scattering
3. Structural order in conjugated oligothiophenes and its implications on opto-electronic devices10.1039/a908312j ↗
4. Optoelectronic properties of hyperbranched polythiophenes10.1021/jp210822s ↗
5. Synthesis, characterization and optical limiting property of covalently oligothiophene functionalized graphene material10.1016/j.carbon.2009.07.027 ↗
6. Oligothiophene semiconductors: synthesis, characterization, and applications for organic devices10.1021/am4060468 ↗
7. Orientation management of α-sexithiophene layer for the application in organic photovoltaic devices10.1016/j.orgel.2012.09.017 ↗
8. Efficient oligothiophene: fullerene bulk heterojunction organic photovoltaic cells10.1016/j.orgel.2008.03.008 ↗
9. Oriented polyfluorene films dye-doped for whitening of polarized electroluminescent devices10.1143/JJAP.50.04DK20 ↗
10. White polarized electroluminescence devices by dye deposition on oriented polyfluorene films
11. Low energy electronic and optical properties of α-sexithiophene single crystals10.1016/S0928-4931(97)00038-6 ↗
12. Two-layer light-emitting diodes based on sexithiophene and derivatives10.1002/adma.19940061007 ↗
13. Disorder influenced optical properties of α-sexithiophene single crystals and thin evaporated films
14. Properties and crystal structure of perfluoro- α -sexithiophene10.1016/S0379-6779(02)00304-1 ↗
15. Influence of field-effect charges on the optical properties of α- sexithiophene thin films10.1016/S0379-6779(96)03764-2 ↗
16. Light controls polymorphism in thin films of sexithiophene10.1021/cg501734w ↗
17. Correlation of the number of thiophene units with structural order and carrier mobility in unsubstituted even- and odd-numbered α-oligothiophene films10.1021/jp044222l ↗
18. Lifetime of organic salt photovoltaics10.1002/aenm.201703678 ↗
19. Optical properties of sexithiophene films grown on ordered and disordered TiO2(110) surfaces10.1016/j.tsf.2007.12.164 ↗
20. Molecular orientation in ultrathin films of α-sexithiophene on silicon dioxide revealed by spatially resolved confocal spectroscopy10.1016/j.synthmet.2005.09.034 ↗
21. The role of electrodynamics in the spectra of organic crystals with mesoscopic order: nanocrystalline α-sexithiophene
22. Temperature activated de-trapping processes in vacuum deposited sexithiophene thin films10.1016/S0379-6779(01)00654-3 ↗
23. Spin correlated radical ion pairs generated by photoinduced electron transfer in composites of sexithiophene/fullerene derivatives: a transient EPR study
24. Absorption and electroabsorption spectra of an α-sexithiophene single crystal at 20 K10.1016/S0379-6779(00)00427-6 ↗
25. Topological, morphological and optical properties of Gamma irradiated Ni (II) tetraphenyl porphyrin thin films10.1016/j.optcom.2011.12.019 ↗
26. Thickness dependence of structural and optical properties of indium tin oxide nanofiber thin films prepared by electron beam evaporation onto quartz substrates10.1016/j.mseb.2011.10.018 ↗
27. Epitaxial growth and domain coalescence of sexithiophene induced by the steps on cleaved KBr(0 0 1)10.1016/j.jcrysgro.2004.01.054 ↗
28. ZnO nanostructures with tunable visible luminescence: effects of kinetics of chemical reduction and annealing
29. The effect of substrate temperature on the optical properties of polycrystalline Sb2O3 thin films10.1016/j.jcrysgro.2005.01.056 ↗
30. Effect of annealing and UV irradiation on structural and optical properties of 6-(3,4 Dimethoxyphenyl)-1-methyl-3-oxo-2-phenyl-2,3-dihydro1Hpyrazolo[4,3-b]-5-carbonitrile thin films10.1016/j.optmat.2017.04.065 ↗
31. The effects of annealing temperature on the structural properties and optical constants of a novel DPEA-MR-Zn organic crystalline semiconductor nanostructure thin films10.1016/j.optmat.2017.08.007 ↗
32. Behavior of the electronic dielectric constant in covalent and ionic materials10.1103/PhysRevB.3.1338 ↗
33. Fabrication and characterization of anthracene thin films for wide scale organic optoelectronic applications based on linear/nonlinear analyzed optical dispersion parameters10.1016/j.optmat.2017.05.006 ↗
34. Structural and optical characterizations of Ni (II) tetraphenyl porphyrin thin films10.1051/epjap/2012110280 ↗
35. Polariton effects in π-conjugated molecular solids: single crystal and nanocrystalline films of sexithiophene10.1016/S0379-6779(03)00303-5 ↗
36. Effect of annealing on structural and optical properties of copper tetraphenylporphyrin (CuTPP) thin films10.1016/j.optlastec.2014.04.013 ↗
37. Effect of Se addition on optical and electrical properties of chalcogenide CdSSe thin films10.1016/j.spmi.2015.10.044 ↗
38. Effective role of thickness on structural, electrical and optical properties of lead sulphide thin films for photovoltaic applications10.1016/j.mseb.2017.06.003 ↗
39. Dielectric function and one-dimensional description of the absorption of poly (3-octylthiophene)10.1016/S0379-6779(02)00502-7 ↗
40. Electronic polarization at surfaces and thin films of organic molecular crystals: PTCDA10.1016/S0009-2614(02)00774-1 ↗
41. 2003 · 7
42. Studies on dielectric properties, opto-electrical parameters and electronic polarizability of thermally evaporated amorphous Cd50S50-xSex thin films10.1016/j.jallcom.2016.02.126 ↗
43. Determination of structural and optical properties of gold phthalocyanine thin films using density functional theory10.1016/j.mssp.2013.06.001 ↗
44. Optical characterizations of thermally evaporated perylene-66 (dye content 40%) thin films10.1016/j.ssc.2012.10.027 ↗
45. Influence of annealing temperature on structural and optical properties of nanocrystalline Platinum octaethylporphyrin (PtOEP) thin films10.1016/j.optmat.2015.09.032 ↗
46. Mills · 1998 · vol. 2 · 37
47. Plasma impact on structural, morphological and optical properties of copper acetylacetonate thin films10.1016/j.saa.2018.04.001 ↗
48. Calculation of macroscopic linear and nonlinear optical susceptibilities for the naphthalene, anthracene and meta nitroaniline crystals
49. A study on linear and non-linear optical constants of Rhodamine B thin film deposited on FTO glass
50. A WO3/ZnO nanoparticle composite system with high photochromic performance
51. Organic materials for nonlinear optics10.1002/adma.19930050304 ↗