Linear and nonlinear properties of novel materials based on DNA containing [2.2]paracyclophane moiety
Source abstract
Abstract
Abstract In this study, the synthesis and the characterization of new deoxyribonucleic acid (DNA) based compounds containing [2.2]paracyclophane moiety are reported. The DNA molecule was functionalized with hexadecyltrimethylammonium chloride (CTMA), [2.2]paracyclophane-4-methoxy-5-formyl [A] and [2.2]paracyclophane-4-hydroxy-5-formyl [B], respectively. These compounds were used for obtaining good optical quality thin films by spin coating method. The absorption and emission spectra of studied solutions and thin films showed that the new obtained materials are of good optical properties. The third-order nonlinear optical (NLO) properties of thin films were characterized by the optical third-harmonic generation technique at 1064.2 nm fundamental wavelength.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: DNA and Nucleic Acid Chemistry · RNA Interference and Gene Delivery · Advanced biosensing and bioanalysis techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (41)
Show source-provided references
1. Counterintuitive affinity of [2.2]paracyclophane to cations10.1016/j.cplett.2005.03.150 ↗
2. A critical account on π–π stacking in metal complexes with aromatic nitrogen-containing ligands10.1039/b003010o ↗
3. Aromatic interactions10.1039/b008495f ↗
4. Cation-pi interactions in structural biology10.1073/pnas.96.17.9459 ↗
5. The cation-π interaction10.1021/cr9603744 ↗
6. Preparation and structure of Di-p-xylylene10.1038/164915b0 ↗
7. NMR and computational studies of the chemical reduction of [2.2]paracyclophane: formation of dianionic p-xylenyl oligomers10.1039/b311885a ↗
8. Vögtle · 1993
9. Bichromophoric Paracyclophanes: models for interchromophore delocalization10.1021/ar9901568 ↗
10. Synthesis, characterization, and spectroscopy of 4,7,12,15-[2.2]Paracyclophane containing donor and acceptor groups: impact of substitution patterns on through-space charge transfer10.1021/ja0121383 ↗
11. NMR and computational studies of the chemical reduction of [2.2]paracyclophane: formation of dianionic p-xylenyl oligomers10.1039/b311885a ↗
12. Ge- and sn-containing poly(p-xylylene): synthesis, structure and thermal behaviour10.1002/(SICI)1521-3935(19981001)199:10<2179::AID-MACP2179>3.0.CO;2-I ↗
13. [2.2]Paracyclophane derivatives in asymmetric catalysis10.1039/b300717k ↗
14. Planar and central chiral [2.2]paracyclophane-based N,O-ligands as highly active catalysts in the diethylzinc addition to aldehydes10.1039/b108347c ↗
15. Electric field tunable light emitting diodes containing Europium β-diketonates with [2.2]paracyclophane moiety10.1016/j.optmat.2016.04.034 ↗
16. The substituted [2.2] paracyclophanes as versatile platform for a design of new optical materials
17. Thermotropic liquid crystals from planar chiral compounds: optically active mesogenic [2.2]Paracyclophane derivatives10.1002/1521-3773(20020916)41:18<3411::AID-ANIE3411>3.0.CO;2-A ↗
18. The transannular interaction in [2.2]Paracyclophane: repulsive or attractive?10.1002/cphc.200200597 ↗
19. Fluorescence, optical absorption and third-order nonlinear optical properties of terbium (III) complex embedded into DNA-CTMA matrix10.1016/j.jlumin.2016.10.010 ↗
20. Functional DNA directed assembly of nanomaterials for biosensing10.1039/b813939c ↗
21. Preparation of novel bio-matrix by the complexation of DNA and metal ions10.1016/j.polymer.2005.07.086 ↗
22. DNA- and DNA-CTMA - novel bio-nanomaterials for application in photonics and in electronics10.1117/12.2032258 ↗
23. Fluorescence, spectroscopic and NLO properties of green tea extract in deoxyribonucleic acid10.1016/j.optmat.2013.04.016 ↗
24. DNA based materials doped with praseodymium (III) hydroxide nanoparticles10.1016/j.optmat.2015.11.011 ↗
25. A significant improvement of luminance vs current density efficiency of a BioLED10.1016/j.optmat.2014.01.018 ↗
26. Synthesis, linear and nonlinear optical properties of DNA-CTMA/europium (III) complex10.1016/j.synthmet.2016.08.013 ↗
27. Novel materials based on DNA-CTMA and lanthanide (Ce3+, Pr3+)10.1002/bip.22861 ↗
28. Synthesis, characterization, and spectroscopy of 4,7,12,15-[2.2]Paracyclophane containing donor and acceptor groups: impact of substitution patterns on through-space charge transfer10.1021/ja0121383 ↗
29. A highly π-stacked organic semiconductor for thin film transistors based on fused thiophenes10.1021/ja9735968 ↗
30. Narrow bandwidth luminescence from blends with energy transfer from semiconducting conjugated polymers to europium complexes10.1002/(SICI)1521-4095(199911)11:16<1349::AID-ADMA1349>3.0.CO;2-W ↗
31. Pope · 1982
32. NLO properties of functionalized DNA thin films10.1016/j.tsf.2007.11.089 ↗
33. Grating inscription in picosecond regime in thin films of functionalized DNA10.1364/OE.15.015268 ↗
34. Opportunities of deoxyribonucleic acid complexes composites for nonlinear optical applications10.1063/1.3655985 ↗
35. Nonlinear optical properties of functionalized DNA-CTMA complexes
36. UV absorption and luminescence spectra of [2.2]paracyclophane phenyl derivatives10.1007/s10812-016-0237-x ↗
37. Nonlinear optical properties of thin films of polysilane10.1063/1.337759 ↗
38. Third harmonic generation in liquids10.1103/PhysRevA.32.2352 ↗
39. Grote · Mol. Cryst. Liq. Cryst. · 2005 · 426 · 310.1080/15421400590890615 ↗
40. Optical third-harmonic generation of fused silica in gas atmosphere: absolute value of the third-order nonlinear optical susceptibility χ(3)10.1103/PhysRevB.61.10702 ↗
41. Nonlinear properties of poled polymer films: SHG and electrooptic measurements10.1117/12.50719 ↗