Synthesis and optical properties of Mn-doped Ba3Al2O6 intense blue oxides
Source abstract
Abstract
Abstract The solid solution of Ba3Al2-xMnxO6+y (0 ≤ x ≤ 0.2) is successfully synthesized through solid state reaction. The colors of compounds are tuned from sky blue (x ≤ 0.1) to ocean blue (x = 0.2) with the increase of Mn content. The X-ray diffraction data shows that the major phase of all the as-synthesized samples is cubic Ba3Al2O6 structure with the space group of P213. The oxidation state of Mn is confirmed to be +5 by X-ray photoelectron spectroscopy analysis. UV–Vis absorption spectroscopy demonstrates that the sample's color comes from the d-d transition of Mn5+ located in [AlO4].
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Pigment Synthesis and Properties · Luminescence Properties of Advanced Materials · Advanced Photocatalysis Techniques
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (29)
Show source-provided references
1. Mn3+ in trigonal bipyramidal coordination: a new blue chromophore10.1021/ja9080666 ↗
2. Colored oxides with hibonite structure II: structural and optical properties of CaAl12O19-type pigments with chromophores based on Fe, Mn, Cr and Cu10.1016/j.progsolidstchem.2017.02.002 ↗
3. M-doped Al2TiO5 (M = Cr, Mn, Co) solid solutions and their use as ceramic pigments10.1111/j.1551-2916.2009.03172.x ↗
4. Ba3(P1−xMnxO4)2: blue/green inorganic materials based on tetrahedral Mn (V)10.1007/s12034-011-0164-7 ↗
5. Stabilization of a tetrahedral (Mn5+O4) chromophore in ternary barium oxides as a strategy toward development of new turquoise/green-colored pigments10.1021/acs.inorgchem.5b02957 ↗
6. Discovery of novel inorganic Mn5+-doped sky-blue pigments based on Ca6BaP4O17: crystal structure, optical and color properties, and color durability10.1016/j.dyepig.2016.12.038 ↗
7. New oxygen-deficient cationic-ordered perovskites containing turquoise-coloring Mn5+O4 tetrahedral layers10.1016/j.jssc.2016.12.020 ↗
8. Intense turquoise and green colors in brownmillerite-type oxides based on Mn5+ in Ba2In2–xMnxO5+x10.1021/ic3020332 ↗
9. Synthesis and optical properties of turquoise-and green-colored brownmillerite-type Ba2In2−x−yMnxAlyO5+x codoped with manganese and aluminum10.1007/s12613-016-1357-2 ↗
10. Synthesis and properties of novel turquoise-green pigments based on BaAl2-xMnxO4+y10.1016/j.dyepig.2018.03.042 ↗
11. A phase equilibria study and thermodynamic assessment of the BaO-Al2O3 system10.1016/j.calphad.2015.07.003 ↗
12. Optical and EPR properties of BaAl12O19: Eu2+, Mn2+ phosphor prepared by facile solution combustion approach10.1016/j.jlumin.2014.08.002 ↗
13. X-ray absorption spectroscopy and tunable color emission study of the Mn-co-doped BaAl2O4: Ce phosphor under synchrotron radiation10.1016/j.optmat.2019.03.052 ↗
14. Synthesis and photoluminescence properties of Ba3Al2O6:Eu3+ red phosphor10.1007/s10853-016-9843-5 ↗
15. On the crystal structure and cation valence of Mn in Mn-substituted Ba-β-Al2O310.1006/jcat.1998.2220 ↗
16. Synergistic catalysis effect of Mn-promoted BaAl2O4 catalysts on catalytic performance for soot combustion10.1016/j.catcom.2015.06.020 ↗
17. Crystal structure of barium aluminate (Ba3Al2O6)
18. Die kristallstrukturen der erdalkalialuminate Ba3Al2O6 und Ba2.33Ca0.67Al2O6 (≡Ba7Ca2Al6O18)10.1016/0925-8388(94)91050-2 ↗
19. On the symmetry of Ba3Al2O6 - X-ray diffraction and Raman spectroscopy studies10.1016/j.solidstatesciences.2008.04.025 ↗
20. Eu3+- and Ho3+-doped Ba3Al2O6- and MgAl2O4-type phosphors and their photoluminescent properties10.1007/s10973-017-6786-2 ↗
21. Carbon dioxide absorption and desorption properties of Ba3Al2O610.2109/jcersj2.15225 ↗
22. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
23. Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Cr, Mn, Fe, Co and Ni10.1016/j.apsusc.2010.10.051 ↗
24. Facile synthesis of brownmillerite-type oxides Ba2In2-xMnxO5+x through a microwave-assisted process10.1016/j.solidstatesciences.2016.12.019 ↗
25. Enhanced oxide ion conductivity in stabilized cubic BaInO2.5 by Mn5+ doping10.1016/j.inoche.2013.04.035 ↗
26. Laser-related spectroscopy of ion-doped crystals for tunable solid-state lasers10.1007/s003400100540 ↗
27. Ligand field theory and its applications
28. Optical spectroscopy of (MnO4)3− and (VO4)5− in Sr10(VO4)6F210.1088/0953-8984/9/45/017 ↗
29. Intense turquoise colors of apatite-type compounds with Mn5+ in tetrahedral coordination10.1016/j.solidstatesciences.2015.12.001 ↗