Synthesis of the uniform hollow spherical Sr2SiO4:Eu2+ phosphors via an h-BN protective method

Abstract The uniform hollow spherical Sr 2 SiO 4 :Eu 2+ green emitting phosphors have been successfully synthesized using hollow silica spheres as templates by an h -BN protective method. The scanning electron microscopy (SEM) and transmission electron microscopy (TEM) results directly confirmed the existence of the hollow spherical structure with a narrow size distribution and a shell thickness of 15–25 nm. The h -BN protective film, observed by high resolution TEM, plays an important role in the formation of the hollow spherical morphology and the improvement of photoluminescence properties. Comparing with the Sr 2 SiO 4 :Eu 2+ micron-phosphor prepared by the traditional solid state reaction method, the hollow spherical phosphor with nano-sized grains exhibits stronger green emission under ultraviolet–blue light excitation. This could be attributed to the elimination of surface defects by the h -BN coating. This research gives an economic and convenient way to synthesize uniform spherical phosphors with high quantum efficiency.