Synthesis, crystal structure and non-linear optical properties of inorganic–organic hybrid compound based on face-sharing octahedral [PbBr3]∞ chains
Source abstract
Abstract
Abstract 4-BenzylPiPeridine-PbBr 3 has been synthesized. The crystal structures of the title compound have been defined by X-ray diffraction analysis and characterized by FT-IR, Raman and UV–visible instrumental methods. The recorded spectrum by UV–visible spectroscopy for the investigated compound show good transparency in the visible region. This result indicates a non-zero value of the first Hyperpolarizability. We also report DFT calculations of the electric dipole moments ( μ ), Polarizability ( α ), the first Hyperpolarizability ( β ) and HOMO–LUMO analysis of the title compound was theoretically investigated by Gaussian 03 package. Our results suggest that the investigated material might have microscopic nonlinear optical behavior with non-zero values.
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Research context
OpenAlex topics: Nonlinear Optical Materials Research · Solid-state spectroscopy and crystallography · Photochemistry and Electron Transfer Studies
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References (32)
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