journal article·2016-02

Preparation and investigation of Ge–S–I glasses for infrared fiber optics

A.P. Velmuzhov, M.V. Sukhanov, A.D. Plekhovich, G.E. Snopatin, M.F. Churbanov, L.D. Iskhakova, R.P. Ermakov, T.V. Kotereva, V.S. Shiryaev

Optical Materials· Volume 52
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Abstract

Abstract Glass samples of [GeSx]90I10 (x = 1.5, 1.7, 2.0, 2.3, 2.45, 2.6) compositions were prepared, and some their thermal, optical properties as well as tendency to crystallization were investigated. The compositional dependences of glass transition temperature, volume fraction of crystallized phase and activation energy of glass formation (Eg) have nonmonotonic character with a maximum for [GeS2.0]90I10 glass. Glasses of 85.8GeS2–14.2GeI4 and [GeS1.5]90I10 compositions are identified as promising for preparation of optical fiber. For the first time, Ge–S–I glass fibers were produced. Minimum optical losses in 85.8GeS2–14.2GeI4 glass fiber were 2.7 dB/m at a wavelength of 5.1 μm, and that in [GeS1.5]90I10 glass fiber were 14.5 dB/m at 5.5 μm.
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Research context

OpenAlex topics: Phase-change materials and chalcogenides · Glass properties and applications · Nonlinear Optical Materials Research

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