journal article·2019-03

Ionic liquids for active photonics components fabrication

Krzysztof Rola, Adrian Zając, Maciej Czajkowski, Andrea Szpecht, Maria Zdończyk, Marcin Śmiglak, Joanna Cybińska, Katarzyna Komorowska

Optical Materials· Volume 89
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Abstract

Abstract We report the new fluorescent polymerizable imidazolium-based ionic liquids for photonics application. We investigate two approaches: one ionic liquid (IL) contains the active fluorescein dianion as an intrinsic part of the polymerizable ionic liquid structure. The second liquid is based on the mixture of polymerizable ionic liquid with optically active europium(III) nitrate hydrate. We demonstrate the polymerization abilities of both liquids by means of electron beam in vacuum conditions. Furthermore, we measure the light emission properties of liquid and polymerized structures. The results reveal that IL with europium(III) nitrate hydrate yields emission spectrum with Eu3+ bands not only as a liquid but also as a polymerized solid microstructure, which is important for its application in active photonics components.
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Research context

OpenAlex topics: Ionic liquids properties and applications · Oxidative Organic Chemistry Reactions · Catalysis and Oxidation Reactions

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Ionic Liquids in Chemical Analysis10.1080/10408340500304016 ↗
2. Task Specific Ionic Liquids for Cellulose Technology10.1246/cl.2009.2 ↗
3. Task-Specific Ionic Liquids10.1002/anie.200905981 ↗
4. Point-Functionalization of Ionic Liquids: An Overview of Synthesis and Applications10.1002/ejoc.201402093 ↗
5. Magnetic ionic liquids in analytical chemistry: A review10.1016/j.aca.2016.06.011 ↗
6. Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis10.1021/cr980032t ↗
7. Applications of ionic liquids in the chemical industry10.1039/B006677J ↗
8. Progress in the use of ionic liquids as electrolyte membranes in fuel cells10.1016/j.memsci.2014.06.033 ↗
9. Ionic liquids for energy, materials, and medicine10.1039/C4CC02021A ↗
10. Application of Ionic Liquids to Energy Storage and Conversion Materials and Devices10.1021/acs.chemrev.6b00504 ↗
11. State-of-the-Art of CO2 Capture with Ionic Liquids10.1021/ie3003705 ↗
12. Ionic-Liquid-Based CO2 Capture Systems: Structure, Interaction and Process10.1021/acs.chemrev.7b00072 ↗
13. Preparation and polymerization of new organic molten salts; N-alkylimidazolium salt derivatives10.1016/S0013-4686(99)00334-5 ↗
14. Solvent Tunable Optical Properties of a Polymerized Vinyl- and Thienyl-Substituted Ionic Liquid10.1021/jp102904e ↗
15. Polymeric ionic liquids: Broadening the properties and applications of polyelectrolytes10.1016/j.progpolymsci.2011.05.007 ↗
16. Poly(ionic liquid)s: Polymers expanding classical property profiles10.1016/j.polymer.2011.01.043 ↗
17. Thermoresponsive polyelectrolytes derived from ionic liquids10.1039/C4PY01665C ↗
18. Three-dimensional micro/nano-scale structure fabricated by combination of non-volatile polymerizable RTIL and FIB irradiation10.1038/srep03722 ↗
19. Polymerization of Room-Temperature Ionic Liquid Monomers by Electron Beam Irradiation with the Aim of Fabricating Three-Dimensional Micropolymer/Nanopolymer Structures10.1021/la503252p ↗
20. Ionic liquids - a novel material for planar photonics10.1088/1361-6528/aae01e ↗
21. Amino Acid-Based Fluorescent Chiral Ionic Liquid for Enantiomeric Recognition10.1021/ac9027774 ↗
22. Self-Aggregation Behavior of Fluorescent Carbazole-Tailed Imidazolium Ionic Liquids in Aqueous Solutions10.1021/jp908136f ↗
23. Fluorescent quinolizinium ionic liquids (salts) with unexpectedly high quantum yields up to >99%10.1039/c1jm11556a ↗
24. Spectroscopic behavior of fluorescein as a constituent anion in a phosphonium-based ionic liquid material10.1016/j.matchemphys.2011.12.009 ↗
25. Excited-State Proton Transfer of Fluorescein Anion as an Ionic Liquid Component10.1021/jp408616r ↗
26. Ionic liquid-based fluorescein colorimetric pH nanosensors10.1039/c3ra42394h ↗
27. Fluorescein-based ionic liquid sensor for label-free detection of serum albumins10.1039/C4RA01461H ↗
28. Selective detection of picric acid by a fluorescent ionic liquid chemosensor10.1016/j.snb.2016.02.016 ↗
29. Tailor-made dicationic ionic liquid as a fluorescent sensor for detection of hydroquinone and catechol10.1016/j.molliq.2017.08.119 ↗
30. Designing an anion-functionalized fluorescent ionic liquid as an efficient and reversible turn-off sensor for detecting SO210.1039/C7CC00676D ↗
31. EuIII Luminescence in a Hygroscopic Ionic Liquid: Effect of Water and Evidence for a Complexation Process10.1002/ejic.200300588 ↗
32. Strong luminescence of rare earth compounds in ionic liquids: Luminescent properties of lanthanide(III) iodides in the ionic liquid 1-dodecyl-3-methylimidazolium bis(trifluoromethanesulfonyl)imide10.1016/j.jallcom.2005.10.069 ↗
33. Exploring the potential of europium(III) luminescence for the detection of phase transitions in ionic liquid crystals10.1039/B614036J ↗
34. Europium-Based Ionic Liquids as Luminescent Soft Materials10.1002/anie.200801159 ↗
35. Luminescent Soft Material: Two New Europium-Based Ionic Liquids10.1002/hlca.200900173 ↗
36. Rare earth metal-containing ionic liquids10.1016/j.ccr.2018.02.004 ↗
37. FRET function of polymeric ionic liquid film containing rhodamine moieties for exhibiting emissions by excitation at wide wavelength areas10.1016/j.jphotochem.2011.06.009 ↗
38. Luminescent Materials of Europium(III) Coordinated by a Terpyridine-Functionalized Poly(Ionic Liquid)10.1002/ejic.201301168 ↗
39. Lanthanide Luminescence Improvement by Using a Functional Poly(Ionic Liquid) as Matrix and Co‐ligand10.1002/asia.201501209 ↗
40. Effect of Ionic Liquid on Prototropic and Solvatochromic Behavior of Fluorescein10.1021/jp106601a ↗
41. Birks · 1970
42. Interpretation of europium (III) spectra10.1016/j.ccr.2015.02.015 ↗
43. Luminescence and Energy Transfer in Solutions of Rare‐Earth Complexes. I. Enhancement of Fluorescence by Deuterium Substitution10.1063/1.1696166 ↗
44. Fluorescence spectra and lifetime measurements of aqueous solutions of europium nitrate and perchlorate10.1021/ic50193a017 ↗
45. Lanthanide ion luminescence probes of the structure of biological macromolecules10.1021/ar00072a004 ↗
46. The luminescence of europium nitrate hexahydrate, Eu(NO3)3·6H2O10.1016/S0020-1693(00)80677-5 ↗
47. Carboxyl-functionalized ionic liquids: synthesis, characterization and synergy with rare-earth ions10.1039/C8TC00658J ↗