journal article·2020-10

Giant-miscanthus-derived activated carbon and its application to lithium sulfur batteries

Geon Hae Lim, Ji Su Chae, Young-Lok Cha, Yun Chan Kang, Kwang Chul Roh

Carbon Letters· Volume 30· Issue 5
Publisher page

Abstract

Giant miscanthus (GM) is an Asian grass that can produce biomass in high yields per land area. It can be used as a cathode material in lithium sulfur (Li/S) batteries. Giant-miscanthus-derived activated carbon (GMAC) is prepared via carbonization of GM followed by KOH activation. It is prepared with a large amount of KOH, and thus contained more defects but had a highly porous structure and graphitic cluster lattice. GMAC has a large specific surface area of 3327 m2/g and a large total pore volume of 1.86 cm3/g. The pore volume served as a storage space for the retention of polysulfides, thereby inhibiting the shuttle effect. When a GMAC–sulfur composite cathode is tested in a Li/S battery, an initial discharge capacity of 1148 mAh/g can be attained at 0.1 C. In a cyclic charge–discharge experiment at 1 C, discharge capacities of 529 mAh/g and 248 mAh/g are observed in the first and 200th cycles, respectively.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Advanced Battery Materials and Technologies · Supercapacitor Materials and Fabrication · Advanced Battery Technologies Research

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (44)

Show source-provided references
1. Lewandowski I, Clifton-Brown J, Scurlock J, Huisman W (2000) Miscanthus: European experience with a novel energy crop. Biomass Bioenerg 19(4):209–22710.1016/S0961-9534(00)00032-5 ↗
2. McKendry P (2002) Energy production from biomass (part 1): overview of biomass. Biores Technol 83(1):37–46. https://doi.org/10.1016/S0960-8524(01)00118-310.1016/S0960-8524(01)00118-3 ↗
3. Hui TS, Zaini MAA (2015) Potassium hydroxide activation of activated carbon: a commentary. Carbon Lett 16(4):275–280. https://doi.org/10.5714/cl.2015.16.4.27510.5714/cl.2015.16.4.275 ↗
4. Kim M-H, Kim K-B, Kang K, Han JT, Roh KC (2013) Ribbon-like activated carbon with a multi-structure for supercapacitors. Journal of Materials Chemistry A 1(44):14008–14012. https://doi.org/10.1039/C3TA13138F10.1039/C3TA13138F ↗
5. Xia L, Zhou Y, Ren J, Wu H, Lin D, Xie F, Jie W, Lam KH, Xu C, Zheng Q (2018) An eco-friendly microorganism method to activate biomass for cathode materials for high-performance lithium–sulfur batteries. Energy Fuels 32(9):9997–10007. https://doi.org/10.1021/acs.energyfuels.8b0145310.1021/acs.energyfuels.8b01453 ↗
6. Sun K, Jc Jiang (2010) Preparation and characterization of activated carbon from rubber-seed shell by physical activation with steam. Biomass Bioenerg 34(4):539–544. https://doi.org/10.1016/j.biombioe.2009.12.02010.1016/j.biombioe.2009.12.020 ↗
7. Qu J, Lv S, Peng X, Tian S, Wang J, Gao F (2016) Nitrogen-doped porous “green carbon” derived from shrimp shell: Combined effects of pore sizes and nitrogen doping on the performance of lithium sulfur battery. J Alloy Compd 671:17–23. https://doi.org/10.1016/j.jallcom.2016.02.06410.1016/j.jallcom.2016.02.064 ↗
8. Cho SY, Yun YS, Lee S, Jang D, Park K-Y, Kim JK, Kim BH, Kang K, Kaplan DL, Jin H-J (2015) Carbonization of a stable β-sheet-rich silk protein into a pseudographitic pyroprotein. Nat Commun 6:7145. https://doi.org/10.1038/ncomms814510.1038/ncomms8145 ↗
9. Tay T, Ucar S, Karagöz S (2009) Preparation and characterization of activated carbon from waste biomass. J Hazard Mater 165(1):481–485. https://doi.org/10.1016/j.jhazmat.2008.10.01110.1016/j.jhazmat.2008.10.011 ↗
10. Zhao Y, Zhang X, He Y, Liu N, Tan T, Liang C (2017) Biomass derived nitrogen-doped highly porous carbon material with a hierarchical porous structure for high-performance lithium/sulfur batteries. Materials 10(10):1158. https://doi.org/10.3390/ma1010115810.3390/ma10101158 ↗
11. Jones MB, Walsh M (2001) Miscanthus for energy and fibre. Earthscan, London
12. Niu S, Zhou G, Lv W, Shi H, Luo C, He Y, Li B, Yang Q-H, Kang F (2016) Sulfur confined in nitrogen-doped microporous carbon used in a carbonate-based electrolyte for long-life, safe lithium–sulfur batteries. Carbon 109:1–6. https://doi.org/10.1016/j.carbon.2016.07.06210.1016/j.carbon.2016.07.062 ↗
13. Yao H, Zheng G, Hsu P-C, Kong D, Cha JJ, Li W, Seh ZW, McDowell MT, Yan K, Liang Z, Narasimhan VK, Cui Y (2014) Improving lithium–sulphur batteries through spatial control of sulphur species deposition on a hybrid electrode surface. Nat Commun 5:3943. https://doi.org/10.1038/ncomms494310.1038/ncomms4943 ↗
14. Li G, Wang X, Seo MH, Li M, Ma L, Yuan Y, Wu T, Yu A, Wang S, Lu J, Chen Z (2018) Chemisorption of polysulfides through redox reactions with organic molecules for lithium–sulfur batteries. Nat Commun 9(1):705. https://doi.org/10.1038/s41467-018-03116-z10.1038/s41467-018-03116-z ↗
15. Wu F, Li J, Tian Y, Su Y, Wang J, Yang W, Li N, Chen S, Bao LJSR (2015) 3D coral-like nitrogen-sulfur co-doped carbon-sulfur composite for high performance lithium-sulfur batteries. Sci Rep 5:1334010.1038/srep13340 ↗
16. Zhou G, Paek E, Hwang GS, Manthiram A (2015) Long-life Li/polysulphide batteries with high sulphur loading enabled by lightweight three-dimensional nitrogen/sulphur-codoped graphene sponge. Nat Commun 6:7760. https://doi.org/10.1038/ncomms876010.1038/ncomms8760 ↗
17. Sohn H, Gordin ML, Regula M, Kim DH, Jung YS, Song J, Wang DJJOPS (2016) Porous spherical polyacrylonitrile-carbon nanocomposite with high loading of sulfur for lithium–sulfur batteries. J Power Sources 302:70–7810.1016/j.jpowsour.2015.10.013 ↗
18. Ahn W, Lim SN, Lee DU, Kim K-B, Chen Z, Yeon S-H (2015) Interaction mechanism between a functionalized protective layer and dissolved polysulfide for extended cycle life of lithium sulfur batteries. J Mater Chem A 3(18):9461–9467. https://doi.org/10.1039/C5TA01378J10.1039/C5TA01378J ↗
19. Jung DS, Hwang TH, Lee JH, Koo HY, Shakoor RA, Kahraman R, Jo YN, Park M-S, Choi JWJNL (2014) Hierarchical porous carbon by ultrasonic spray pyrolysis yields stable cycling in lithium–sulfur battery. Nano Lett 14(8):4418–442510.1021/nl501383g ↗
20. Strubel P, Thieme S, Biemelt T, Helmer A, Oschatz M, Brückner J, Althues H, Kaskel SJAFM (2015) ZnO hard templating for synthesis of hierarchical porous carbons with tailored porosity and high performance in lithium–sulfur battery. Adv Func Mater 25(2):287–29710.1002/adfm.201402768 ↗
21. Li G, Sun J, Hou W, Jiang S, Huang Y, Geng J (2016) Three-dimensional porous carbon composites containing high sulfur nanoparticle content for high-performance lithium–sulfur batteries. Nat Commun 7:10601. https://doi.org/10.1038/ncomms1060110.1038/ncomms10601 ↗
22. Sun Q, Xi B, Li JY, Mao H, Ma X, Liang J, Feng J, Xiong SJAEM (2018) Nitrogen-doped graphene-supported mixed transition-metal oxide porous particles to confine polysulfides for lithium–sulfur batteries. Adv Energy Mater 8:180059510.1002/aenm.201800595 ↗
23. Wang X, Zhang Z, Qu Y, Lai Y, Li J (2014) Nitrogen-doped graphene/sulfur composite as cathode material for high capacity lithium–sulfur batteries. J Power Sources 256:361–368. https://doi.org/10.1016/j.jpowsour.2014.01.09310.1016/j.jpowsour.2014.01.093 ↗
24. Shi J-L, Tang C, Huang J-Q, Zhu W, Zhang QJJOEC (2018) Effective exposure of nitrogen heteroatoms in 3D porous graphene framework for oxygen reduction reaction and lithium–sulfur batteries. J Energy Chem 27(1):167–17510.1016/j.jechem.2017.09.014 ↗
25. Xu G, Yan Q-b, Kushima A, Zhang X, Pan J, Li JJNE (2017) Conductive graphene oxide-polyacrylic acid (GOPAA) binder for lithium-sulfur battery. Nano Energy 31:568–57410.1016/j.nanoen.2016.12.002 ↗
26. Li Y, Mi R, Li S, Liu X, Ren W, Liu H, Mei J, Lau W-M (2014) Sulfur–nitrogen doped multi walled carbon nanotubes composite as a cathode material for lithium sulfur batteries. Int J Hydrog Energy 39(28):16073–1608010.1016/j.ijhydene.2014.04.047 ↗
27. Gueon D, Hwang JT, Yang SB, Cho E, Sohn K, Yang D-K, Moon JHJAN (2018) Spherical macroporous carbon nanotube particles with ultrahigh sulfur loading for lithium–sulfur battery cathodes. ACS Nano 12(1):226–23310.1021/acsnano.7b05869 ↗
28. Li M, Carter R, Douglas A, Oakes L, Pint CLJAN (2017) Sulfur vapor-infiltrated 3D carbon nanotube foam for binder-free high areal capacity lithium–sulfur battery composite cathodes. ACS Nano 11(5):4877–488410.1021/acsnano.7b01437 ↗
29. Ren W, Ma W, Zhang S, Tang BJCEJ (2018) Nitrogen-doped carbon fiber foam enabled sulfur vapor deposited cathode for high performance lithium sulfur batteries. Chem Eng J 341:441–44910.1016/j.cej.2018.02.057 ↗
30. Ahn W, Seo MH, Jun Y-S, Lee DU, Hassan FM, Wang X, Yu A, Chen Z (2016) Sulfur nanogranular film-coated three-dimensional graphene sponge-based high power lithium sulfur battery. ACS Appl Mater Interfaces 8(3):1984–1991. https://doi.org/10.1021/acsami.5b1026710.1021/acsami.5b10267 ↗
31. Sohn H, Gordin ML, Xu T, Chen S, Lv D, Song J, Manivannan A, Wang DJAAM (2014) Porous spherical carbon/sulfur nanocomposites by aerosol-assisted synthesis: the effect of pore structure and morphology on their electrochemical performance as lithium/sulfur battery cathodes. ACS Appl Mater Interfaces 6(10):7596–760610.1021/am404508t ↗
32. Liu J, Liu B, Wang C, Huang Z, Hu L, Ke X, Liu L, Shi Z, Guo Z (2017) Walnut shell—Derived activated carbon: synthesis and its application in the sulfur cathode for lithium–sulfur batteries. J Alloy Compd 718:373–378. https://doi.org/10.1016/j.jallcom.2017.05.20610.1016/j.jallcom.2017.05.206 ↗
33. Ryu HS, Park JW, Park J, Ahn J-P, Kim K-W, Ahn J-H, Nam T-H, Wang G, Ahn H-J (2013) High capacity cathode materials for Li–S batteries. J Mater Chem A 1(5):1573–1578. https://doi.org/10.1039/C2TA00056C10.1039/C2TA00056C ↗
34. Ji Hayashi, Kazehaya A, Muroyama K, Watkinson AP (2000) Preparation of activated carbon from lignin by chemical activation. Carbon 38(13):1873–1878. https://doi.org/10.1016/S0008-6223(00)00027-010.1016/S0008-6223(00)00027-0 ↗
35. Aygün A, Yenisoy-Karakaş S, Duman I (2003) Production of granular activated carbon from fruit stones and nutshells and evaluation of their physical, chemical and adsorption properties. Microporous Mesoporous Mater 66(2):189–195. https://doi.org/10.1016/j.micromeso.2003.08.02810.1016/j.micromeso.2003.08.028 ↗
36. Prahas D, Kartika Y, Indraswati N, Ismadji S (2008) Activated carbon from jackfruit peel waste by H3PO4 chemical activation: pore structure and surface chemistry characterization. Chem Eng J 140(1):32–42. https://doi.org/10.1016/j.cej.2007.08.03210.1016/j.cej.2007.08.032 ↗
37. Bouchelta C, Medjram MS, Bertrand O, Bellat J-P (2008) Preparation and characterization of activated carbon from date stones by physical activation with steam. J Anal Appl Pyrol 82(1):70–77. https://doi.org/10.1016/j.jaap.2007.12.00910.1016/j.jaap.2007.12.009 ↗
38. Chang C-F, Chang C-Y, Tsai W-T (2000) Effects of burn-off and activation temperature on preparation of activated carbon from corn cob agrowaste by CO2 and Steam. J Colloid Interface Sci 232(1):45–49. https://doi.org/10.1006/jcis.2000.717110.1006/jcis.2000.7171 ↗
39. Rodríguez-Reinoso F, Molina-Sabio M, González MT (1995) The use of steam and CO2 as activating agents in the preparation of activated carbons. Carbon 33(1):15–23. https://doi.org/10.1016/0008-6223(94)00100-E10.1016/0008-6223(94)00100-E ↗
40. Yoshikawa M, Katagiri G, Ishida H, Ishitani A, Akamatsu T (1988) Raman spectra of diamondlike amorphous carbon films. J Appl Phys 64(11):6464–6468. https://doi.org/10.1063/1.34206310.1063/1.342063 ↗
41. Guo J, Xu Y, Wang C (2011) Sulfur-impregnated disordered carbon nanotubes cathode for lithium–sulfur batteries. Nano Lett 11(10):4288–4294. https://doi.org/10.1021/nl202297p10.1021/nl202297p ↗
42. Han J, Kwon JH, Lee J-W, Lee JH, Roh KC (2017) An effective approach to preparing partially graphitic activated carbon derived from structurally separated pitch pine biomass. Carbon 118:431–437. https://doi.org/10.1016/j.carbon.2017.03.07610.1016/j.carbon.2017.03.076 ↗
43. Zhao Y, Ren J, Tan T, Babaa M-R, Bakenov Z, Liu N, Zhang Y (2017) Biomass waste inspired highly porous carbon for high performance lithium/sulfur batteries. Nanomaterials 7(9):26010.3390/nano7090260 ↗
44. Zhang J, Xiang J, Dong Z, Liu Y, Wu Y, Xu C, Du G (2014) Biomass derived activated carbon with 3D connected architecture for rechargeable lithium–sulfur batteries. Electrochim Acta 116:146–151. https://doi.org/10.1016/j.electacta.2013.11.03510.1016/j.electacta.2013.11.035 ↗