Spectroscopic investigation of Dy3+:Lu2Si2O7 single crystal: A potential 589 nm laser medium

Abstract A trivalent dysprosium-doped Lu2Si2O7 single crystal was grown by the Czochralski method. Segregation coefficient of Dy3+ ion in the crystal is about 0.56. Spectroscopic properties of the crystal were investigated at room temperature. In particular, the polarized absorption spectra were analyzed using the Judd-Ofelt theory and the intensity parameters were determined. Then the spontaneous transition probabilities, branching ratios, and radiative lifetime related to the 4F9/2 multiplet were calculated. Emission cross-section for the 4F9/2 → 6H13/2 transition at 589 nm is up to 1.27 × 10−21 cm2 for E//Y polarization. Thermal conductivity of the crystal was measured to be 9.46 Wm−1K−1 at room temperature. The experimental results show that the Dy3+:Lu2Si2O7 crystal is a promising gain medium for solid state 589 nm laser.