Investigation of site occupancy and photoluminescence of Ce3+ in cubic borate Ba3Y2(B2O5)3 and Ce3+ → Tb3+ energy transfer behavior
Source abstract
Abstract
Abstract Ce3+, Tb3+ and Ce3+-Tb3+ activated Ba3Y2(B2O5)3 phosphors were synthesized by a sol-gel pyrolysis method. The synthesized phosphors were investigated using X-ray diffraction (XRD) analysis, photoluminescence emission and excitation spectra and luminescence decay curves. In the Ce3+ activated Ba3Y2(B2O5)3 samples, two different Ce3+ centers (marked as Ce(1) and Ce(2)) could exist. The Ba3Y2(B2O5)3:Tb3+ phosphor shows some emission peaks at ∼350–650 nm among which the green emission peak at 540 nm is the strongest. For the Ba3Y2(B2O5)3:Ce3+, Tb3+ co-doped phosphor, the existence of energy transfer process from Ce3+ center to Tb3+ center is confirmed and the interaction mechanism between Ce3+ and Tb3+ in Ba3Y2(B2O5)3:Ce3+,Tb3+ system is dipole-dipole interaction based on Inokuti–Hirayama (I H) model.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Luminescence Properties of Advanced Materials · Glass properties and applications · Perovskite Materials and Applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (46)
Show source-provided references
1. CaB5O7F3: a beryllium-free alkaline-earth fluorooxoborate exhibiting excellent nonlinear optical performances10.1021/acs.inorgchem.8b00531 ↗
2. An efficient green phosphor of Ce3+ and Tb3+-codoped Ba2Lu5B5O17 and a model for elucidating the high thermal stability of the green emission10.1039/C7TC05614A ↗
3. Recent advances in rare earth doped alkali-alkaline earth borates for solid state lighting applications10.1016/j.physb.2017.06.073 ↗
4. An excellent cyan-emitting orthosilicate phosphor for NUV-pumped white LED application10.1039/C7TC04168C ↗
5. Ba9Lu2Si6O24:Ce3+: an efficient green phosphor with high thermal and radiation stability for solid-state lighting10.1002/adom.201500078 ↗
6. Syntheses, thermal stability, and structure determination of the novel isostructural RBa3B9O18 (R = Y, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb)10.1021/ic049710m ↗
7. Phase relations in the Y2O3–BaO–B2O3 system10.1016/S0925-8388(03)00654-6 ↗
8. YBa3B9O18: A promising scintillation crystal10.1021/cg0606141 ↗
9. Ab initio structure determination and photoluminescent properties of an efficient, thermally stable blue phosphor, Ba2Y5B5O17:Ce3+10.1021/acs.chemmater.5b04542 ↗
10. NaBaY(BO3)2:Ce3+,Tb3+: a novel sharp green-emitting phosphor used for WLED and FEDs10.1111/jace.15693 ↗
11. A novel green BaZn2(BO3)2:Eu2+ phosphor for n-UV pumped white light-emitting diodes10.1016/j.jlumin.2017.06.009 ↗
12. Ba3Y2B6O15:Ce3+—a high symmetry, narrow-emitting blue phosphor for wide-gamut white lighting10.1021/acs.chemmater.8b00111 ↗
13. Next-generation narrow-band green-emitting RbLi(Li3SiO4)2:Eu2+ phosphor for backlight display application10.1002/adma.201802489 ↗
14. Learning from a mineral structure toward an ultra-narrow-band blue-emitting silicate phosphor RbNa3(Li3SiO4)4:Eu2+10.1002/anie.201807087 ↗
15. Photoluminescence properties and site-preferable distribution of Ce3+ in Na2Ca1-xSrxSi2O6 (x = 0−1) blue-emitting phosphors10.1016/j.jallcom.2018.06.104 ↗
16. Tunable luminescence of K2MgSi3O8:Ce3+, Tb3+ phosphors through energy transfer10.1016/j.ceramint.2017.11.007 ↗
17. On the photoluminescence of multi-sites Ce3+ in T-phase orthosilicate and energy transfer from Ce3+ to Tb3+10.1016/j.jallcom.2018.03.252 ↗
18. A two-step solid-state reaction to synthesize the yellow persistent Gd3Al2Ga3O12:Ce3+ phosphor with an enhanced optical performance for AC-LEDs10.1039/C7CC05041K ↗
19. Synthesis and photoluminescent properties of high-efficient color-tunable Ba3Y2B6O15:Ce3+, Tb3+ phosphors10.1016/j.ceramint.2018.08.068 ↗
20. Tunable optical properties and increased thermal quenching in the blue-emitting phosphor series: Ba2(Y1–xLux)5B5O17:Ce3+ (x = 0–1)10.1021/acs.chemmater.7b01416 ↗
21. Tunable emission properties of Ca3B2O6:Ce3+ polycrystalline ceramics under ultraviolet light excitation10.1016/j.ceramint.2014.10.166 ↗
22. Effect of temperature on the luminescence and decay behavior of divalent europium in lithium barium borate
23. Unusual Ce3+ luminescence and Ce3+→Tb3+ energy transfer behavior in strontium lithium borate SrLiB9O1510.1016/j.jallcom.2014.04.063 ↗
24. Thermally stable luminescence and energy transfer in Ce3+, Mn2+ doped Sr2Mg(BO3)2 phosphor, Optic
25. Ba3Y2B6O15, a novel cubic borate10.1107/S010827011102052X ↗
26. Narrow-band red-emitting Sr[LiAl3N4]:Eu2+ as a next-generation LED-phosphor material10.1038/nmat4012 ↗
27. EXPGUI, a graphical user interface for GSAS10.1107/S0021889801002242 ↗
28. Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides10.1107/S0567739476001551 ↗
29. Improving quantum efficiency and thermal stability in blue-emitting Ba2–xSrxSiO4:Ce3+ phosphor via solid solution10.1021/acs.chemmater.8b01652 ↗
30. Luminescence and cationic-size-driven site selection of Eu3+ and Ce3+ ions in Ca8Mg(SiO4)4Cl210.1021/acs.inorgchem.8b02639 ↗
31. Site occupancy and VUV–UV–Vis photoluminescence of the lanthanide ions in BaY2Si3O1010.1021/acs.jpcc.8b01118 ↗
32. Blasse · 1994
33. Photoluminescent properties of NaCl:Ce3+ phosphor synthesized using antisolvent crystallization10.1016/j.jlumin.2013.08.062 ↗
34. Optical properties of Ce-doped Li4SrCa(SiO4)2: a combined experimental and theoretical study10.1021/acs.inorgchem.7b02561 ↗
35. Site occupation of Eu2+ in Ba2–xSrxSiO4 (x = 0–1.9) and origin of improved luminescence thermal stability in the intermediate composition10.1021/acs.inorgchem.8b00773 ↗
36. VUV/Vis photoluminescence, site occupancy, and thermal-resistance properties of K4SrSi3O9:Ce3+10.1002/chem.201704373 ↗
37. Structure, site occupancies, and luminescence properties of Ca10M(PO4)7: Ce3+ (M = Li, Na, K) phosphors10.1016/j.jallcom.2018.10.162 ↗
38. Calculation of the energy of the 5d barycenter of La3F3[Si3O9]: Ce3+10.1016/S0022-2313(03)00116-9 ↗
39. 5d-level energies of Ce3+ and the crystalline environment. IV. Aluminates and "simple" oxides10.1016/S0022-2313(02)00347-2 ↗
40. Enhanced luminescent performance for remote LEDs of Ce:YAG phosphor-in-glass film on regular textured glass substrate by using chemical wet-etching10.1016/j.ceramint.2018.08.351 ↗
41. Enhanced photoluminescence property of single-component CaAlSiN3:Ce3+, Eu2+ multicolor phosphor through Ce3+-Eu2+ energy transfer10.1016/j.jallcom.2017.08.168 ↗
42. An efficient blue phosphor Ba2Lu5B5O17:Ce3+ stabilized by La2O3: photoluminescence properties and potential use in white LEDs10.1016/j.dyepig.2018.02.036 ↗
43. Predictability of 5d level positions of the triply ionized lanthanides in halogenides and chalcogenides10.1016/S0022-2313(99)00495-0 ↗
44. The 4fn↔4fn-15d transitions of the trivalent lanthanides in halogenides and chalcogenides10.1016/S0022-2313(00)00197-6 ↗
45. A single-phase Ba9Lu2Si6O24:Eu2+, Ce3+, Mn2+ phosphor with tunable full-color emission for NUV-based white LED applications10.1016/j.materresbull.2016.04.009 ↗
46. Influence of energy transfer by exchange mechanism on donor luminescence10.1063/1.1697063 ↗