High pressure optical studies of LMA:Mn2+, Nd3+ and LMA:Mn2+

Abstract This study considers effects of pressure of up to 110 kbar on line position and fluorescence lifetime τ for 4 T 1 → 6 A 1 transition in LMA:Mn 2+ and LMA:Mn 2+ , Nd 3+ . Energy transfer between Mn 2+ and Nd 3+ in LMA:Mn 2+ , Nd 3+ has also been considered. Results indicate pressure induced line shift towards longer wavelengths, a red-shift in both crystals with the same rate of 0.182 nm kbar −1 . Pressure influences fluorescence lifetime τ in the considered crystals differently; whereas for LMA:Mn 2+ increasing pressure causes slow linear decrease of τ , and for LMA:Mn 2+ , Nd 3+ τ increases linearly as pressure raises. Energy transfer efficiencies decrease with pressure. High pressure induced red-shift can be explained by a simple model.