Corroles Coated Ti₃C₂T_{x} MXene for Gas Sensors

Rahul Suresh Ghuge; Rence P. Reji; Mallikarjuna Swamy Shabanur Matada; SuryaVelappa Jayaraman; Gabriele Magna; Roberto Paolesse; Yuvaraj Sivalingam; Corrado Di Natale

doi:10.1021/acsanm.4c04359

journal article·2024-12-13

Corroles Coated Ti₃C₂T_x MXene for Gas Sensors

Rahul Suresh Ghuge, Rence P. Reji, Mallikarjuna Swamy Shabanur Matada, SuryaVelappa Jayaraman, Gabriele Magna, Roberto Paolesse, Yuvaraj Sivalingam, Corrado Di Natale

ACS Applied Nano Materials· Volume 7· Issue 23

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Source abstract

Abstract

MXenes are promising materials for a wide range of technological applications. In gas sensing, the properties of MXene are often combined with those of organic or inorganic materials to create high-performance sensors. In this study, the combination of corrole molecules and Ti 3 C 2 T x MXene is explored. Corroles, akin to porphyrins, impart chemical sensitivity to MXene, while MXene’s conductivity forms the basis for developing chemiresistors. Previous studies suggest that the chemical sensitivity of corroles is strongly dependent on the metal ion complexed at the core of the macrocycle. Thus, to investigate the role of metal, we utilized a 5,15-tolyl,10-(4-carboxyphenyl)corrole both as a free base and as a hydroxy-Si(IV) complex. Ti 3 C 2 T x MXene coated with silicon corrole and free-base corrole exhibit similar responses to gases, with silicon corrole demonstrating the modulation of the sensitivity respect to the free base molecule. The distinctions between the two corroles are significant enough to distinguish aromatic compounds from other volatile organic compounds (VOCs). These findings suggest that corrole-coated MXene holds promise as a candidate for gas sensor arrays.

Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: MXene and MAX Phase Materials · 2D Materials and Applications · Advanced Photocatalysis Techniques

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Laboratory of Sensors, Energy and Electronic devices (Lab SEED), Department of PhySipCs and Nanotechnology, SRM Institute of Science and Technology, Kattankulathur 603203, Tamil Nadu, India

Novel, Advanced, and Applied Materials (NAAM) Laboratory, Department of PhySipCs and Nanotechnology, SRM Institute of Science and Technology, Kattankulathur 603203, Tamil Nadu, India

New Industry Creation Hatchery Center (NICHe), Tohoku University, Aoba-ku, Sendai 980-8579, Miyagi, Japan

Department of Chemical Science and Technologies, University of Rome Tor Vergata, Via della Ricerca Scientifica, 00133 Rome, Italy

Computer, Electrical and Mathematical Science and Engineering Division (CEMSE), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Kingdom of Saudi Arabia

Department of Electronic Engineering, University of Rome Tor Vergata, Via del Politecnico 1, 00133 Rome, Italy

Funding

Department of Science and Technology, Ministry of Science and Technology, India

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