journal article·2018-05

Addressing the efficiency roll-off in a fluorescent OLED by facile electron transport layer doping and carrier confinement

Anjaly Soman, Manuraj M, K. N. Narayanan Unni

Optical Materials· Volume 79
Publisher page

Abstract

Abstract Organic light emitting diodes (OLEDs) often face the issue of decreasing power efficiency with increasing brightness. Loss of charge carrier balance is one of the factors contributing to the efficiency roll-off. We demonstrate that by using a combination of doped electron transport layer (ETL) and a specially chosen electron blocking layer (EBL) having high hole mobility, this efficiency roll-off can be effectively suppressed. A tris-(8-hydroxyquinoline) aluminium (Alq3) based OLED has been fabricated with 2,3,6,7-Tetrahydro-1,1,7,7,-tetramethyl-1H, 5H,11H-10-(2-benzothiazolyl) quinolizino-[9,9a, 1n gh]coumarin (C545T) as the emissive dopant. Bulk doping of the ETL with lithium fluoride (LiF) was optimized to increase the luminous intensity as well as the current efficiency. An EBL with high hole mobility introduced between the EML and the hole transport layer (HTL) improved the performance drastically, and the device brightness at 9 V got improved by a factor of 2.5 compared to that of the control device. While increasing the brightness from 100 cd/m2 to 1000 cd/m2, the power efficiency drop was 47% for the control device whereas only a drop of 15% was observed for the modified device. The possible mechanisms for the enhanced performance are discussed.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Organic Light-Emitting Diodes Research · Organic Electronics and Photovoltaics · Thin-Film Transistor Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (46)

Show source-provided references
1. Organic electroluminescent diodes10.1063/1.98799 ↗
2. White organic light-emitting devices for solid-state lighting10.1002/adma.200400684 ↗
3. White light-emitting organic electroluminescent devices using the poly(N-vinylcarbazole) emitter layer doped with three fluorescent dyes10.1063/1.111023 ↗
4. Organic electroluminescent devices with improved stability10.1063/1.117151 ↗
5. Electroluminescence of doped organic thin films10.1063/1.343409 ↗
6. Highly efficient phosphorescent emission from organic electroluminescent devices10.1038/25954 ↗
7. Nearly 100% internal phosphorescence efficiency in an organic light-emitting device10.1063/1.1409582 ↗
8. Thermally activated delayed fluorescence from Sn4+–Porphyrin complexes and their application to organic light emitting diodes — a novel mechanism for electroluminescence10.1002/adma.200900983 ↗
9. Highly efficient organic light-emitting diodes from delayed fluorescence10.1038/nature11687 ↗
10. Organic light-emitting diodes employing efficient reverse intersystem crossing for triplet-to-singlet state conversion10.1038/nphoton.2012.31 ↗
11. A review on the light extraction techniques in organic electroluminescent devices10.1016/j.optmat.2009.07.014 ↗
12. Deepak, Effect of the electric field during annealing of organic light emitting diodes for improving its on/off ratio10.1039/C5CP06637A ↗
13. Deepak, Improving the contrast ratio of OLED displays: an analysis of various techniques10.1016/j.optmat.2011.10.005 ↗
14. Charge injection and transport in poly(p-phenylene vinylene) light emitting diodes10.1016/0379-6779(93)90569-I ↗
15. Lithium doping of semiconducting organic charge transport materials10.1063/1.1359161 ↗
16. Highly efficient organic devices based on electrically doped transport layers10.1021/cr050156n ↗
17. Controlled p-doping of zinc phthalocyanine by coevaporation with tetrafluorotetracyanoquinodimethane: a direct and inverse photoemission study10.1063/1.1424067 ↗
18. Lüssem · Doping of organic semiconductors, physica status solidi (a) · 2013 · 210 · 910.1002/pssa.201228310 ↗
19. Leuco crystal violet as a dopant for n-doping of organic thin films of fullerene C6010.1021/jp0478615 ↗
20. Bright organic electroluminescent devices with double-layer cathode10.1109/16.216443 ↗
21. Bipolar transport organic light emitting diodes with enhanced reliability by LiF doping10.1063/1.125904 ↗
22. Interaction between organic semiconductors and LiF dopant10.1063/1.1821653 ↗
23. Photoemission spectroscopy of LiF coated Al and Pt electrodes10.1063/1.369000 ↗
24. Operational stability of electrophosphorescent devices containing p and n doped transport layers10.1063/1.1624473 ↗
25. Dramatic photoluminescence quenching of phenylene vinylene oligomer thin films upon submonolayer Ca deposition10.1063/1.116918 ↗
26. Molecular material-based junctions: formation of a Schottky contact with metallophthalocyanine thin films doped by the cosublimation method10.1063/1.337151 ↗
27. Highly efficient white organic light-emitting diodes based on fluorescent blue emitters10.1063/1.3516481 ↗
28. Influence of charge balance and exciton distribution on efficiency and lifetime of phosphorescent organic light-emitting devices10.1063/1.2951960 ↗
29. Efficiency roll-off in organic light-emitting diodes10.1002/adma.201301603 ↗
30. Measuring the efficiency of organic light-emitting devices10.1002/adma.200302151 ↗
31. LiF as an n-dopant in tris(8-hydroxyquinoline) aluminum thin films10.1002/adma.200701657 ↗
32. Simple accurate system for measuring absolute photoluminescence quantum efficiency in organic solid-state thin films10.1143/JJAP.43.7729 ↗
33. Surface-plasmon-enhanced photoluminescence from metal-capped Alq3 thin Films10.1063/1.3190501 ↗
34. Improved quantum efficiency for electroluminescence in semiconducting polymers10.1038/17087 ↗
35. Lampert · 1970
36. Electron and hole mobility in tris(8-hydroxyquinolinolato-N1,O8) aluminum10.1063/1.113806 ↗
37. Ultralow doping in organic semiconductors: evidence of trap filling10.1103/PhysRevLett.109.176601 ↗
38. Efficient quantum-dot light-emitting diodes with 4,4,4-tris(N-carbazolyl)-triphenylamine (TcTa) electron-blocking layer10.1109/LED.2015.2398850 ↗
39. Comparative Study on Hole Transport inN, N′-bis(naphthalen-1-yl)-N,N′-bis(pheny) Benzidine and 4, 4′, 4"-tri(N-carbazolyl)triphenylamine10.1088/0256-307X/27/8/088504 ↗
40. Carrier conduction mechanism for phosphorescent material doped organic semiconductor10.1063/1.3072693 ↗
41. Enhanced emission efficiency in organic light-emitting diodes using deoxyribonucleic acid complex as an electron blocking layer10.1063/1.2197973 ↗
42. Graded mixed-layer organic light-emitting devices10.1063/1.1446992 ↗
43. Reduced reflectance cathode for organic light-emitting devices using metalorganic mixtures10.1063/1.1591067 ↗
44. Influence of confinement layers in the emitting layer of the blue phosphorescent organic light-emitting diodes10.1016/j.optmat.2016.09.023 ↗
45. Molecular origin of differences in hole and electron mobility in amorphous Alq3-a multiscale simulation study10.1039/c2cp23489k ↗
46. On the use and influence of electron-blocking interlayers in polymer light-emitting diodes10.1039/b819200f ↗