journal article·2021-09

Color tunable up-conversion luminescence characteristics of Yb3+-Er3+-Tm3+ tri-doped fluorosilicate glass potentially used in WLED field

Haozhang Liang, Weicheng Lei, Songxuan Liu, Ping Zhang, Zhiwei Luo, Anxian Lu

Optical Materials· Volume 119
Publisher page

Abstract

Abstract A series of Yb3+-Er3+-Tm3+ tri-doped fluorosilicate glasses with different molar compositions were fabricated by a conventional melt-quenching method. The amorphous nature of glasses was confirmed by XRD. The structure of the glass network was characterized by FTIR and Raman scattering spectra. The absorption spectra were measured by a UV–vis–NIR spectrophotometer. Under the excitation of a 980 nm laser, as-prepared glass can emit intense red, green, and blue light in the emission spectra. And the warm-white emission (0.3569, 0.3953) can be generated at the glass sample SACF-Tm0.40. Finally, according to the up-conversion emission spectra recorded under 980 nm laser with different pump power conditions, a three-photon absorption process in the glass sample SACF-Tm0.50 was determined. And the energy transfer process in Yb3+-Er3+-Tm3+ tri-doped up-conversion luminescence system was discussed in detail.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Glass properties and applications · Solid State Laser Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (35)

Show source-provided references
1. Enhanced luminescence properties of Ho/Yb ions regulated by the nanocrystalline environment and phonon energy in silicate glasses10.1016/j.jlumin.2019.116949 ↗
2. Tungsten sodium phosphate glasses doped with trivalent rare earth ions (Eu3+, Tb3+, Nd3+ and Er3+) for visible and near-infrared applications10.1016/j.jnoncrysol.2019.119838 ↗
3. Upconversion and anti-Stokes processes with f and d ions in solids10.1021/cr020357g ↗
4. Towards high-power mid-infrared emission from a fibre laser10.1038/nphoton.2012.149 ↗
5. Structure and fluorescence properties of ternary aluminosilicate glasses doped with samarium and europium10.1039/C4TC00036F ↗
6. Phosphor in glass with Eu3+ and Pr3+-doped silicate glasses for LED color conversion10.1016/j.optmat.2014.08.017 ↗
7. Er3+-Yb3+ co-doped silicate glass for optical temperature sensor10.1016/j.cplett.2007.06.081 ↗
8. Structural and optical study of silicate glasses for nonlinear optical devices10.1016/0022-3093(89)90469-9 ↗
9. Spectral properties of erbium-doped oxyfluoride silicate glasses for broadband optical amplifiers10.1088/0256-307X/20/6/336 ↗
10. The spectroscopic and energy transfer characteristics of the rare earth ions used for silicate glass fibre lasers operating in the shortwave infrared10.1002/lpor.200810058 ↗
11. Intense upconversion luminescence and effect of local environment for Tm3+/Yb3+ co-doped novel TeO2–BiCl3 glass system10.1016/j.saa.2005.07.030 ↗
12. The influence of F--ion doping on the fluorescence (4I13/2→4I15/2) line shape broadening in Er3+-doped oxyfluoride silicate glasses10.1016/j.optmat.2003.08.006 ↗
13. Electronic energy levels in the trivalent lanthanide aquo ions. I. Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, and Tm3+10.1063/1.1669893 ↗
14. Optical characterization and electronic energy‐level structure of Er3+‐doped CsCdBr310.1063/1.472850 ↗
15. Luminescence processes in Tm3+‐and Er3+‐ion‐activated, Yb3+‐ion‐sensitized infrared upconversion devices10.1063/1.354337 ↗
16. Color-tunable emission by adjusting sensitizer (Yb3+) and excitation power of 980 nm in NaGdTiO4: Yb3+/Tm3+/Er3+ phosphors for light emitting diodes10.1016/j.jlumin.2017.09.055 ↗
17. White up-conversion efficiency of Yb3+/Er3+/Tm3+ co-doped β-NaYF4 nano-crystals
18. White light generation via up-conversion and blue tone in Er3+/Tm3+/Yb3+ -doped zinc-tellurite glasses10.1016/j.optmat.2017.03.028 ↗
19. Growth, spectroscopy, and stimulated emission of cubic Bi4Ge3O12 crystals doped with Dy3+, Ho3+, Er3+, Tm3+, or Yb3+ ions10.1002/pssa.2210560240 ↗
20. Application of infrared spectroscopy to studies of silicate glass structure: examples from the melilite glasses and the systems Na2O-SiO2 and Na2O-Al2O3-SiO2
21. High-quartz solid-solution phases from xerogels with composition 2MgO·2Al2O3·5SiO2 (μ-cordierite) and Li2O·Al2O3·nSiO2 (n = 2 to 4)(β-eucryptite): characterization by XRD, FTIR and surface measurements10.1016/0955-2219(93)90029-Q ↗
22. The preparation and thermal evolution of polymeric gels with garnet stoichiometry in the CaO-Al2O3-SiO2 and CaO-Cr2O3-SiO2 systems10.1016/0955-2219(90)90042-E ↗
23. Crystallization, structure and properties of MgO-Al2O3-SiO2 highly crystalline transparent glass-ceramics nucleated by multiple nucleating agents10.1016/j.jeurceramsoc.2018.05.025 ↗
24. Network connectivity and properties of non-alkali aluminoborosilicate glasses10.1016/j.jnoncrysol.2017.11.023 ↗
25. In-situ high-temperature Raman-spectroscopic studies of aluminosilicate liquids10.1007/BF00202467 ↗
26. The oxidation state of sulfur detected in Na2O-CaO-SiO2 float glass by X-ray absorption near edge structure spectra10.1007/s11595-013-0644-2 ↗
27. Spectral analysis of Er3+-, Er3+/Yb3+-and Er3+/Tm3+/Yb3+-doped TeO2–ZnO–WO3–TiO2–Na2O glasses10.1088/0953-8984/20/37/375101 ↗
28. Multicolor upconversion of Er3+/Tm3+/Yb3+ doped oxyfluoride glass ceramics10.1016/j.matlet.2006.08.049 ↗
29. Lanthanide-doped NaYF4 nanocrystals in aqueous solution displaying strong upconversion emission10.1021/cm062385b ↗
30. High up-conversion efficiency of YVO4:Yb,Er nanoparticles in water down to the single-particle level10.1021/jp107900z ↗
31. Power dependence of upconversion luminescence in lanthanide and transition-metal-ion systems10.1103/PhysRevB.61.3337 ↗
32. Up-conversion luminescence of Tm3+/Yb3+ co-doped oxy-fluoride glasses10.1016/S1002-0721(09)60079-X ↗
33. Study on optical properties and upconversion luminescence of Er3+/Yb3+ co-doped tellurite glass for highly sensitive temperature measuring10.1364/OME.7.003238 ↗
34. Three-photon phenomena in the upconversion luminescence of erbium-ytterbium-codoped phosphate glass10.1063/1.1404996 ↗
35. Up-conversion, energy transfer and CIE analysis of Er3+/Tm3+: MCZBP glasses10.1016/j.ijleo.2021.167324 ↗