journal article·2023-06

Synthesis, characterization and evaluation of porous carbon adsorbents derived from waste biomass for CO2 capture

Dosali Mallesh, Shobanaboyina Swapna, Paka Rajitha, Yarasi Soujanya, Chenna Sumana, Nakka Lingaiah

Carbon Letters· Volume 33· Issue 4
Publisher page

Abstract

In this work, subabul wood biomass was used to prepare carbon adsorbents by physical and chemical activation methods at various carbonization temperatures. The properties of the carbon adsorbents were estimated through characterization techniques such as X-ray diffraction, Fourier transform infrared spectroscopy, X–ray photo electron spectroscopy, laser Raman spectroscopy, scanning electron microscopy, CHNS-elemental analysis and N2 adsorption studies. Subabul-derived carbon adsorbents were used for CO2 capture in the temperature range of 25–70 °C. A detailed adsorption kinetic study was also carried out. The characterization results indicated that these carbons contain high surface area with microporosity. Surface properties were depended on treatment method and carbonization temperature. Among the carbons, the carbon prepared after treatment of H3PO4 and carbonization at 800 °C exhibited high adsorption capacity of 4.52 m.mol/g at 25 °C. The reason for high adsorption capacity of the adsorbents was explained based on their physicochemical characteristics. The adsorbents showed easy desorption and recyclability up to ten cycle with consistent activity.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Carbon Dioxide Capture Technologies · Phase Equilibria and Thermodynamics · Membrane Separation and Gas Transport

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (79)

Show source-provided references
1. Nurrokhmah L, Mezher T, Zahra A (2013) Evaluation of handling and reuse approaches for the waste generated from MEA-based CO2 capture with the consideration of regulations in the UAE. Environ Sci Technol 47:13644–13651. https://doi.org/10.1021/es402719810.1021/es4027198 ↗
2. Rochelle GT (2009) Amine scrubbing for CO2 capture. Science 325:1652–1654. https://doi.org/10.1126/science.117673110.1126/science.1176731 ↗
3. Siriwardane RV, Shen MS, Fisher EP, Poston JA (2010) Adsorption of CO2 on molecular sieves and activated carbon. Energy Fuels 15:279–284. https://doi.org/10.1021/ef000241s10.1021/ef000241s ↗
4. Heo YJ, Park SJ (2018) H2O2/steam activation as an eco-friendly and efficient top-down approach to enhancing porosity on carbonaceous materials: the effect of inevitable oxygen functionalities on CO2 capture. Green Chem 20:5224–5234. https://doi.org/10.1039/C8GC02570C10.1039/C8GC02570C ↗
5. Plaza MG, Pevida C, Arenillas A, Rubiera F, Pis JJ (2007) CO2 capture by adsorption with nitrogen enriched carbons. Fuel 86:2204–2212. https://doi.org/10.1016/j.fuel.2007.06.00110.1016/j.fuel.2007.06.001 ↗
6. Little RJ, Versteeg GF, Swaaij WPM (1991) Physical absorption into non-aqueous solutions in a stirred cell reactor. Chem Eng Sci 46:3308–3313. https://doi.org/10.1016/0009-2509(91)85036-W10.1016/0009-2509(91)85036-W ↗
7. Chiesa P, Consonni SP, Eng J (1999) Shift reactors and physical absorption for low-CO2 emission IGCCs. Gas Turbines Power 121:295–305. https://doi.org/10.1115/1.281712010.1115/1.2817120 ↗
8. Aroonwilas A, Veawab A (2004) Characterization and comparison of the CO2 absorption performance into single and blended alkanolamines in a packed column. Ind Eng Chem Res 43:2228–2237. https://doi.org/10.1021/ie030606710.1021/ie0306067 ↗
9. Bishnoi S, Rochelle GT (2000) Absorption of carbon dioxide into aqueous piperazine: reaction kinetics, mass transfer and solubility. Chem Eng Sci 55:5531–5543. https://doi.org/10.1016/S0009-2509(00)00182-210.1016/S0009-2509(00)00182-2 ↗
10. Wei H, Chen J, Fu N, Chen H, Lin H, Han S (2018) Biomass-derived nitrogen-doped porous carbon with superior capacitive performance and high CO2 capture capacity. Electrochim Acta 266:161–169. https://doi.org/10.1016/j.electacta.2017.12.19210.1016/j.electacta.2017.12.192 ↗
11. Harlick PJE, Tezel FH (2004) An experimental adsorbent screening study for CO2 removal from N2. Microporous Mesoporous Mater 76:71–79. https://doi.org/10.1016/j.micromeso.2004.07.03510.1016/j.micromeso.2004.07.035 ↗
12. Chang FY, Chao KJ, Cheng HH, Tan CS (2009) Adsorption of CO2 onto amine-grafted mesoporous silicas. Sep Purif Technol 70:87–95. https://doi.org/10.1016/j.seppur.2009.08.01610.1016/j.seppur.2009.08.016 ↗
13. Shahkarami S, Dalai AK, Soltan J (2016) Enhanced CO2 adsorption using MgO-impregnated activated carbon: impact of preparation techniques. Ind Eng Chem Res 55:5955–5964. https://doi.org/10.1021/acs.iecr.5b0482410.1021/acs.iecr.5b04824 ↗
14. Zukal A, Dominguez I, Mayerova J, Cejka J (2009) Functionalization of delaminated zeolite ITQ-6 for the adsorption of carbon dioxide. Langmuir 25:10314–10321. https://doi.org/10.1021/la901156z10.1021/la901156z ↗
15. Boehm HP (1994) Some aspects of the surface chemistry of carbon blacks and other carbons. Carbon 32:759–769. https://doi.org/10.1016/0008-6223(94)90031-010.1016/0008-6223(94)90031-0 ↗
16. Shuren Y, Ding Z, Zhiyong Z, Hai L, Guangjin C, Bei L (2019) A pilot-scale experimental study on CO2 capture using Zeolitic imidazolate framework-8 slurry under normal pressure. Appl Energy 248:104–114. https://doi.org/10.1016/j.apenergy.2019.04.09710.1016/j.apenergy.2019.04.097 ↗
17. Morris W, Leung B, Furukawa H, Yaghi OK, He N, Hayashi H (2011) A Combined experimental-computational investigation of carbon dioxide capture in a series of Isoreticular Zeolitic Imidazolate frameworks. J Am Chem Soc 132:11006–11008. https://doi.org/10.1021/ja104035j10.1021/ja104035j ↗
18. Sevilla M, Valle-Vigon P, Fuertes AB (2011) N-Doped polypyrrole-based porous carbons for CO2 capture. Adv Funct Mater 21:2781–2787. https://doi.org/10.1002/adfm.20110029110.1002/adfm.201100291 ↗
19. Vassilev SV, Vassileva CG (2019) Extra CO2 capture and storage by carbonation of biomass ashes. Energ Convers Manage 204:112331. https://doi.org/10.1016/j.enconman.2019.11233110.1016/j.enconman.2019.112331 ↗
20. Farha OK, Hupp JT (2010) Rational design, synthesis, purification, and activation of metal-organic framework materials. Acc Chem Res 43:1166–1175. https://doi.org/10.1021/ar100061710.1021/ar1000617 ↗
21. Dalai SS, AK, Soltan J, Hu Y, Wang D, (2015) Selective CO2 capture by activated carbons: evaluation of the effects of precursors and pyrolysis process. Energy Fuels 29:7433–7440. https://doi.org/10.1021/acs.energyfuels.5b0047010.1021/acs.energyfuels.5b00470 ↗
22. Lua AC, Guo J (2001) Preparation and characterization of activated carbons from oil-palm stones for gas-phase adsorption. Colloids Surf A 179:151–162. https://doi.org/10.1016/S0927-7757(00)00651-810.1016/S0927-7757(00)00651-8 ↗
23. Plaza MG, Gonzalez AS, Pevida CJ, Pis J (2012) Valorisation of spent coffee grounds as CO2 adsorbents for post combustion capture applications. Appl Energy 99:272–279. https://doi.org/10.1016/j.apenergy.2012.05.02810.1016/j.apenergy.2012.05.028 ↗
24. Boonamnuayvitaya V, Sae-ung S, Tanthapanichakoon W (2005) Preparation of activated carbons from coffee residue for the adsorption of formaldehyde. Sep Purif Technol 42:159–168. https://doi.org/10.1016/j.seppur.2004.07.00710.1016/j.seppur.2004.07.007 ↗
25. Eunji J, Seung W, Choi W, Seok-Min H, Shin S, Lee K (2018) Development of a cost-effective CO2 adsorbent from petroleum coke via KOH activation. Appl Surf Sci 429:62–71. https://doi.org/10.1016/j.apsusc.2017.08.07510.1016/j.apsusc.2017.08.075 ↗
26. Liou TH (2010) Development of mesoporous structure and high adsorption capacity of biomass-based activated carbon by phosphoric acid and zinc chloride activation. Chem Eng J 158:129–142. https://doi.org/10.1016/j.cej.2009.12.01610.1016/j.cej.2009.12.016 ↗
27. Ding S, Liu Y (2020) Adsorption of CO2 from flue gas by novel seaweed-based KOH activated porous biochars. Fuel 260:116382. https://doi.org/10.1016/j.fuel.2019.11638210.1016/j.fuel.2019.116382 ↗
28. Huang GG, Liu YF, Wu XX, Cai JJ (2019) Activated carbons prepared by the KOH activation of a hydrochar from garlic peel and their CO2 adsorption performance. New Carbon Mater 34:247–257. https://doi.org/10.1016/S1872-5805(19)60014-410.1016/S1872-5805(19)60014-4 ↗
29. Al-Wabel M, Elfaki J, Usman A, Hussain Q (2009) Performance of dry water- and porous carbon-based sorbents for carbon dioxide capture. Environ Res 174:69–79. https://doi.org/10.1016/j.envres.2019.04.02010.1016/j.envres.2019.04.020 ↗
30. Dias JM, Alvim-Ferraz CM, Almeida MF, Sanchez-Polo JM (2007) Waste materials for activated carbon preparation and its use in aqueous-phase treatment: A review. J Environ Manag 85:833–846. https://doi.org/10.1016/j.jenvman.2007.07.03110.1016/j.jenvman.2007.07.031 ↗
31. Khuong DA, Nguyen HN, Tsubota T (2021) Activated carbon produced from bamboo and solid residue by CO2 activation utilized as CO2 adsorbents. Biomass Bioenergy 148:106039. https://doi.org/10.1016/j.biombioe.2021.10603910.1016/j.biombioe.2021.106039 ↗
32. Yang J, Yue L, Hu X, Wang L, Zhao Y, Lin Y, Guo L (2017) Efficient CO2 capture by porous carbons derived from coconut shell. Energy Fuels 31:4287–4293. https://doi.org/10.1021/acs.energyfuels.7b00610.1021/acs.energyfuels.7b006 ↗
33. Wu R, Ye Q, Wu K, Wang L, Dai H (2021) Highly efficient CO2 adsorption of corn kernel-derived porous carbon with abundant oxygen functional groups. J CO2 Util 51:101620. https://doi.org/10.1016/j.jcou.2021.10162010.1016/j.jcou.2021.101620 ↗
34. Ismail IS, Rashidi NA, Yusup S (2021) Production and characterization of bamboo-based activated carbon through single-step H3PO4 activation for CO2 capture. Environ Sci Pollut Res 29:12434–12440. https://doi.org/10.1007/s11356-021-15030-x10.1007/s11356-021-15030-x ↗
35. Yan M, Zhou Z, Zheng R, Jiang J, Feng H, Yu C, Zhu G, Hantoko D (2021) Low-temperature sintering behavior of fly ash from hazardous waste incinerator: Effect of temperature and oxygen on ash properties. J Environ Chem Eng 9:105261. https://doi.org/10.1016/j.jece.2021.10526110.1016/j.jece.2021.105261 ↗
36. Hughes C, (1998) Monograph of Leucaena (Leguminosae-Mimosoideae), Systematic botany monographs, 55:1–5.ISBN 978–0–912861–55–510.2307/25027876 ↗
37. Mallesh D, Anbarasan J, Mahesh Kumar P, Upendar K, Chandrashekar P, Rao BVSK, Lingaiah N (2020) Synthesis, characterization of carbon adsorbents derived from waste biomass and its application to CO2 capture. Appl Surf Sci 530:147226–147232. https://doi.org/10.1016/j.apsusc.2020.14722610.1016/j.apsusc.2020.147226 ↗
38. Kumar A, Mohan Jena H (2016) Preparation and characterization of high surface area activated carbon from Fox nut (Euryale ferox) shell by chemical activation with H3PO4. Results Phys 6:651–658. https://doi.org/10.1016/j.rinp.2016.09.01210.1016/j.rinp.2016.09.012 ↗
39. Juarez-Galan J, Silvestre-Albero MA, Silvestre-Albero J, Rodríguez-Reinoso F (2009) Synthesis of activated carbon with highly developed ‘‘mesoporosity”. Microporous Mesoporous Mater 117:519–521. https://doi.org/10.1016/j.micromeso.2008.06.01110.1016/j.micromeso.2008.06.011 ↗
40. Beckert M, Menzel M, Tolle FJ, Bruchmann B, Mulhaupt R (2015) Nitrogenated graphene and carbon nanomaterials by carbonization of polyfurfuryl alcohol in the presence of urea and dicyandiamide. Green Chem 17:1032–1037. https://doi.org/10.1039/C4GC01676A10.1039/C4GC01676A ↗
41. Hong K, Qie L, Zeng R, Yi Z, Zhang W, Wang D, Yin W, Wu C, Fan Q, Huang WXY (2014) Biomass derived hard carbon used as a high performance anode material for sodium ion batteries. J Mater Chem A 32:12733–12738. https://doi.org/10.1039/C4TA02068E10.1039/C4TA02068E ↗
42. Singh G, Lakhi SK, Ramadass KCI, Vinu A (2019) High-performance biomass-derived activated porous biocarbons for combined pre- and post-combustion CO2 capture, ACS sustainable. Chem Eng 7:7412–7420. https://doi.org/10.1021/acssuschemeng.9b0092110.1021/acssuschemeng.9b00921 ↗
43. Datsyuk V, Papagelis K, Parthenios J, Tasis D, Siokou A, Kallitsis I, Galiotisa C (2018) Chemical oxidation of multiwalled carbon nanotubes. Carbon 46:833–840. https://doi.org/10.1016/j.carbon.2008.02.01210.1016/j.carbon.2008.02.012 ↗
44. Padmakar D, Surendar M, Chandrashekar P, Lingaiah N (2020) A highly stable and efficient Co–Mg–Sr mixed oxide catalysts for hydrogen production from glycerol steam reforming. Catal Lett 150:2734–2743. https://doi.org/10.1007/s10562-020-03181410.1007/s10562-020-031814 ↗
45. Li J, Michalkiewicz B, Min J, Ma C, Chen X, Gong J, Mijowsk E, Tang T (2019) Selective preparation of biomass-derived porous carbon with controllable pore sizes toward highly efficient CO2 capture. Chem Eng J 360:250–259. https://doi.org/10.1016/j.cej.2018.11.20410.1016/j.cej.2018.11.204 ↗
46. Li D, Zhou J, Wang Y, Tian Y, Wei L, Zhang Z, Qiao Y, Li J (2019) Effects of activation temperature on densities and volumetric CO2 adsorption performance of alkali-activated carbons. Fuel 238:232–239. https://doi.org/10.1016/j.fuel.2018.10.12210.1016/j.fuel.2018.10.122 ↗
47. Basu S, Ghosh G, Saha S (2018) Adsorption characteristics of phosphoric acid induced activation of bio-carbon: Equilibrium, kinetics, thermodynamics and batch adsorber design, Process Saf. Environ Prot 117:125–142. https://doi.org/10.1016/j.psep.2018.04.01510.1016/j.psep.2018.04.015 ↗
48. Michele LB, Patrícia P, Janaína J, Daniele P, Aline D, Marcelo G (2017) Preparation and characterization of a metal-rich activated carbon from CCA-treated wood for CO2 capture. Chem Eng J 321:614–621. https://doi.org/10.1016/j.cej.2017.04.00410.1016/j.cej.2017.04.004 ↗
49. Kim DG, Tae-Hoon K, Seok-Oh K (2022) Enhanced catalytic activity of a coal-based powdered activated carbon by thermal treatment. Water 14:3308–3320. https://doi.org/10.3390/w1420330810.3390/w14203308 ↗
50. Kaur B, Gupta RK, Bhunia H (2019) Chemically activated nanoporous carbon adsorbents from waste plastic for CO2 capture: Breakthrough adsorption study. Microporous Mesoporous Mater 282:146–158. https://doi.org/10.1016/j.micromeso.2019.03.02510.1016/j.micromeso.2019.03.025 ↗
51. Sivaraman B, Raja Sekhar BN, Nair BG, Hatode V, Mason NJ (2013) Infrared spectrum of formamide in the solid phase. Spectrochim Acta A Mol Biomol Spectrosc 105:238–244. https://doi.org/10.1016/j.saa.2012.12.03910.1016/j.saa.2012.12.039 ↗
52. Singh G, Lakhi KS, Sil S, Bhosale SV, Kim IY, Albahily K, Vinu A (2019) Biomass derived porous carbon for CO2 capture. Carbon 148:164–186. https://doi.org/10.1016/j.carbon.2019.03.05010.1016/j.carbon.2019.03.050 ↗
53. Jang E, Wan Choi S, Hong SM, Shin S, Lee KB (2018) Development of a cost-effective CO2 adsorbent from petroleum coke via KOH activation. Appl Surf Sci 429:62–71. https://doi.org/10.1016/j.apsusc.2017.08.07510.1016/j.apsusc.2017.08.075 ↗
54. Fierro V et al (2006) Kraft lignin as a precursor for microporous activated carbons prepared by impregnation with ortho-phosphoric acid: Synthesis and textural characterization. Microporous Mesoporous Mater 92:243–250. https://doi.org/10.1016/j.micromeso.2006.01.01310.1016/j.micromeso.2006.01.013 ↗
55. Li J, Michalkiewicz B, Min J, Ma C, Chen X, Gong J, Mijowska E, Tang T (2019) Selective preparation of biomass-derived porous carbon with controllable pore sizes toward highly efficient CO2 capture. Chem Eng J 360:250–259. https://doi.org/10.1016/j.cej.2018.11.20410.1016/j.cej.2018.11.204 ↗
56. Basu S, Ghosh G (2018) Adsorption characteristics of phosphoric acid induced activation of bio-carbon: equilibrium, kinetics, thermodynamics and batch adsorber design. Process Saf Environ 117(2018):125–142. https://doi.org/10.1016/j.psep.2018.04.01510.1016/j.psep.2018.04.015 ↗
57. Singh G, Ramadass K, Lee JM, Ismail IS, Singh M, Bansal V, Yang JH, Vinu A (2019) Convenient design of porous and heteroatom self-doped carbons for CO2 capture. Microporous Mesoporous Mater 287:1–8. https://doi.org/10.1016/j.micromeso.2019.05.04210.1016/j.micromeso.2019.05.042 ↗
58. Chiang YC, Juang RS (2017) Surface modifications of carbonaceous materials for carbon dioxide adsorption: A review. J Taiwan Inst Chem Eng 71:214–234. https://doi.org/10.1016/j.jtice.2016.12.01410.1016/j.jtice.2016.12.014 ↗
59. Prahas D, Kartika Y, Indraswati N, Ismadji S (2008) Activated carbon from jackfruit peel waste by H3PO4 chemical activation: Pore structure and surface chemistry characterization. Chem Eng J 140:32–42. https://doi.org/10.1016/j.cej.2007.08.03210.1016/j.cej.2007.08.032 ↗
60. Nilantha P, Mietek J (2013) Importance of small micropores in CO2 capture by phenolic resin-based activated carbon spheres. J Mater Chem A 1:112–116. https://doi.org/10.1039/c2ta00388k10.1039/c2ta00388k ↗
61. Silvestre-Albero J, Wahby A, Sepulveda-Escribano A, Martinez-Escandell M, Kaneko K, Rodriguez-Reinoso F (2011) Ultrahigh CO2 adsorption capacity on carbon molecular sieves at room temperature. Chem Commun 47:6840–6842. https://doi.org/10.1039/C1CC11618E10.1039/C1CC11618E ↗
62. Sevilla M, Antonio Fuerte B (2011) Sustainable porous carbons with a superior performance for CO2 capture, energy environ. Sci 4:1765–1771. https://doi.org/10.1039/C0EE00784F10.1039/C0EE00784F ↗
63. Wahby A, Ramos-Fernandez JM, Martinez-Escandell MA, Sepulveda-Escribano J, Silvestre-Albero F (2010) High-surface-area carbon molecular sieves for selective CO2 adsorption. Chemsuschem 3:974–981. https://doi.org/10.1002/cssc.20100008310.1002/cssc.201000083 ↗
64. Zhanga S, Zhoua Q, Jianga X, Yaoa L, Jianga W, Xiea R (2019) Preparation and evaluation of nitrogen-tailored hierarchical meso-/micro-porous activated carbon for CO2 adsorption. Environ Technol 41:3544–3553. https://doi.org/10.1080/09593330.2019.161513110.1080/09593330.2019.1615131 ↗
65. Wei H, Deng S, Hu B, Chen Z, Wang B, Huang J, Yu G (2012) Granular bambooderived activated carbon for high CO2 adsorption: the dominant role of narrow micropores. Chemsuschem 5:2354–2360. https://doi.org/10.1016/j.cej.2015.07.05510.1016/j.cej.2015.07.055 ↗
66. Turkan K (2021) Hydrogen storage characteristics of bio-based porous carbons of different origin: a comparative review. Int J Energy Res. https://doi.org/10.1002/er.713010.1002/er.7130 ↗
67. Turkan K, Sefa K (2010) Sulfur dioxide adsorption isotherms and breakthrough analysis on molecular sieve 5A zeolite. Chem Eng Commun 190:1041–1054. https://doi.org/10.1080/0098644030210310.1080/00986440302103 ↗
68. Wei H, Deng S, Hu B, Chen Z, Wang B, Huang J, Yu G (2012) Granular bamboo-derived activated carbon for high CO2 adsorption: the dominant role of narrow micropores. Chemsuschem 5:2354–2360. https://doi.org/10.1002/cssc.20120057010.1002/cssc.201200570 ↗
69. Sevilla M, Falco C, Titirici MM, Fuertes AB (2012) High-performance CO2 sorbents from algae. RSC Adv 2:12792–12797. https://doi.org/10.1039/c2ra22552b10.1039/c2ra22552b ↗
70. Diez N, Alvarez P, Granda M, Blanco C, Santamaria R (2015) N-enriched ACF from coal-based pitch blended with urea-based resin for CO2 capture. Microporous Mesoporous Mater 201:10–16. https://doi.org/10.1016/j.micromeso.2014.08.05410.1016/j.micromeso.2014.08.054 ↗
71. Ismail S, Singh G, Smith P, Kim S, Joseph YJH, S, Yusup S, Singh M, Siddulu VB, Talapaneni N, Vinu A, (2020) Oxygen functionalized porous activated biocarbons with high surface area derived from grape marc for enhanced capture of CO2 at elevated pressure. Carbon 160:113–124. https://doi.org/10.1016/j.carbon.2020.01.00810.1016/j.carbon.2020.01.008 ↗
72. Mutyala S, Jonnalagadda M, Mitta H, Gundeboyina R (2019) CO2 capture and adsorption kinetic study of amine-modified MIL-101 (Cr). Chem Eng Res Des 143:241–248. https://doi.org/10.1016/j.cherd.2019.01.02010.1016/j.cherd.2019.01.020 ↗
73. Wang J, Li M, Lu P, Ning P, Wang Q (2020) Kinetic study of CO2 capture on ternary nitrates modified MgO with different precursor and morphology. Chem Eng J 39:123752. https://doi.org/10.1016/j.cej.2019.12375210.1016/j.cej.2019.123752 ↗
74. Ello AS, de souza L.K.C., Trokourey A, Jaroniec M, (2013) Coconut shell-based microporous carbons for CO2 capture. Microporous Mesoporous Mater 180:280–283. https://doi.org/10.1016/j.micromeso.2013.07.00810.1016/j.micromeso.2013.07.008 ↗
75. Nelson KM, Mahurin SM, Mayes RT, Williamson B, Teague CM, Binder AJ, Baggetto L, Veith GM, Dai S (2016) Preparation and CO2 adsorption properties of soft-templated mesoporous carbons derived from chestnut tannin precursors. Microporous Mesoporous Mater 222:94–103. https://doi.org/10.1016/j.micromeso.2015.09.05010.1016/j.micromeso.2015.09.050 ↗
76. Li D, Tian Y, Li L, Li J, Zhang H (2015) Production of highly microporous carbons with large CO2 uptakes at atmospheric pressure by KOH activation of peanut shell char. Porous Mater 22:1581–1588. https://doi.org/10.1007/s10934-015-0041-710.1007/s10934-015-0041-7 ↗
77. Gonzalez A, Plaza M, Rubiera F, Pevida C (2013) Sustainable biomass-based carbon adsorbents for post-combustion CO2 capture. Chem Eng J 230:456–465. https://doi.org/10.1016/j.cej.2013.06.11810.1016/j.cej.2013.06.118 ↗
78. Ello AS, De Souza LK, Trokourey A, Jaroniec M (2013) Development of microporous carbons for CO2 capture by KOH activation of African palm shells. J CO2 Util 2:35–38. https://doi.org/10.1016/j.jcou.2013.07.00310.1016/j.jcou.2013.07.003 ↗
79. Singh G, Kim IY, Lakhi KS, Srivastava P, Naidu R, Vinu A (2017) Single step synthesis of activated bio-carbons with a high surface area and their excellent CO2 adsorption capacity. Carbon 116:448–455. https://doi.org/10.1016/j.carbon.2017.02.01510.1016/j.carbon.2017.02.015 ↗