journal article·2020-11

A novel borosilicate glass based PiGs for WLEDs with tunable interface defects and high anti-thermal quenching power

Lu Chen, Fang Lei, Haohong Chen, Luqiao Yin, Ding Zhou, Ying Shi, Teng Ma

Optical Materials· Volume 109
Publisher page

Abstract

Abstract A novel Eu3+ doped SiO2-B2O3-Al2O3-CaO-Na2O based borosilicate glass was designed to embed YAG: Ce for PiGs. It exhibits intense Eu3+ red emission with the average decay times of 6.8 μs and has the thermal conductivity of about 0.9 W/(mK) (five times that of silicone resin). The doped Eu3+ is over 10 mol% without any concentration quenching. The PiGs show variable decay time of Ce3+, which results from the tunable interface defects explained by the pseudo-solid solubility mechanism. The color of the WLEDs changes from cool white (6004 K) to warm white (3799 K) with more yellow emission added. The obtained maximal luminous efficiency and color rendering index are about 68 lm/W and 78, respectively. The anti-thermal quenching power of the PiGs is three times that of PiS based on the luminescent reduction. The PiG system can be used potentially for resin-free high power WLEDs.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Glass properties and applications · Solid State Laser Technologies

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (38)

Show source-provided references
1. Phosphor in glass with Eu3+ and Pr3+-doped silicate glasses for LED color conversion10.1016/j.optmat.2014.08.017 ↗
2. Properties of transparent Ce:YAG ceramic phosphors for white LED10.1016/j.optmat.2010.06.005 ↗
3. Phosphor-in-glass for high-powered remote-type white AC-LED10.1021/am506251z ↗
4. Control of chromaticity by phosphor in glasses with low temperature sintered silicate glasses for LED applications10.1364/OL.39.004084 ↗
5. Chromaticity-tunable phosphor-in-glass for long-lifetime high-power warm w-LEDs10.1039/C5TC01057H ↗
6. Optical properties of zinc borate glasses dispersed with Eu-doped SiAlON for white LED applications10.1016/j.ceramint.2017.12.063 ↗
7. Erosion mechanism of YAG: Ce3+ phosphor in bismuth borate glasses10.1016/j.ceramint.2017.09.109 ↗
8. All-inorganic light convertor based on phosphor-in-glass engineering for next-generation modular high-brightness white LEDs/LDs10.1021/acsphotonics.7b00049 ↗
9. Luminescence and energy transfer in Dy3+/Eu3+ co-doped aluminosilicate oxyfluoride glasses and glass-ceramics10.1016/j.jallcom.2017.11.077 ↗
10. Glass ceramic phosphors: towards long-lifetime high-power white light-emitting-diode applications-A review10.1002/lpor.201700344 ↗
11. Purification of Ce3+ yellow-fluorescence in UV-pumped Y3Al5O12-tellurite phosphor-in-glass10.1016/j.optmat.2019.109372 ↗
12. Tunable chromaticity and enhanced luminous efficacy of white LEDs with phosphor-in-glass coating via multilayer screen-printing10.1016/j.ceramint.2017.07.065 ↗
13. Erosion behavior and luminescence properties of Y3Al5O12: Ce3+-embedded calcium bismuth borate glass-ceramics for WLEDs10.1111/jace.16062 ↗
14. Facile fabrication of Eu3+ activated YAG: Ce3+ glass ceramics exhibiting high thermal stability and tunable luminescence for warm white LEDs10.1007/s10854-017-6585-3 ↗
15. Facile preparation and ultrastable performance of single-component white-light-emitting phosphor-in-glass used for high-power warm white LEDs10.1021/acsami.5b09739 ↗
16. Improved color rendering index and thermal stability of white LEDs with phosphor-in-glass using the SiO2-B2O3-ZnO-Na2O glass system10.1016/j.jnoncrysol.2016.05.011 ↗
17. Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs10.1039/C7TC04196A ↗
18. New Eu3+-activated perovskite La0.5Na0.5TiO3 phosphors in glass for warm white light emitting diodes10.1039/C5DT04909A ↗
19. Non-rare-earth BaMgAl10–2xO17:xMn4+,xMg2+: a narrow-band red phosphor for use as a high-power warm w-LED10.1021/acs.chemmater.6b01303 ↗
20. A low sintering temperature glass based on SiO2-P2O5-ZnO-B2O3-R2O system for white LEDs with high color rendering index10.1111/jace.15043 ↗
21. Radio-photoluminescence observed in Eu-doped BABF glass-ceramics10.1016/j.ceramint.2018.08.027 ↗
22. Eu3+-doped glass as a color rendering index enhancer in phosphor-in-glass10.1111/jace.15464 ↗
23. Eu3+-Doped phosphor-in-glass: a route toward tunable multicolor materials for near-UV high-power warm-white LEDs10.1002/adom.201600910 ↗
24. Facile preparation and optical properties of Te/Pb-free Y3Al5O12:Ce3+ phosphor-in-glass via a screen-printing route for high-power WLEDs10.1016/j.jeurceramsoc.2019.05.031 ↗
25. Photoluminescence properties of tellurite glasses doped Dy3+ and Eu3+ for the UV and blue converted WLEDs10.1016/j.jnoncrysol.2016.11.025 ↗
26. Optical studies of Eu3+ ions doped in tellurite glass10.1016/S1386-1425(01)00684-9 ↗
27. Phosphor in glasses with Pb-free silicate glass powders as robust color-converting materials for white LED applications10.1364/OL.37.003276 ↗
28. Highly thermally stable and emission color tunable borate glass for white-light-emitting diodes with zero organic resin10.1111/jace.14951 ↗
29. Highly thermally stable single-component white-emitting silicate glass for organic-resin-free white-light-emitting diodes10.1021/am405228x ↗
30. Ultrastable red-emitting phosphor-in-glass for superior high-power artificial plant growth LEDs10.1039/C7TC05250B ↗
31. Structure and luminescence properties of Eu2+ doped LuxSr2−xSiNxO4−x phosphors evolved from chemical unit cosubstitution10.1039/C5TC04222D ↗
32. Time-resolved fluorescence measurements on Eu3+- and Eu2+-doped glasses10.1016/j.jnoncrysol.2009.06.033 ↗
33. Enhanced, shortened and tunable emission in Eu3+ doped borosilicate glasses by Cu+ co-doping10.1016/j.optmat.2018.05.056 ↗
34. Optical properties of phosphor-in-glass through modification of pore properties for LED packaging10.1016/j.optmat.2017.12.003 ↗
35. Multi-color luminescence in Eu3+/Tb3+ co-doped ZnAl amorphous materials and their annealed samples10.1016/j.jre.2018.01.024 ↗
36. Temperature dependence of luminescence and decay time of YAG: Ce nanophosphor10.3724/SP.J.1077.2008.01045 ↗
37. Time-Resolved luminescence characteristics of cerium doped YAG nanocrystals10.4028/www.scientific.net/SSP.128.173 ↗
38. The thermal stability performances of the color rendering index of white light emitting diodes with the red quantum dots encapsulation10.1016/j.optmat.2015.01.007 ↗