journal article·2019-02

Luminescence properties and energy transfer investigations of Ce3+ singly doped and Ce3+/Tb3+ codoped Na3LuSi2O7 phosphors

Qingxi Li, Xiyan Zhang, Lipeng Jiang, Shiqi Zhu, He Tang, Wenmin Zhang

Optical Materials· Volume 88
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Abstract

Abstract The Na3LuSi2O7:Ce3+ and Na3LuSi2O7:Ce3+, Tb3+ phosphors were synthesized under a weak reducing atmosphere by the traditional high temperature solid state reaction method. The synthesized phosphors were characterized by X-ray diffraction (XRD), Photoluminescence (PL) emission and excitation spectra. The effects of Ce3+ singly doped and Ce3+/Tb3+ codoped concentrations on the structure, luminescence properties and energy transfer of Na3LuSi2O7 phosphors were studied in detail. The results indicated that the energy transfers between Ce3+ and Tb3+ in the host occurred mainly via a dipole-quadrupole mechanism, and the critical distances of the ion pairs (Rc) were calculated by the quenching concentration method and spectral overlap method. Based on the good PL properties adjusting the doping concentration of the activators (Ce3+,Tb3+) might be promising as a host material for solid-state lighting and display fields.
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Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Radiation Detection and Scintillator Technologies · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

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