journal article·2018-06

Composition effect in luminescence properties of Y(NbxTa1-x)O4 mixed crystals

D. Spassky, A. Vasil'ev, S. Vielhauer, O. Sidletskiy, O. Voloshyna, A. Belsky

Optical Materials· Volume 80
Publisher page

Abstract

Abstract The luminescence properties of Y(NbxTa1-x)O4 mixed crystals were studied. Local structure modifications arise due to the inhomogeneous distribution of the substitutional ions in the mixed crystal and can be traced using the luminescence spectroscopy. In particular, it is shown that the intensity of exciton emission under interband VUV excitation increases for intermediate values of x with the maximum at x = 0.4 relatively to the intensity observed in the constituents of the mixed crystals - YTaO4 and YNbO4. From the luminescence excitation spectra it follows that the probability of exciton creation from the separated e-h pairs increases for intermediate values of x as well. Using numerical simulation it is shown that the effect is connected with the variation of the thermalization length of hot electrons and holes, which is minimal at x = 0.4.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Luminescence Properties of Advanced Materials · Radiation Detection and Scintillator Technologies · Perovskite Materials and Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (33)

Show source-provided references
1. Su · 2005 · 500
2. Rare-earth Tantalates and niobates single crystals: promising Scintillators and laser Materials10.3390/cryst8020055 ↗
3. Synthesis and luminescence properties of YNbO4:a (a = Eu3+ and/or Tb3+) nanocrystalline phosphors via a Sol−Gel process10.1021/jp508773t ↗
4. Luminescent and scintillation properties of orthotantalates with common formulae RETaO4 (RE = Y, Sc, La, Lu and Gd)10.1016/j.mseb.2013.08.003 ↗
5. Hydrothermal formation and characteristics of rare-earth niobite phosphors and solid solutions between YNbO4 and TbNbO410.1016/j.matchemphys.2013.10.025 ↗
6. Mechanochemical synthesis of YNbO4:Eu nanocrystalline powder and its structural, microstructural and photoluminescence properties10.1016/j.ceramint.2014.01.028 ↗
7. Die Konstitution der Mischkristalle und die Raumfüllung der Atome10.1007/BF01349680 ↗
9. Growth and light yield performance of dense Ce3+-doped (Lu,Y)AlO3 solid solution crystals10.1016/S0022-0248(99)00810-6 ↗
10. Luminescence and scintillation characteristics of Gd3Al2Ga3O12:Ce3+ scintillators10.1016/j.optmat.2013.10.033 ↗
11. Structure–property correlations in a Ce-doped (Lu, Gd)2SiO5: Ce scintillator10.1021/cg300608t ↗
12. Composition engineering in cerium-doped (Lu, Gd)3(Ga, Al)5O12 single crystal scintillators10.1021/cg200694a ↗
13. Light-yield improvement trends in mixed scintillation crystals10.1002/pssa.201431137 ↗
14. Energy transfer in solid solutions ZnxMg1-xWO410.1016/j.optmat.2013.12.039 ↗
15. Electronic and optical properties of scintillators based on mixed ionic crystals
16. Scintillation efficiency improvement by mixed crystal use10.1109/TNS.2013.2277883 ↗
17. The normal incidence monochromator beamline I3 on MAX III10.1063/1.3463293 ↗
18. Luminescence phenomena in compounds with fergusonite structure10.1016/0022-2313(70)90011-6 ↗
19. Luminescence properties of the yttrium and gadolinium tantalo-niobates10.4028/www.scientific.net/SSP.230.172 ↗
20. Luminescence of yttrium niobium-tantalate doubly activated by europium and/or terbium under X-ray and electron beam excitation10.1016/j.jlumin.2012.04.039 ↗
21. Charge transfer transitions in the transition metal oxides ABO4:Ln3+ and APO4:Ln3+ (A=La, Gd, Y, Lu, Sc; B=V, Nb, Ta; Ln=lanthanide)10.1016/j.jlumin.2010.02.035 ↗
22. X-ray diffraction experiments, luminescence measurements and first-principles GGA + U calculations on YTaO410.1016/j.commatsci.2013.03.042 ↗
23. First-principles LDA+U calculations and luminescence study of YNbO410.1088/0031-8949/89/9/095102 ↗
24. New, dense, and fast scintillators based on rare-earth tantalo-niobates10.1016/j.nima.2014.07.044 ↗
25. Luminescence study of some yttrium tantalate-based phosphors10.1016/j.jlumin.2011.01.021 ↗
26. Trap centers in molybdates10.1016/j.optmat.2013.06.054 ↗
27. Luminescence properties of solid solutions of borates doped with rare-earth ions10.1134/S1063783414110171 ↗
28. Control of electron transfer between Ce3+ and Cr3+ in Y3Al5-xGaxO12 host by conduction band engineering10.1039/C5TC00546A ↗
29. Nonlinear behavior of structural and luminescent properties in Gd(TaxNb1-x)O4 mixed crystals10.1016/j.optmat.2018.01.003 ↗
30. Urbach · 1930 · vol. 139 · 363
31. The features of energy transfer to the emission centers in ZnWO4 and ZnWO4:Mo10.1016/j.jlumin.2013.06.039 ↗
32. Recombination of correlated electron-hole pairs with account of hot capture with emission of optical phonons10.1109/TNS.2012.2194306 ↗
33. Multiscale approach to estimation of scintillation characteristics10.1109/TNS.2013.2282117 ↗