journal article·2025-08-22

Composite Chitosan-TiO2 Nanocrystal Optical Metasurfaces for Humidity Sensing in the Visible Spectrum

Chavez F. K. Lawrence, Akhila Mallavarapu, Kai Lu, Jonah J. Ng, Cherie R. Kagan

ACS Applied Nano Materials· Volume 8· Issue 33
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Abstract

We report the fabrication and characterization of responsive dielectric metasurfaces composed of titanium dioxide (TiO 2 ) nanocrystals (NCs) and chitosan hydrogel biopolymer composites. Chitosan is controllably introduced into aqueous TiO 2 NC dispersions to formulate adaptive inks. The inks are then used in a nanoimprinting process to produce moisture-responsive metasurfaces with high quality factor ( Q ), quasi-guided mode (QGM) resonances. The metasurfaces function as environmental relative humidity (RH) sensors, exhibiting a 250% enhancement in sensitivity with the addition of chitosan─to a maximum of 0.29 nm/%RH. This work presents a scalable, single-step, room-temperature strategy for producing optically tunable metasurfaces in the visible, offering high sensitivity and quality factor resonances, and enabling enhanced optical humidity sensor performance.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Gas Sensing Nanomaterials and Sensors · Polydiacetylene-based materials and applications · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Electrical and Systems Engineering

University of Pennsylvania

Department of Materials Science and Engineering

Department of Chemistry

Funding

Division of Engineering Education and Centers

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