Acridine-1, 8-diones – A new class of thermally stable NLOphores: Photophysical, (hyper)polarizability and TD-DFT studies
Source abstract
Abstract
Abstract Linear and non-linear optical properties of a series of new acridine-1, 8-dione derivatives are investigated in different solvents by using solvatochromic and computational methods. Values of first-order hyperpolarizabilities (βCT or β0) obtained using solvatochromic and computational methods are compared with the reported values for urea and 3-aminoxanthone. The new materials under study show first hyperpolarizability values 2.3 to 5.6 times larger than that of urea and 2 to 15.6 times more than that of 3-aminoxanthone. The dyes possess very high thermal stabilities. The dyes are prepared using one pot multicomponent reaction between dimedone, various aromatic aldehydes and amino acids, and characterized by spectroscopic techniques.
Source: openaire · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Nonlinear Optical Materials Research · Photochromic and Fluorescence Chemistry · Synthesis and biological activity
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