Growth and spectroscopic properties of Tm3+:NaBi(MoO4)2 single crystal
Source abstract
Abstract
Abstract In this work we report the spectroscopic properties of Tm3+:NaBi(MoO4)2 crystals with the dopant concentrations of 0.7 at.% and 3 at.%. The energy levels of the Tm3+ in the NaBi(MoO4)2 host were determined from polarized optical absorption and photoluminescence spectra measured at 77.4 K. Radiative properties of the crystals were calculated in context of Judd-Ofelt theory. Raman spectra of the crystal were studied. The concentration dependences of emission decay times of 3H4 and 3F4 levels were analyzed. The potential of the crystal for building tunable and ultrafast pulse lasers is shown on the base of cross sections and gain coefficient in the range of 1.9 μm.
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Research context
OpenAlex topics: Solid State Laser Technologies · Luminescence Properties of Advanced Materials · Glass properties and applications
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (45)
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1. 2 μm laser sources and their possible applications, Frontiers in Guided Wave Optics and Optoelectronics
2. Spectroscopic analysis of Tm3+:NaLa(MoO4)210.1063/1.352215 ↗
3. Spectral properties of Tm3+:NaGd(MoO4)2 crystal10.1016/j.materresbull.2007.12.011 ↗
4. Polarized spectral properties and laser demonstration of Tm3+ -doped LiGd(MoO4)2 crystal10.1364/JOSAB.27.001769 ↗
5. Spectroscopy of NaLa(MoO4)2: Tm3+ and NaGd(MoO4)2: Tm3+ crystals as advanced laser materials10.1134/S1063783408090023 ↗
6. Growth, thermal and spectral properties of Tm3+, Ho3+ co-doped NaGd(MoO4)2 Crystal10.1016/j.jallcom.2014.06.084 ↗
7. Growth, optical parameters, and spectroscopic properties of crystals of disordered scheelite-like molybdates NaLaxGd1−x(MoO4)2 (x = 0–1) activated by Tm3+ ions10.1134/S0030400X10050127 ↗
8. Optical absorption and spectroscopic characteristics of Tm3+ ions doped NaY(MoO4)2 crystal10.1016/j.jallcom.2007.04.010 ↗
9. Growth and spectroscopic studies of NaLa(MoO4)2:Tm3+ crystals: a new promising laser material10.1134/S0030400X08100081 ↗
10. Tunable quasi-cw two-micron lasing in diode-pumped crystals of mixed Tm3+-doped sodium – lanthanum – gadolinium molybdates and tungstates10.1070/QE2010v040n10ABEH014403 ↗
11. Efficient infrared (≈1.9–2.0 μm) laser operation in color-defect-free Tm:NaGd(MoO4)2 crystal10.1088/1612-2011/10/4/045808 ↗
12. Efficient 1.9 μm monolithic Tm3+:NaLa(MoO4)2 micro-laser10.1002/lapl.201110113 ↗
13. Preparation and properties of disordered NaBi(XO4)2, X=W or Mo, crystals doped with rare earths10.1016/S0022-3697(01)00084-1 ↗
14. Measurement and crystal-field analysis of Er3+ energy levels in crystals of NaBi(MoO4)2 and NaBi(WO4)2 with local disorder10.1016/S0301-0104(02)00486-X ↗
15. Crystal field analysis and emission cross sections of Ho3+ in the locally disordered single-crystal laser hosts M+Bi(XO4)2 (M+ = Li, Na; X=W, Mo)10.1103/PhysRevB.75.174208 ↗
16. Polarization and local disorder effects on the properties of Er3+ -doped XBi(YO4)2, X = Li or Na and Y = W or Mo, crystalline tunable laser hosts10.1364/JOSAB.23.002066 ↗
17. Growth and spectroscopic characteristics of Yb3+-Doped NaBi(MoO4)2 crystals10.1134/S0020168514060193 ↗
18. Structural, spectroscopic, and tunable laser properties of Yb3+-doped NaGd(WO4)210.1103/PhysRevB.74.174114 ↗
19. Khafizov, Spectroscopy and stimulated emission of Nd3+-doped tetragonal NaBi(MoO4)2 and NaBi(WO4)2 disordered crystals10.1002/pssa.2211140235 ↗
20. Thermo-optical properties of uniaxial NaT(XO4)2 laser host crystals (where T=Y, La, Gd or Bi, and X=W or Mo)10.1007/s00340-012-5331-z ↗
21. Kaminskii · 1981
22. Intensities of crystal spectra of rare-earth ions10.1063/1.1701366 ↗
23. Optical absorption intensities of rare-earth ions10.1103/PhysRev.127.750 ↗
24. Electronic energy levels in the trivalent lanthanide aquo ions. I. Pr3+, Nd3+, Pm3+, Sm3+, Dy3+, Ho3+, Er3+, and Tm3+10.1063/1.1669893 ↗
25. Radiative transition probabilities within 4fn configurations: the fluorescence spectrum of europium ethylsulfate10.1063/1.1734405 ↗
26. Optical-absorption intensities of rare-earth ions in crystals: the absorption spectrum of thulium ethyl sulfate10.1103/PhysRev.139.A2008 ↗
27. Wybourne · 1965
28. Tb3+ f-d absorption as indicator of the effect of covalency on the Judd–Ofelt Ω2 parameter in glasses10.1016/S0022-3093(99)00243-4 ↗
29. Optical intensities of rare-earth ions in yttrium orthoaluminate10.1103/PhysRevB.8.47 ↗
30. Branching ratios, cross sections, and radiative lifetimes of rare earth ions in solids: application to Tm3+ and Ho3+ ions in LiYF410.1063/1.367037 ↗
31. Judd-Ofelt analysis of spectroscopic properties of Tm3+, Ho3+ doped GdVO4 crystals10.1016/j.optmat.2006.06.003 ↗
32. Growth and fluorescence properties of Tm3+ doped YVO4 and Y2O3 single crystals10.1016/S0925-3467(97)00029-3 ↗
33. Thulium doped monoclinic KLu(WO4)2 single crystals: growth and spectroscopy10.1007/s00340-007-2664-0 ↗
34. Growth and spectral properties of Tm3+-doped NaGd(WO4)2 crystal10.1007/s00340-006-2209-y ↗
35. Optical spectra of Tm3+ doped NaBi(WO4)210.1016/j.optmat.2006.01.008 ↗
36. Thermal and optical properties of Tm3+:NaLa(WO4)2 crystal10.1007/s00340-006-2428-2 ↗
37. Efficient stimulated Raman scattering in tetragonal laser crystalline hosts NaBi(MoO4)2 and NaBi(WO4)210.1143/JJAP.34.L1461 ↗
38. Polarized Raman spectra of NaBi(MoO4)2 crystal and order-disorder effect in solid scheelites10.1016/0022-2860(94)80026-X ↗
39. Raman spectra of acoustooptic NaBi(MoO4)210.1002/1097-4555(200006)31:6<539::AID-JRS550>3.0.CO;2-G ↗
40. Polarized IR and Raman spectra of tetragonal NaBi(WO4)2, NaBi(MoO4)2 and LiBi(MoO4)2 single crystals with scheelite structure10.1016/0022-2860(95)08660-N ↗
41. Population dynamics of the 3F4 and 3H4 levels in highly-doped Tm3+:ZB(L)AN glasses10.1016/j.jnoncrysol.2006.09.037 ↗
42. Effect of cross relaxation on the 1470 and 1800 nm emissions in Tm3+:TeO2–CdCl2 glass10.1088/0953-8984/16/15/001 ↗
43. Integral method of reciprocity in the spectroscopy of laser crystals with impurity centers10.1023/B:JAPS.0000032875.04400.a0 ↗
44. Infrared cross-section measurements for crystals doped with Er3+, Tm3+, and Ho3+10.1109/3.161321 ↗
45. Diode-laser absorption measurements of CO2, H2O, N2O, and NH3 near 2.0 μm10.1007/s003400050507 ↗