journal article·2015-12

New bithiophene-containing electroluminescent polymer: Synthesis, characterization, optical and electrical properties

Nejmeddine Jaballah, Mejed Chemli, Jean-Louis Fave, Mustapha Majdoub

Optical Materials· Volume 50
Publisher page

Abstract

A semi-conducting polymer, P-DSBT, based on distyryl-bithiophene π-conjugated sequences has been synthesized and characterized. The macromolecular material was soluble in volatile solvents and showed a good film quality; it exhibited an amorphous morphology with relatively high glass transition temperature. The absorption and photoluminescence properties of the polymer were studied in solution and as thin solid film, which showed an optical gap of 2.6 eV. The HOMO/LUMO energy levels were evaluated by cyclic voltammetry measurements and indicate a p-type semi-conducting material. The electrical properties of P-DSBT were investigated by the current-tension characteristic and modeled by the current space-charge-limited (SCLC) mechanism; charge carrier mobility higher than 10−6 cm2 V−1 s−1 was evaluated. A yellow-green electroluminescence was evidenced in a multilayer organic light-emitting diode with an [ITO/PEDOT:PPS/P-DSBT/BCP/Al] configuration.
Source: openaire · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Organic Electronics and Photovoltaics · Conducting polymers and applications · Organic Light-Emitting Diodes Research

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References (49)

Show source-provided references
1. Bao · 2007
2. On the mode of operation in electrolyte-gated thin film transistors based on different substituted polythiophenes10.1016/j.orgel.2014.06.017 ↗
3. Semiconducting p-conjugated systems in field-effect transistors: a material odyssey of organic electronics10.1021/cr100380z ↗
4. Buckley · 2013
5. New confined p-phenylenevinylene (PPV)-type polymer analogue of poly(phenylene sulfide)10.1016/j.eurpolymj.2008.07.003 ↗
6. Green-Yellow electroluminescence from a host-dopant blended system as the active layer in a bilayer polymer light emitting diode: poly(n-vinyl carbazole) as the host and a new soluble thiophene based copolymer [poly(2,2′-BT)-co-(3-DDT)] as the dopant10.1016/j.optmat.2014.09.004 ↗
7. Krebs · 2008
8. Chemical sensors based on amplifying fluorescent conjugated polymers10.1021/cr0501339 ↗
9. Water-soluble fluorescent conjugated polymers and their interactions with biomacromolecules for sensitive biosensors10.1039/b909065g ↗
10. Rapid detection methodology for inorganic mercury (Hg2+) in seafood samples using conjugated polymer (1,4-bis-(8-(4-phenylthiazole-2-thiol)-octyloxy)-benzene) (PPT) by colorimetric and fluorescence spectroscopy10.1016/j.snb.2015.05.046 ↗
11. Conjugated polymer nanoparticles10.1039/b9nr00374f ↗
12. Nanoparticles of conjugated polymers10.1021/cr100132y ↗
13. Nanoparticles of conjugated polymers prepared from phase-separated films of phospholipids and polymers for biomedical applications10.1002/adma.201400906 ↗
14. Synthesis and characterization of new anthracene-based semiconducting polyethers10.1002/app.32659 ↗
15. New anthracene-based semi-conducting polymer analogue of poly(phenylene sulfide): synthesis and photophysical properties10.1016/j.optmat.2015.04.055 ↗
16. Color control in π-conjugated organic polymers for use in electrochromic devices10.1021/cr900129a ↗
17. Fichou · 1999
18. Electrical properties of a new sulfur-containing polymer for optoelectronic application10.1007/s00339-015-9100-9 ↗
19. Light-Emitting Polythiophenes10.1002/adma.200500461 ↗
20. Intermolecular interactions in organic semiconductors based on annelated β-oligothiophenes and their effect on the performance of organic field-effect transistors10.1016/j.orgel.2013.01.002 ↗
21. Printable polythiophene gas sensor array for low-cost electronic noses10.1063/1.2208743 ↗
22. Colorimetric detection of copper ions based on a supramolecular complex of water-soluble polythiophene and ATP10.1039/c3an00151b ↗
23. High photoluminescence efficiency in substituted polythiophene aggregates10.1016/S0379-6779(03)00171-1 ↗
24. Oligothiophenes with the naphthalene core for organic thin-film transistors: variation in positions of bithiophenyl attachment to the naphthalene10.1016/j.synthmet.2015.01.020 ↗
25. Study on interactions among ortho-biphenyl groups in oligothiophene for structural control of bulk heterojunction films10.1016/j.tsf.2015.03.070 ↗
26. α,ω-Distyryl oligothiophenes: high mobility semiconductors for environmentally stable organic thin film transistors10.1021/ja054358c ↗
27. Synthesis and characterization of new blue-photoluminescent copolymer derived from bisphenol A10.1002/app.23022 ↗
28. New Semiconducting poly(arylene sulfide)s: synthesis, characterization, and optical properties10.1080/1023666X.2014.933066 ↗
29. Organic light-emitting devices with polymethylmethacrylate interfacial layer: role of organic internal interface on electric field distribution10.1063/1.3660515 ↗
30. Conjugated polymers as molecular materials: how chain conformation and film morphology influence energy transfer and interchain interactions10.1146/annurev.physchem.54.011002.103811 ↗
31. The effect of the PEDOT:PSS surface energy on the interface potential barrier10.1016/j.synthmet.2011.10.006 ↗
32. Influence of chromophore dipole moments in parameters of organic light emitting devices based on phenyl and methyl modified pyrazoloquinoline10.1016/j.saa.2010.02.006 ↗
33. Monopolar surfaces10.1016/0001-8686(87)80008-8 ↗
34. Surface energy for electroluminescent polymers and indium-tin-oxide10.1016/S0169-4332(02)01328-4 ↗
35. Blue-luminescent poly(p-phenylenevinylene) derivatives: synthesis and effect of side-group size on the optical properties10.1016/j.eurpolymj.2010.10.017 ↗
36. Optical properties and electronic structure of amorphous germanium10.1002/pssb.19660150224 ↗
37. Aggregate versus excimer emissions from poly(2,5-di-n-octyloxy-1,4-phenylenevinylene)10.1021/jp067751t ↗
38. Photooxidative stability of substituted poly(phenylene vinylene) (PPV) and poly(phenylene acetylene) (PPA)10.1002/(SICI)1097-4628(19980919)69:12<2451::AID-APP16>3.0.CO;2-# ↗
39. Synthesis and characterization of new anthracene-based semi-conducting materials10.1007/s10853-012-6699-1 ↗
40. Quantum efficiencies of fluorescence of organic substances: effect of solvent and concentration of the fluorescent solute10.1021/j100820a009 ↗
41. New blue-photoluminescent semi-conducting polymer derived from fluorinated bisphenol A10.1177/0954008309348664 ↗
42. Müllen · 2006
43. Rod–coil and all-conjugated block copolymers for photovoltaic applications10.1016/j.progpolymsci.2012.10.001 ↗
44. Kao · 1981
45. Effect of the side-chain size on the optical and electrical properties of confined-PPV derivatives10.1016/j.spmi.2015.05.006 ↗
46. Determination of carrier mobility in MEH-PPV thin-films by stationary and transient current techniques10.1016/j.jnoncrysol.2011.11.001 ↗
47. Status of and prospects for organic electroluminescence10.1557/JMR.1996.0403 ↗
48. Synthesis and characterization of new electroluminescent poly(p-phenylene) derivative10.1016/j.synthmet.2011.03.031 ↗
49. Blue electroluminescence from a novel polymer structure10.1016/0379-6779(94)03206-L ↗