Core–shell ZIF-67(Co) wrapped CuO as high efficient peroxymonosulfate catalyst for the degradation of methylene blue
Source abstract
Abstract
Core–shell ZIFs wrapped CuO hybrid materials (CuO@ZIF-67(Co)) were designed, synthesized, characterized, and employed as peroxymonosulfate (PMS) activators to degrade methylene blue (MB). It demonstrated outstanding catalytic activity on account of the unique structure and the synergistic effect between CuO cores and ZIF-67(Co) shells, resulting in complete degradation of MB (10 mg/L) in 1 min. Reactive oxygen species (ROSs) research showed that both SO4− and OH were responsible for the removal of MB. The synergistic activation mechanisms in the CuO@ZIF-67(Co)/PMS system were investigated, which mainly involved the effective electron transfer of CuO and ZIF-67(Co) for accelerating the cycle of CuII/CuI and CoIII/CoII. This study broadens the application of MOF-derived materials for wastewater treatment.
Source: expertdata · Quality: candidate unverified · Source record ↗
Research context
OpenAlex topics: Advanced oxidation water treatment · Advanced Photocatalysis Techniques · Nanomaterials for catalytic reactions
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (57)
Show source-provided references
1. Zhang T, Ma Q, Zhou M, Li C, Sun J, Shi W, Ai S (2021) Degradation of methylene blue by a heterogeneous Fenton reaction catalyzed by FeCo2O4-N-C nanocomposites derived by ZIFs. Powder Technol 383:225–232. https://doi.org/10.1016/j.powtec.2021.01.05110.1016/j.powtec.2021.01.051 ↗
2. Wu W, Zhang X, Yang J, Li J, Li X (2020) Facile preparation of oxygen-rich activated carbon from petroleum coke for enhancing methylene blue adsorption. Carbon Lett 30:627–636. https://doi.org/10.1007/s42823-020-00134-010.1007/s42823-020-00134-0 ↗
3. Hui TS, Zaini MAA (2021) Valorization of spent activated carbon in glycerine deodorization unit for methylene blue removal. Carbon Lett 31:721–728. https://doi.org/10.1007/s42823-020-00189-z10.1007/s42823-020-00189-z ↗
4. Maia LS, Duizit LD, Pinhatio FR, Mulinari DR (2021) Valuation of banana peel waste for producing activated carbon via NaOH and pyrolysis for methylene blue removal. Carbon Lett 31:749–762. https://doi.org/10.1007/s42823-021-00226-510.1007/s42823-021-00226-5 ↗
5. Buxton GV, Greenstock CL, Helman WP, Ross AB (1988) Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (·OH/·O−) in aqueous solution. J Phys Chem Ref Data 17:513–521. https://doi.org/10.1063/1.55580510.1063/1.555805 ↗
6. Su L, Ou L, Wen Y, Wang Y, Zhao W, Zhou Z, Zhong M, Zhu Y, Zhou N (2021) High-efficiency degradation of quinclorac via peroxymonosulfate activated by N-doped CoFe2O4/Fe0@CEDTA hybrid catalyst. J Ing Eng Chem 17:177–185. https://doi.org/10.1016/j.jiec.2021.06.04010.1016/j.jiec.2021.06.040 ↗
7. Ghanbari F, Moradi M (2017) Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: Review. Chem Eng J 17:51–62. https://doi.org/10.1016/j.cej.2016.10.06410.1016/j.cej.2016.10.064 ↗
8. Anipsitakis GP, Dionysiou DD (2004) Radical generation by the interaction of transition metals with common oxidants. Environ Sci Technol 38:3705–3712. https://doi.org/10.1021/es035121o10.1021/es035121o ↗
9. Olmez-Hanci T, Arslan-Alaton I (2013) Comparison of sulfate and hydroxyl radical based advanced oxidation of phenol. Chem Eng J 224:10–16. https://doi.org/10.1016/j.cej.2012.11.00710.1016/j.cej.2012.11.007 ↗
10. Wang J, Wang S (2018) Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants. Chem Eng J 334:1502–1517. https://doi.org/10.1016/j.cej.2017.11.05910.1016/j.cej.2017.11.059 ↗
11. Yang P, Ji Y, Lu J, Huang Q (2019) Formation of nitrophenolic byproducts during heat-activated peroxydisulfate oxidation in the presence of natural organic matter and nitrite. Environ Sci Technol 53:4255–4264. https://doi.org/10.1021/acs.est.8b0696710.1021/acs.est.8b06967 ↗
12. Huang W, Xiao S, Zhong H, Yan M, Yang X (2021) Activation of persulfates by carbonaceous materials: a review. Chem Eng J 418:129297. https://doi.org/10.1016/j.cej.2021.12929710.1016/j.cej.2021.129297 ↗
13. Anipsitakis GP, Dionysiou DD (2003) Degradation of organic contaminants in water with sulfate radicals generated by the conjunction of peroxymonosulfate with cobalt. Environ Sci Technol 37:4790–4797. https://doi.org/10.1021/es026379210.1021/es0263792 ↗
14. Ding Y, Fu L, Peng X, Lei M, Wang C, Jiang J (2022) Copper catalysts for radical and nonradical persulfate based advanced oxidation processes: Certainties and uncertainties. Chem Eng J 427:131776. https://doi.org/10.1016/j.cej.2021.13177610.1016/j.cej.2021.131776 ↗
15. Ding Y, Zhu L, Wang N, Tang H (2013) Sulfate radicals induced degradation of tetrabromobisphenol A with nanoscaled magnetic CuFe2O4 as a heterogeneous catalyst of peroxymonosulfate. Appl Catal B: Environ 129:153–162. https://doi.org/10.1016/j.apcatb.2012.09.01510.1016/j.apcatb.2012.09.015 ↗
16. Niu H, Liu S, Cai Y, Wu F, Zhao X (2016) MOF derived porous carbon supported Cu/Cu2O composite as high performance non-noble catalyst. Microporous Mesoporous Mater 219:48–53. https://doi.org/10.1016/j.micromeso.2015.07.02710.1016/j.micromeso.2015.07.027 ↗
17. Zou J, Wu S, Liu Y, Sun Y, Cao Y, Hsu J, Wee ATS, Jiang J (2018) An ultra-sensitive electrochemical sensor based on 2D g-C3N4/CuO nanocomposites for dopamine detection. Carbon 130:652–663. https://doi.org/10.1016/j.carbon.2018.01.00810.1016/j.carbon.2018.01.008 ↗
18. Tang S, Vongehr S, Zheng Z, Liu H, Meng X (2010) Silver doping mediated route to bimetallically doped carbon spheres with controllable nanoparticle distributions. J Phys Chem C 114:18338–18346. https://doi.org/10.1021/jp105871w10.1021/jp105871w ↗
19. Deng Y, Cai Y, Sun Z, Liu J, Liu C, Wei J, Li W, Liu C, Wang Y, Zhao D (2010) Multifunctional mesoporous composite microspheres with well-designed nanostructure: a highly integrated catalyst system. J Am Chem Soc 132:8466–8473. https://doi.org/10.1021/ja102574410.1021/ja1025744 ↗
20. Zhang Y, Huang J, Dong Z, Zhan Y, Xi J, Xiao J, Huang S, Fan T (2022) Pd–Fe bimetallic nanoparticles anchored on N-doped carbon-modified graphene for efficient catalytic organic reactions. Carbon Lett 32:1–11. https://doi.org/10.1007/s42823-022-00404-z10.1007/s42823-022-00404-z ↗
21. Wang J, Qin Q, Li F, Anjarsari Y, Sun W, Azzahiidah R, Zou J, Xiang K, Ma H, Jiang J (2022) Recent advances of MXenes Mo2C-based materials for efficient photocatalytic hydrogen evolution reaction. Carbon Lett 32:152–161. https://doi.org/10.1007/s42823-022-00401-210.1007/s42823-022-00401-2 ↗
22. Jiang J, Xiong Z, Wang H, Liao G, Bai S, Zou J, Wu P, Zhang P, Li X (2022) Sulfur-doped g-C3N4/g-C3N4 isotype step-scheme heterojunction for photocatalytic H2 evolution. J Mater Sci Technol 118:15–24. https://doi.org/10.1016/j.jmst.2021.12.01810.1016/j.jmst.2021.12.018 ↗
23. Jiang J, Ou-yang L, Zhu L, Zheng A, Zou J, Yi X, Tang H (2014) Dependence of electronic structure of g-C3N4 on the layer number of its nanosheets: a study by Raman spectroscopy coupled with first-principles calculations. Carbon 80:213–221. https://doi.org/10.1016/j.carbon.2014.08.05910.1016/j.carbon.2014.08.059 ↗
24. Bai S, Yang M, Jiang J, He X, Zou J, Xiong Z, Liao G, Liu S (2021) Recent advances of MXenes as electrocatalysts for hydrogen evolution reaction. NPJ 2D Mater Appl. 5:1–15. https://doi.org/10.1038/s41699-021-00259-410.1038/s41699-021-00259-4 ↗
25. Yang M, Chen Y, Wang H, Zou Y, Wu P, Zou J, Jiang J (2022) Solvothermal preparation of CeO2 nanoparticles–graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol. Carbon Lett 32:1277–1285. https://doi.org/10.1007/s42823-022-00353-710.1007/s42823-022-00353-7 ↗
26. Ai L, Yue H, Jiang J (2012) Environmentally friendly light-driven synthesis of Ag nanoparticles in situ grown on magnetically separable biohydrogels as highly active and recyclable catalysts for 4-nitrophenol reduction. J Mater Chem 22:23447. https://doi.org/10.1039/C2JM35616C10.1039/C2JM35616C ↗
27. Li F, Anjarsari Y, Wang J, Azzahiidah R, Jiang J, Zou J, Xiang K, Ma H (2022) Modulation of the lattice structure of 2D carbon-based materials for improving photo/electric properties. Carbon Lett 32:127–135. https://doi.org/10.1007/s42823-022-00380-410.1007/s42823-022-00380-4 ↗
28. Chaemchuen S, Kabir NA, Zhou K, Verpoort F (2013) Metal-organic frameworks for upgrading biogas via CO2 adsorption to biogas green energy. Chem Soc Rev 42:9304–9332. https://doi.org/10.1039/C3CS60244C10.1039/C3CS60244C ↗
29. Yang J, Zhang F, Lu H, Hong X, Jiang H, Wu Y, Li Y (2015) Hollow Zn/Co ZIF particles derived from core-shell ZIF-67@ZIF-8 as selective catalyst for the semi-hydrogenation of acetylene. Angew Chem Int Ed 54:10889–10893. https://doi.org/10.1002/ange.20150424210.1002/ange.201504242 ↗
30. Zhong G, Liu D, Zhang J (2018) The application of ZIF-67 and its derivatives: adsorption, separation, electrochemistry and catalysts. J Mater Chem A 6:1887–1899. https://doi.org/10.1039/C7TA08268A10.1039/C7TA08268A ↗
31. Bennett TD, Tan JC, Moggach SA, Galvelis R, Mellot-Draznieks C, Reisner BA, Thirumurugan A, Allan DR, Cheetham AK (2010) Mechanical properties of dense zeolitic imidazolate frameworks (ZIFs): a high-pressure X-ray diffraction, nanoindentation and computational study of the zinc framework Zn(Im)2, and its lithium-boron analogue, LiB(Im)4. Chem Eur J 16:10684–10690. https://doi.org/10.1002/chem.20100141510.1002/chem.201001415 ↗
32. Azhar MR, Abid HR, Tade MO, Periasamy Sun VH, Wang S (2018) Cascade applications of robust MIL-96 metal organic frameworks in environmental remediation: Proof of concept. Chem Eng J 341:262–271. https://doi.org/10.1016/j.cej.2018.02.03010.1016/j.cej.2018.02.030 ↗
33. Zhang MW, Yang MT, Tong S, Lin KYA (2018) Ferrocene-modified iron-based metal-organic frameworks as an enhanced catalyst for activating oxone to degrade pollutants in water. Chemosphere 213:295–304. https://doi.org/10.1016/j.chemosphere.2018.09.05110.1016/j.chemosphere.2018.09.051 ↗
34. Park KS, Ni Z, Côté AP, Choi JY, Huang R, Uribe-Romo FJ, Chae HK, O’Keeffe M, Yaghi OM (2006) Exceptional chemical and thermal stability of zeolitic imidazolate frameworks. Proc Natl Acad Sci 103:10186. https://doi.org/10.1073/pnas.060243910310.1073/pnas.0602439103 ↗
35. Jiang Z, Li Z, Qin Z, Sun H, Jiao X, Chen D (2013) LDH nanocages synthesized with MOF templates and their high performance as supercapacitors. Nanoscale 5:11770–11775. https://doi.org/10.1039/C3NR03829G10.1039/C3NR03829G ↗
36. Zhang D, Zhang C, Wang Q, Li S, Zhao X, Luo H (2020) Preparation and electrochemical properties of self-doped nitrogen porous carbon derived from Zn-MOFs. Carbon Lett 30:315–324. https://doi.org/10.1007/s42823-019-00100-510.1007/s42823-019-00100-5 ↗
37. Lin KYA, Chang HA (2015) Zeolitic imidazole framework-67 (ZIF-67) as a heterogeneous catalyst to activate peroxymonosulfate for degradation of Rhodamine B in water. J Taiwan Inst Chem Eng 53:40–45. https://doi.org/10.1016/j.jtice.2015.02.02710.1016/j.jtice.2015.02.027 ↗
38. Wang L, Zhu H, Shi Y, Ge Y, Feng X, Liu R, Li Y, Ma Y, Wang L (2018) Novel catalytic micromotor of porous zeolitic imidazolate framework-67 for precise drug delivery. Nanoscale 10:11384–11391. https://doi.org/10.1039/C8NR02493F10.1039/C8NR02493F ↗
39. Butova VV, Polyakov VA, Budnyk AP, Aboraia AM, Bulanova EA, Guda AA, Reshetnikova EA, Podkovyrina YS, Lamberti C, Soldatov AV (2018) Zn/Co ZIF family: MW synthesis, characterization and stability upon halogen sorption. Polyhedron 154:457–464. https://doi.org/10.1016/j.poly.2018.08.00610.1016/j.poly.2018.08.006 ↗
40. Kida K, Okita M, Fujita K, Tanaka S, Miyake Y (2013) Formation of high crystalline ZIF-8 in an aqueous solution. CrystEngComm 15:1794–1801. https://doi.org/10.1039/C2CE26847G10.1039/C2CE26847G ↗
41. Vinu A, Murugesan V, Tangermann O, Hartmann M (2004) Adsorption of cytochrome c on mesoporous molecular sieves: influence of pH, pore diameter, and aluminum incorporation. Chem Mater 16:3056–3065. https://doi.org/10.1021/cm049718u10.1021/cm049718u ↗
42. Duan P, Ma T, Yue Y, Li Y, Zhang X, Shang Y, Gao B, Zhang Q, Yue Q, Xu X (2019) Nanostructured manganese oxides: natural/artificial formation and their induced catalysis for wastewater remediation. Environ Sci Nano 6:1799–1811. https://doi.org/10.1039/C9EN01250H10.1039/C9EN01250H ↗
43. Zhang Z, Dai Y (2022) Co3O4/C-PC composite derived from pomelo peel-loaded ZIF-67 for activating peroxymonosulfate (PMS) to degrade ciprofloxacin. J Water Process Eng 49:103043. https://doi.org/10.1016/j.jwpe.2022.10304310.1016/j.jwpe.2022.103043 ↗
44. Zhen J, Zhang S, Zhuang X, Ahmad S, Ni SQ (2021) Sulfate radicals based heterogeneous peroxymonosulfate system catalyzed by CuO-Fe3O4-Biochar nanocomposite for bisphenol A degradation. J Water Process Eng 41:102078. https://doi.org/10.1016/j.jwpe.2021.10207810.1016/j.jwpe.2021.102078 ↗
45. Dong L, Li Y, Chen X, Zhang D, Guan Y (2021) ZIF-67 loaded on Fe3O4-MnO2 as efficient peroxymonosulfate activator for rapid degradation of carbamazepine. Adv Mater Interfaces 8:21–35. https://doi.org/10.1002/admi.20210017810.1002/admi.202100178 ↗
46. Ding Y, Nie W, Li W, Chang Q (2019) Co-doped NaBiO3 nanosheets with surface confined Co species: high catalytic activation of peroxymonosulfate and ultra-low Co leaching. Chem Eng J 356:359–370. https://doi.org/10.1016/j.cej.2018.09.06310.1016/j.cej.2018.09.063 ↗
47. Oh WD, Dong Z, Lim TT (2016) Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: current development, challenges and prospects. Appl Catal B: Environ 194:169–201. https://doi.org/10.1016/j.apcatb.2016.04.00310.1016/j.apcatb.2016.04.003 ↗
48. Xu X, Liao P, Yuan S, Tong M, Luo M, Xie W (2013) Cu-catalytic generation of reactive oxidizing species from H2 and O2 produced by water electrolysis for electro-Fenton degradation of organic contaminants. Chem Eng J 233:117–123. https://doi.org/10.1016/j.cej.2013.08.04610.1016/j.cej.2013.08.046 ↗
49. Hou X, Huang X, Ai Z, Zhao J, Zhang L (2016) Ascorbic acid/Fe@Fe2O3: a highly efficient combined Fenton reagent to remove organic contaminants. J Hazard Mater 310:170–178. https://doi.org/10.1016/j.jhazmat.2016.01.02010.1016/j.jhazmat.2016.01.020 ↗
50. Zeng T, Zhang X, Wang S, Niu H, Cai Y (2015) Spatial confinement of a Co3O4 catalyst in hollow metal–organic frameworks as a nanoreactor for improved degradation of organic pollutants. Environ Sci Technol 49:2350–2357. https://doi.org/10.1021/es505014z10.1021/es505014z ↗
51. Liang C, Su HW (2009) Identification of sulfate and hydroxyl radicals in thermally activated persulfate. Ind Eng Chem Res 48:472–475. https://doi.org/10.1021/ie900284810.1021/ie9002848 ↗
52. Ma Y, Ji B, Lv X, Xiong D, Zhao X, Xie H, Zhang Z (2022) Confined heterogeneous catalysis by boron nitride-Co3O4 nanosheet cluster for peroxymonosulfate oxidation toward ranitidine removal. Chem Eng J 435:135126. https://doi.org/10.1016/j.cej.2022.13512610.1016/j.cej.2022.135126 ↗
53. Luo R, Liu C, Li J, Wang C, Sun X, Shen J, Han W, Wang L (2018) Convenient synthesis and engineering of ultrafine Co3O4-incorporated carbon composite: Towards practical application of environmental remediation. J Mater Chem A 6:3454–3461. https://doi.org/10.1039/C7TA11052A10.1039/C7TA11052A ↗
54. Liu Y, Luo R, Li Y, Qi J, Wang C, Li J, Sun X, Wang L (2018) Sandwich-like Co3O4/MXene composite with enhanced catalytic performance for Bisphenol A degradation. Chem Eng J 347:731–740. https://doi.org/10.1016/J.CEJ.2018.04.15510.1016/J.CEJ.2018.04.155 ↗
55. Wang S, Tian J, Wang Q, Xiao F, Gao S, Shi W, Cui F (2019) Development of CuO coated ceramic hollow fiber membrane for peroxymonosulfate activation: a highly efficient singlet oxygen-dominated oxidation process for bisphenol a degradation. Appl Catal B: Environ 256:117783. https://doi.org/10.1016/j.apcatb.2019.11778310.1016/j.apcatb.2019.117783 ↗
56. Qi C, Liu X, Li Y, Lin C, Ma J, Li X, Zhang H (2017) Enhanced degradation of organic contaminants in water by peroxydisulfate coupled with bisulfite. J Hazard Mater 328:98–107. https://doi.org/10.1016/j.jhazmat.2017.01.01010.1016/j.jhazmat.2017.01.010 ↗
57. Zou J, Ma J, Chen L, Li X, Guan Y, Xie P, Pan C (2013) Rapid acceleration of ferrous iron/peroxymonosulfate oxidation of organic pollutants by promoting Fe (III)/Fe (II) cycle with hydroxylamine. Environ Sci Technol 47:11685–11691. https://doi.org/10.1021/es401914510.1021/es4019145 ↗