Pt/PtO_{x} Nanoparticle-Decorated BiVO₄ Pinelike Structure for Enhanced Sulfamethoxazole Mineralization under Visible Light Irradiation

Nhat Le-Duy; Lan-Anh T. Hoang; Trinh Duy Nguyen; Taeyoon Lee

doi:10.1021/acsanm.3c02357

journal article·2023-08-25

Pt/PtO_x Nanoparticle-Decorated BiVO₄ Pinelike Structure for Enhanced Sulfamethoxazole Mineralization under Visible Light Irradiation

Nhat Le-Duy, Lan-Anh T. Hoang, Trinh Duy Nguyen, Taeyoon Lee

ACS Applied Nano Materials· Volume 6· Issue 16

Publisher page

Source abstract

Abstract

Effective charge separation is an important factor for enhancing the activity of BiVO 4 photocatalysts. In this study, we present selective and random deposition of Pt/PtO x nanoparticles on the surface of BiVO 4 pinelike architectures (Pt/PtO x /BiVO 4 ) to improve charge separation. The effectiveness of the charge separation achieved through noble metal decoration depends on the specific loading location on the surface of the BiVO 4 crystal. The photocatalytic activity of the Pt/PtO x /BiVO 4 samples was investigated through the photodegradation of sulfamethoxazole (SMX) under visible light irradiation. Pt/PtO x decorated on the BiVO 4 {040} facet catalyst (Pt/PtO x /BiVO 4 -PD) resulted in higher approximately 1.5 times higher SMX photodegradation compared to that of Pt/PtO x randomly decorated Pt/PtO x on BiVO 4 (Pt/PtO x /BiVO 4 -R) and approximately 23 times higher than that of bare BiVO 4 . In addition, Pt/PtO x /BiVO 4 -PD achieved 83% total organic carbon (TOC) removal, whereas Pt/PtO x /BiVO 4 -R and BiVO 4 achieved TOC removal rates of 68 and 8%, respectively. The three-dimensional excitation-emission matrix fluorescence spectra further confirmed the high degree of mineralization achieved by the Pt/PtO x /BiVO 4 -PD. The establishment of a Schottky barrier at the interface between the Pt/PtO x and BiVO 4 {040} facets provides an efficient route for transferring and accumulating photoinduced electrons from the conduction band of BiVO 4 to the Pt/PtO x nanoparticles. The holes (h + ) and superoxide ( • O 2 – ) radicals were identified as the primary active species during the SMX elimination reaction over the Pt/PtO x /BiVO 4 -PD photocatalyst. A liquid chromatography–mass spectroscopy system was employed to analyze the intermediate products of SMX present in the solution following the reaction. This investigation can provide offer insights into the development of heterojunction photocatalysts for antibiotic photodegradation in aqueous media through the synthesis of a heterojunction photocatalyst.

Source: openalex_inverted_index · Quality: baseline

Research context

Nanomaterials Catalysis & surfaces Materials processing

OpenAlex topics: Advanced Photocatalysis Techniques · Gas Sensing Nanomaterials and Sensors

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Environmental Engineering, College of Environmental and Marine, Pukyong National University, 45 Yongso-ro, Nam-gu, Busan 48513, Republic of Korea

Institute of Applied Technology and Sustainable Development, Nguyen Tat Thanh University, Ho Chi Minh City 700000, Vietnam

Faculty of Environmental and Food Engineering, Nguyen Tat Thanh University, Ho Chi Minh City 700000, Vietnam

Funding

Pukyong National University

References (74)

Show source-provided references

1. 10.1016/j.cej.2015.02.07310.1016/j.cej.2015.02.073 ↗

2. 10.1016/j.jtice.2019.01.01010.1016/j.jtice.2019.01.010 ↗

3. 10.1016/j.jwpe.2020.10133510.1016/j.jwpe.2020.101335 ↗

4. 10.1002/etc.333910.1002/etc.3339 ↗

5. 10.1016/j.scitotenv.2019.01.40610.1016/j.scitotenv.2019.01.406 ↗

6. 10.1016/j.envint.2020.10573310.1016/j.envint.2020.105733 ↗

7. 10.1016/j.scitotenv.2014.12.05510.1016/j.scitotenv.2014.12.055 ↗

8. 10.1016/j.envpol.2019.11316110.1016/j.envpol.2019.113161 ↗

9. 10.1016/j.scitotenv.2018.08.23510.1016/j.scitotenv.2018.08.235 ↗

10. 10.1016/j.chemosphere.2006.03.02610.1016/j.chemosphere.2006.03.026 ↗

11. 10.1016/j.watres.2015.01.02510.1016/j.watres.2015.01.025 ↗

12. 10.1016/j.envint.2013.06.01210.1016/j.envint.2013.06.012 ↗

13. 10.1126/science.301.5636.102710.1126/science.301.5636.1027 ↗

14. 10.1016/j.apcata.2020.11745910.1016/j.apcata.2020.117459 ↗

15. 10.1016/j.jece.2020.10462810.1016/j.jece.2020.104628 ↗

16. 10.1016/j.cej.2019.12249710.1016/j.cej.2019.122497 ↗

17. 10.3390/catal1106072810.3390/catal11060728 ↗

18. 10.1016/j.jmst.2020.04.02310.1016/j.jmst.2020.04.023 ↗

19. 10.1016/j.seppur.2022.12050710.1016/j.seppur.2022.120507 ↗

20. 10.1007/s11356-018-2437-9ï10.1007/s11356-018-2437-9ï ↗

21. 10.1016/j.jcis.2020.02.09310.1016/j.jcis.2020.02.093 ↗

22. 10.1016/j.jcat.2017.09.00510.1016/j.jcat.2017.09.005 ↗

23. 10.1016/j.apsusc.2020.14553410.1016/j.apsusc.2020.145534 ↗

24. 10.1016/j.molcata.2007.11.01710.1016/j.molcata.2007.11.017 ↗

25. 10.1016/j.apsusc.2021.15077310.1016/j.apsusc.2021.150773 ↗

26. 10.1002/anie.20131063510.1002/anie.201310635 ↗

27. 10.1021/jacs.5b1252110.1021/jacs.5b12521 ↗

28. 10.1038/ncomms240110.1038/ncomms2401 ↗

29. 10.1038/nmat445110.1038/nmat4451 ↗

30. 10.1002/adfm.20180121410.1002/adfm.201801214 ↗

31. 10.1021/acs.inorgchem.0c0146510.1021/acs.inorgchem.0c01465 ↗

32. 10.1016/j.jhazmat.2021.12759610.1016/j.jhazmat.2021.127596 ↗

33. 10.1016/j.arabjc.2020.05.02910.1016/j.arabjc.2020.05.029 ↗

34. 10.1016/j.chemosphere.2023.13811810.1016/j.chemosphere.2023.138118 ↗

35. 10.1016/j.catcom.2019.02.01310.1016/j.catcom.2019.02.013 ↗

36. 10.1021/acsanm.1c0268810.1021/acsanm.1c02688 ↗

37. 10.1021/acsami.0c1462410.1021/acsami.0c14624 ↗

38. 10.1021/acssuschemeng.1c0076410.1021/acssuschemeng.1c00764 ↗

39. 10.1039/d1ra00807b10.1039/d1ra00807b ↗

40. 10.1021/acsanm.1c0011510.1021/acsanm.1c00115 ↗

41. 10.1016/j.surfin.2020.10050210.1016/j.surfin.2020.100502 ↗

42. 10.1016/j.mtener.2022.10098610.1016/j.mtener.2022.100986 ↗

43. 10.1016/j.apsusc.2022.15530510.1016/j.apsusc.2022.155305 ↗

44. 10.1039/c7ra02848b10.1039/c7ra02848b ↗

45. 10.1021/jp108670310.1021/jp1086703 ↗

46. 10.1021/ie502910710.1021/ie5029107 ↗

47. 10.1039/c1jm10413f10.1039/c1jm10413f ↗

48. 10.1038/s41598-018-33795-z10.1038/s41598-018-33795-z ↗

49. 10.1039/d0nj05596d10.1039/d0nj05596d ↗

50. 10.3390/catal1301014410.3390/catal13010144 ↗

51. 10.1016/j.solmat.2017.06.02110.1016/j.solmat.2017.06.021 ↗

52. 10.1039/c7nr03238b10.1039/c7nr03238b ↗

53. 10.1016/j.cej.2019.12350410.1016/j.cej.2019.123504 ↗

54. 10.1016/j.jcou.2018.09.01910.1016/j.jcou.2018.09.019 ↗

55. 10.1021/acs.jpclett.6b0042810.1021/acs.jpclett.6b00428 ↗

56. 10.1016/j.physb.2020.41271910.1016/j.physb.2020.412719 ↗

57. 10.1016/j.catcom.2007.05.01910.1016/j.catcom.2007.05.019 ↗

58. 10.1016/j.carbon.2012.12.01010.1016/j.carbon.2012.12.010 ↗

59. 10.1016/j.watres.2015.06.04410.1016/j.watres.2015.06.044 ↗

60. 10.1016/j.jhazmat.2019.05.00810.1016/j.jhazmat.2019.05.008 ↗

61. 10.1016/j.chemosphere.2021.13319310.1016/j.chemosphere.2021.133193 ↗

62. 10.1021/es034354c10.1021/es034354c ↗

63. 10.1039/c1ee01120k10.1039/c1ee01120k ↗

64. 10.1002/wer.1074410.1002/wer.10744 ↗

65. 10.1016/j.scitotenv.2018.12.40110.1016/j.scitotenv.2018.12.401 ↗

66. 10.1016/j.jhazmat.2016.04.05210.1016/j.jhazmat.2016.04.052 ↗

67. 10.1016/j.cej.2020.12408410.1016/j.cej.2020.124084 ↗

68. 10.1016/j.watres.2007.02.02610.1016/j.watres.2007.02.026 ↗

69. 10.1016/j.jallcom.2018.04.28610.1016/j.jallcom.2018.04.286 ↗

70. 10.1016/j.apsusc.2012.03.16110.1016/j.apsusc.2012.03.161 ↗

71. 10.1016/j.watres.2009.04.00610.1016/j.watres.2009.04.006 ↗

72. 10.1016/j.cej.2016.12.08010.1016/j.cej.2016.12.080 ↗

73. 10.1016/j.jhazmat.2016.09.06210.1016/j.jhazmat.2016.09.062 ↗

74. 10.1016/j.cej.2019.12338310.1016/j.cej.2019.123383 ↗