journal article·2023-06-23

MgFe2O4Nanoparticle/Peracetic Acid Hybrids for Catalytic Oxidative Depolymerization of Lignin

Jingshun Zhuang, Saerona Kim, Mairui Zhang, Jiae Ryu, Jeeranan Nonkumwong, Laongnuan Srisombat, Kwang Ho Kim, Jeong Jae Wie, Gyu Leem, Chang Geun Yoo

ACS Applied Nano Materials· Volume 6· Issue 12
Publisher page

Abstract

Lignin is a promising feedstock for renewable fuels and chemicals due to its aromatic skeleton and natural abundance. Lignin can be converted to diverse aromatic monomers as well as dicarboxylic acids depending on the applied conversion technologies. Despite its great potential, its native and processing-induced heterogeneity and complexity limit the conversion efficiency and product selectivity. In this study, magnesium ferrite (MgFe 2 O 4 ) nanoparticle–peracetic acid (PAA) has been investigated as an efficient catalyst–oxidant incorporation for catalytic oxidative depolymerization of lignin under mild conditions. Typically, the increase in processing severity can enhance the lignin conversion while it results in the further decomposition of aromatic compounds to dicarboxylic acids. However, in this study, the incorporation of MgFe 2 O 4 nanoparticles and PAA not only enhanced the total product yield but also improved the selectivity of aromatic monomers. The oxidative depolymerization system using the catalyst–oxidant combination resulted in 46 wt % of total oil product with a 61% selectivity of aromatic monomers under mild temperature (90 °C). In addition, this combination catalyst showed relatively good cycling stability based on the total product yield after recycling five times via magnetic separation. Overall, MgFe 2 O 4 nanoparticles play an important role as a co-catalyst with a PAA oxidant in the oxidative conversion of lignin with an enhanced conversion efficiency and recyclability, and it will facilitate the valorization of lignin in future bio-based fuels and chemicals.
Source: openalex_inverted_index · Quality: baseline

Research context

OpenAlex topics: Lignin and Wood Chemistry · Catalysis and Hydrodesulfurization Studies · Enzyme-mediated dye degradation

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Department of Chemical Engineering, State University of New York College of Environmental Science and Forestry, Syracuse, New York 13210, United States

School of Environmental and Natural Resources, Zhejiang University of Science and Technology, Hangzhou 310023, China

Department of Chemistry, State University of New York College of Environmental Science and Forestry, Syracuse, New York 13210, United States

Department of Chemistry, Faculty of Science, Chiang Mai University, Chiang Mai 50200, Thailand

National Nanotechnology Center, National Science and Technology Development Agency, Pathum Thani 12120, Thailand

Center of Excellence in Materials Science and Technology, Chiang Mai University, Chiang Mai 50200, Thailand

Clean Energy Research Center, Korea Institute of Science and Technology, 5, Hwarang-ro 14-gil, Seongbuk-gu, Seoul 02792, Republic of Korea

KIST-SKKU Carbon-Neutral Research Center, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea

School of Chemical Engineering, Sungkyunkwan University (SKKU), Suwon 16419, Republic of Korea

Department of Organic and Nano Engineering, Hanyang University, Seoul 04763, Republic of Korea

Human-Tech Convergence Program, Hanyang University, Seoul 04763, Republic of Korea

The Michael M. Szwarc Polymer Research Institute, Syracuse, New York 13210, United States

Funding

Chiang Mai University · College of Environmental Science and Forestry, State University of New York

References (54)

Show source-provided references
1. 10.1039/C7CS00566K10.1039/C7CS00566K ↗
2. 10.1126/science.124684310.1126/science.1246843 ↗
3. 10.1021/acs.chemrev.5b0015510.1021/acs.chemrev.5b00155 ↗
4. 10.1002/anie.20151035110.1002/anie.201510351 ↗
5. 10.1002/adma.20190186610.1002/adma.201901866 ↗
6. 10.1039/C8GC00502H10.1039/C8GC00502H ↗
7. 10.1021/acscatal.1c0019810.1021/acscatal.1c00198 ↗
8. 10.1039/D0EE02870C10.1039/D0EE02870C ↗
9. Fache M. · ACS Sustainable Chem. Eng. · 2015 · 4 · 3510.1021/acssuschemeng.5b01344 ↗
10. 10.1039/C9GC02445J10.1039/C9GC02445J ↗
11. 10.1021/acsestwater.0c0002910.1021/acsestwater.0c00029 ↗
12. 10.1039/D1GC01521D10.1039/D1GC01521D ↗
13. 10.1002/chem.20160054610.1002/chem.201600546 ↗
14. 10.1007/s12155-013-9348-x10.1007/s12155-013-9348-x ↗
15. 10.1002/ceat.20140066010.1002/ceat.201400660 ↗
16. 10.1016/j.biombioe.2017.10.04610.1016/j.biombioe.2017.10.046 ↗
17. 10.1515/hf.2011.07110.1515/hf.2011.071 ↗
18. 10.1016/j.ces.2007.02.01810.1016/j.ces.2007.02.018 ↗
19. 10.1039/C5GC01473E10.1039/C5GC01473E ↗
20. 10.1002/app.4080910.1002/app.40809 ↗
21. 10.1039/D1GC02300D10.1039/D1GC02300D ↗
22. 10.1039/C5GC01306B10.1039/C5GC01306B ↗
23. 10.1002/cssc.20160083110.1002/cssc.201600831 ↗
24. 10.1021/cr068445e10.1021/cr068445e ↗
25. 10.1016/j.jallcom.2021.16167310.1016/j.jallcom.2021.161673 ↗
26. 10.1039/D1RA01588E10.1039/D1RA01588E ↗
27. 10.1039/C6RA07680G10.1039/C6RA07680G ↗
28. 10.1002/cssc.20140312810.1002/cssc.201403128 ↗
29. 10.1021/j100390a02710.1021/j100390a027 ↗
30. 10.1080/10643389.2016.127234310.1080/10643389.2016.1272343 ↗
31. 10.1021/acs.est.7b0469410.1021/acs.est.7b04694 ↗
32. 10.1016/j.watres.2018.11.03110.1016/j.watres.2018.11.031 ↗
33. 10.1016/j.watres.2015.08.03710.1016/j.watres.2015.08.037 ↗
34. 10.1021/jo001348f10.1021/jo001348f ↗
35. 10.1021/es100913610.1021/es1009136 ↗
36. 10.1039/C2NJ20852K10.1039/C2NJ20852K ↗
37. 10.1039/C4RA04095C10.1039/C4RA04095C ↗
38. 10.1021/acsanm.1c0174310.1021/acsanm.1c01743 ↗
39. 10.1021/acsanm.9b0130510.1021/acsanm.9b01305 ↗
40. 10.1021/acssuschemeng.0c0353310.1021/acssuschemeng.0c03533 ↗
41. 10.1021/cm051489410.1021/cm0514894 ↗
42. Sluiter A. · Lab. Anal. Proc. · 2008 · 1617 · 1
43. 10.1016/j.fuel.2022.12373910.1016/j.fuel.2022.123739 ↗
44. 10.1139/v99-03610.1139/v99-036 ↗
45. 10.1002/cssc.20140250310.1002/cssc.201402503 ↗
46. 10.1126/science.aaf781010.1126/science.aaf7810 ↗
47. 10.1016/j.apcatb.2020.11942210.1016/j.apcatb.2020.119422 ↗
48. 10.1021/am100457v10.1021/am100457v ↗
49. 10.1021/acs.orglett.0c0302910.1021/acs.orglett.0c03029 ↗
50. 10.1021/ja411346210.1021/ja4113462 ↗
51. 10.1021/bk-2021-1377.ch00510.1021/bk-2021-1377.ch005 ↗
52. 10.1021/acsenergylett.9b0239110.1021/acsenergylett.9b02391 ↗
53. Barros D. P. · BioResources · 2010 · 5 · 88110.15376/biores.5.2.881-898 ↗
54. 10.1021/acsanm.1c0362210.1021/acsanm.1c03622 ↗