DataVXACS Applied Nano MaterialsPaper
journal article·2024-06-28

Photothermic Energy Harvesting in Reduced Graphene Oxide Nanosheets Intercalated with Vanadium Nitride as Pseudocapacitive Electrode

Kiruthiga Ramakrishnan, Srivathsava Surabhi, Udayabhaskar Rednam, Jong-Ryul Jeong, Kumaramangalam Jeyalakshmi, Santhosh Girish, Daniela V. Morales, Mangalaraja Ramalinga Viswanathan, Ramasamy Karvembu

ACS Applied Nano Materials· Volume 7· Issue 12
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Abstract

The photothermal energy conversion mechanism in pseudocapacitive nanoelectrodes endures temperature-enervated power dissipation due to self-heating, leading to rapid heating and cooling cycles during the redox reactions triggered by plasmonic excitation. Herein, we report on vanadium nitride (VN)-intercalated reduced graphene oxide (RGO) nanosheets (VN@RGO) as a photoresponsive pseudocapacitive electrode material. Finite-difference time-domain (FDTD) simulations were used to analyze the photothermal-driven localized self-heating considering the complex dielectric properties of VN@RGO. The effect of morphology and stoichiometry on the polarization-induced electric field intensity (| E | 2 ), power absorption ( P abs ), and current density ( J ) of the VN@RGO system has been systematically explored. Both the simulation and experimental results complement each other. This study delineates electrically coupled thermal attenuation in VN@RGO, overcoming the limitations related to potential modulation of the electrode material. VN@RGO exhibits excellent electrochemical performance in the half-cell and full-cell modes of a symmetric supercapacitor, achieving maximum specific capacitances of 276 and 56 F g –1 at a current density of 0.1 A g –1, respectively.
Source: openalex_inverted_index · Quality: baseline

Research context

Energy storageNanomaterials

OpenAlex topics: Supercapacitor Materials and Fabrication · Advanced Sensor and Energy Harvesting Materials · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Departamento de Mecánica, Facultad de Ingeniería, Universidad Tecnológica Metropolitana, José Pedro Alessandri 1242, Ñuñoa, 7800003 Santiago, Chile

Laboratorio de Nanocompuestos, Departamento de Ingeniería de Materiales (DIMAT), Facultad de Ingeniería (FI), Universidad de Concepción (UdeC), Concepción 4030000, Chile

Laboratorio de Nanociencias y Nanotecnología, Facultad de Ciencias Físico Matemáticas (CICFM-FCFM), Universidad Autónoma de Nuevo León (UANL), San Nicolás de los Garza, Nuevo León 66451, Mexico

Department of Materials Science and Engineering, Graduate School of Energy Science and Technology, Chungnam National University, Daejeon 305-704, South Korea

Department of Chemistry, M.Kumarasamy College of Engineering, Karur 639113, Tamil Nadu,India

Nitte (Deemed to be University), Nanomaterials and Energy Devices Lab (NMEDL), Department of Mechanical Engineering, NMAM Institute of Technology, Nitte 574110, Karnataka, India

Department of Environmental Chemistry, Faculty of Sciences; Centro de Energía; and Centro de investigación en Biodiversidad y Ambientes Sustentables (CIBAS), Universidad Católica de la Santísima Concepción (UCSC), Concepción 4030000, Chile

Faculty of Engineering and Sciences, Universidad Adolfo Ibáñez, Diagonal las Torres 2640, Peñalolén, Santiago 7941169, Chile

Instituto Universitario de Investigación y Desarrollo Tecnológico (IDT), Universidad Tecnológica Metropolitana (UTEM), Ignacio Valdivieso 2409, San Joaquín, 7800003 Santiago, Chile

Department of Chemistry, National Institute of Technology, Tiruchirappalli 620 015, Tamil Nadu, India

Funding

NMAM Institute of Technology · National Research Foundation of Korea · Fondo Nacional de Desarrollo Cient?fico y Tecnol?gico · Universidad Cat?lica de la Sant?sima Concepci?n · Agencia Nacional de Investigaci?n y Desarrollo

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