journal article·2024-01

Preparation of PAN/GO composite nanofiber membrane for oil-containing wastewater treatment

Tong Lu, Qingxia Zhang, Jingjing Yang, Yue Xin, Zhilei Zhang, Lingye Hu, Jing Hu, Qin Qin, Hao Yang

Carbon Letters· Volume 34· Issue 1
Publisher page

Abstract

The discharge of industrial oily wastewater and oil spill accidents has resulted in significant environmental pollution, creating an urgent need for the treatment of oily wastewater. Nanofiber membranes, known for their high stability, flux, and efficiency, are widely employed in oil–water separation. This study systematically compared the performance of polyacrylonitrile/graphene oxide (PAN/GO) composite nanofiber membranes prepared through immersion and electrospinning methods for oily wastewater treatment. Experimental findings demonstrated that immersion-prepared membranes achieved high flux (772.9 ± 2.9 L·m−2·h−1, n-hexane/water mixture) and efficiency (98.8%) at a GO concentration of 1.0 g/mL. On the other hand, electrospinning-prepared membranes exhibited superior flux (1500.3 ± 4.4 L·m−2·h−1, n-hexane/water mixture) and efficiency (99.6%) at a higher GO concentration (1.5 g/mL). This membrane displayed excellent stability, maintaining their exceptional performance even after ten cycles of separation. This study compared the advantages and disadvantages of the two methods for preparation of PAN/GO composite nanofiber membrane, offering valuable guidance for practical applications.
Source: expertdata · Quality: candidate unverified · Source record ↗

Research context

OpenAlex topics: Membrane Separation Technologies · Electrospun Nanofibers in Biomedical Applications · Surface Modification and Superhydrophobicity

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (47)

Show source-provided references
1. Su RL, Li SM, Wu WL, Song C, Liu GQ, Yu Y (2021) Recent progress in electrospun nanofibrous membranes for oil/water separation. Sep Purif Technol 256:117790. https://doi.org/10.1016/j.seppur.2020.11779010.1016/j.seppur.2020.117790 ↗
2. Cozzarelli IM, Skalak KJ, Kent DB, Engle MA, Benthem A, Mumford AC, Haase K, Farag A, Harper D, Nagel SC, Iwanowicz LR, Orem WH, Akob DM, Jaeschke JB, Galloway J, Kohler M, Stoliker DL, Jolly GD (2017) Environmental signatures and effects of an oil and gas wastewater spill in the Williston Basin, North Dakota. Sci Total Environ 579:1781–1793. https://doi.org/10.1016/j.scitotenv.2016.11.15710.1016/j.scitotenv.2016.11.157 ↗
3. Burgos WD, Castillo-Meza L, Tasker TL, Geeza TJ, Drohan PJ, Liu XF, Landis JD, Blotevogel J, McLaughlin M, Borch T, Warner NR (2017) Watershed-scale impacts from surface water disposal of oil and gas wastewater in western Pennsylvania. Environ Sci Technol 51:8851–8860. https://doi.org/10.1021/acs.est.7b0169610.1021/acs.est.7b01696 ↗
4. Danellakis D, Ntaikou I, Kornaros M, Dailianis S (2011) Olive oil mill wastewater toxicity in the marine environment: alterations of stress indices in tissues of mussel mytilus galloprovincialis. Aquat Toxicol 101:358–366. https://doi.org/10.1016/j.aquatox.2010.11.01510.1016/j.aquatox.2010.11.015 ↗
5. Liu T, Tang QJ, Lu T, Zhu C, Li SD, Zhou CL, Yang H (2023) Metal-organic frameworks-based membranes with special wettability for oil-water separation: a review. Caotings 13:1241. https://doi.org/10.3390/coatings1307124110.3390/coatings13071241 ↗
6. Ge MZ, Cao CY, Huang JY, Zhang XN, Tang YX, Zhou XR, Zhang KQ, Chen Z, Lai YK (2018) Rational design of materials interface at nanoscale towards intelligent oil-water separation. Nanoscale Horiz 3:235–260. https://doi.org/10.1039/c7nh00185a10.1039/c7nh00185a ↗
7. Feng N, Yong JL (2020) Femtosecond laser microfabrication of porous superwetting materials for oil/water separation: a mini-review. Front Chem 8:585723. https://doi.org/10.3389/fchem.2020.58572310.3389/fchem.2020.585723 ↗
8. Dmitrieva ES, Anokhina TS, Novitsky EG, Volkov VV, Borisov IL, Volkov AV (2022) Polymeric membranes for oil-water separation: a review. Polymers 14:980. https://doi.org/10.3390/polym1405098010.3390/polym14050980 ↗
9. Su CP, Yang H, Zhao HP, Liu YL, Chen R (2017) Recyclable and biodegradable superhydrophobic and superoleophilic chitosan sponge for the effective removal of oily pollutants from water. Chem Eng J 330:423–432. https://doi.org/10.1016/j.cej.2017.07.15710.1016/j.cej.2017.07.157 ↗
10. Xu SH, Tang QJ, Li SJ, Liao TF, Cheng HJ, Lu T, Jiang N, Lu Z, Zhou CL, Yang H (2023) Preparation of underwater superoleophobic ZIF-67 composite membrane with high antibacterial activity and emulsion separation efficiency. J Environ Chem Eng 11:110078. https://doi.org/10.1016/j.jece.2023.11007810.1016/j.jece.2023.110078 ↗
11. Zhou CL, Chen ZD, Yang H, Hou K, Zeng XJ, Zheng YF, Cheng J (2017) Nature-inspired strategy toward superhydrophobic fabrics for versatile oil/water separation. ACS Appl Mater Interfaces 9:9184–9194. https://doi.org/10.1021/acsami.7b0041210.1021/acsami.7b00412 ↗
12. Cui JY, Zhou ZP, Xie AT, Meng MJ, Cui YH, Liu SW, Lu J, Zhou S, Yan YS, Dong HJ (2019) Bio-inspired fabrication of superhydrophilic nanocomposite membrane based on surface modification of SiO2 anchored by polydopamine towards effective oil-water emulsions separation. Sep Purif Technol 209:434–442. https://doi.org/10.1016/j.seppur.2018.03.05410.1016/j.seppur.2018.03.054 ↗
13. Xu PL, Na N (2020) Study on antibacterial properties of cellulose acetate seawater desalination reverse-osmosis membrane with graphene oxide. J Coast Res 105:246–251. https://doi.org/10.2112/jcr-si105-052.110.2112/jcr-si105-052.1 ↗
14. Tanudjaja HJ, Hejase CA, Tarabara VV, Fane AG, Chew JW (2019) Membrane-based separation for oily wastewater: a practical perspective. Water Res 156:347–365. https://doi.org/10.1016/j.watres.2019.03.02110.1016/j.watres.2019.03.021 ↗
15. Pan XC, Lamson M, Yan JJ, Matyjaszewski K (2015) Photoinduced metal-free atom transfer radical polymerization of acrylonitrile. ACS Macro Lett 4:192–196. https://doi.org/10.1021/mz500834g10.1021/mz500834g ↗
16. Wang R, Guan SH, Sato AN, Wang X, Wang Z, Yang R, Hsiao BS, Chu B (2013) Nanofibrous microfiltration membranes capable of removing bacteria, viruses and heavy metal ions. J Membr Sci 446:376–382. https://doi.org/10.1016/j.memsci.2013.06.02010.1016/j.memsci.2013.06.020 ↗
17. Lu XY, Geng YZ, Jia ZQ, Yang Y, Huang HO, Men Y, Hou LA (2021) In situ syntheses of Nh2-Mil-53/PVDF composite membranes for dyes separation. Sep Purif Technol 269:118760. https://doi.org/10.1016/j.seppur.2021.11876010.1016/j.seppur.2021.118760 ↗
18. Yu YX, Ma QY, Zhang JB, Liu GB (2020) Electrospun SiO2 aerogel/polyacrylonitrile composited nanofibers with enhanced adsorption performance of volatile organic compounds. Appl Surf Sci 512:145697. https://doi.org/10.1016/j.apsusc.2020.14569710.1016/j.apsusc.2020.145697 ↗
19. Chen YN, Liu N, Cao YZ, Lin X, Xu LX, Zhang WF, Wei Y, Feng L (2016) Fabrication of silica nanospheres coated membranes: towards the effective separation of oil-in-water emulsion in extremely acidic and concentrated salty environments. Sci Rep 6:32540. https://doi.org/10.1038/srep3254010.1038/srep32540 ↗
20. Melbiah JSB, Nithya D, Mohan D (2017) Surface modification of polyacrylonitrile ultrafiltration membranes using amphiphilic pluronic F127/CaCO3 nanoparticles for oil/water emulsion separation. Colloids Surf A 516:147–160. https://doi.org/10.1016/j.colsurfa.2016.12.00810.1016/j.colsurfa.2016.12.008 ↗
21. Geng Q, Pu Y, Li YJ, Yang X, Wu HZ, Dong SJ, Yuan D, Ning X (2022) Multi-component nanofiber composite membrane enabled high PM0.3 removal efficiency and oil/water separation performance in complex environment. J Hazard Mater 422:126835. https://doi.org/10.1016/j.jhazmat.2021.12683510.1016/j.jhazmat.2021.126835 ↗
22. Zhang F, Gao SJ, Zhu YZ, Jin J (2016) Alkaline-induced superhydrophilic/underwater superoleophobic polyacrylonitrile membranes with ultralow oil-adhesion for high-efficient oil/water separation. J Membr Sci 513:67–73. https://doi.org/10.1016/j.memsci.2016.04.02010.1016/j.memsci.2016.04.020 ↗
23. Xiao SJ, Yu SW, Yan L, Liu Y, Tan XY (2017) Preparation and properties of PPSU/GO mixed matrix membrane. Chin J Chem Eng 25:408–414. https://doi.org/10.1016/j.cjche.2017.02.00910.1016/j.cjche.2017.02.009 ↗
24. Wang HT, Wang W, Wang L, Zhao B, Zhang ZH, Xia XM, Yang HF, Xue Y, Chang N (2018) Enhancement of hydrophilicity and the resistance for irreversible fouling of polysulfone (PSF) membrane immobilized with graphene oxide (GO) through chloromethylated and quaternized reaction. Chem Eng J 334:2068–2078. https://doi.org/10.1016/j.cej.2017.11.13510.1016/j.cej.2017.11.135 ↗
25. Song N, Sun YC, Xie X, Wang D, Shao FF, Yu LY, Dong LF (2020) Doping MIL-101(Cr)@GO in polyamide nanocomposite membranes with improved water flux. Desalination 492:114601. https://doi.org/10.1016/j.desal.2020.11460110.1016/j.desal.2020.114601 ↗
26. Yang M, Chen YY, Wang HT, Zou YL, Wu PX, Zou J, Jiang JZ (2022) Solvothermal preparation of CeO2 nanoparticles-graphene nanocomposites as an electrochemical sensor for sensitive detecting pentachlorophenol. Carbon Lett 32:1277–1285. https://doi.org/10.1007/s42823-022-00353-710.1007/s42823-022-00353-7 ↗
27. Deng FX, Jiang JZ, Sires I (2023) State-of-the-art review and bibliometric analysis on electro-Fenton process. Carbon Lett 33:17–34. https://doi.org/10.1007/s42823-022-00420-z10.1007/s42823-022-00420-z ↗
28. Zou J, Wu SL, Liu Y, Sun YJ, Cao Y, Hsu JP, Wee ATS, Jiang JZ (2018) An ultra-sensitive electrochemical sensor based on 2D g-C3N4/CuO nanocomposites for dopamine detection. Carbon 130:652–663. https://doi.org/10.1016/j.carbon.2018.01.00810.1016/j.carbon.2018.01.008 ↗
29. Wang JM, Qin Q, Li FY, Anjarsari Y, Sun W, Azzahiidah R, Zou J, Xiang K, Ma HJ, Jiang JZ, Arramel (2023) Recent advances of MXenes Mo2C-based materials for efficient photocatalytic hydrogen evolution reaction. Carbon Lett 33:1381–1394. https://doi.org/10.1007/s42823-022-00401-210.1007/s42823-022-00401-2 ↗
30. Jiang JZ, Bai SS, Yang MQ, Zou J, Li N, Peng JH, Wang HT, Xiang K, Liu S, Zhai TY (2022) Strategic design and fabrication of MXenes-Ti3CNCl2@CoS2 core-shell nanostructure for high-efficiency hydrogen evolution. Nano Res 15:5977–5986. https://doi.org/10.1007/s12274-022-4276-810.1007/s12274-022-4276-8 ↗
31. Li FY, Anjarsari Y, Wang JM, Azzahiidah R, Jiang JZ, Zou J, Xiang K, MaArramel, HJ (2023) Modulation of the lattice structure of 2D carbon-based materials for improving photo/electric properties. Carbon Lett 33:1321–1331. https://doi.org/10.1007/s42823-022-00380-410.1007/s42823-022-00380-4 ↗
32. Wang QQ, Li GH, Zhang JN, Huang FL, Lu KY, Wei QF (2014) PAN nanofibers reinforced with MMT/GO hybrid nanofillers. J Nanomater 2014:298021. https://doi.org/10.1155/2014/29802110.1155/2014/298021 ↗
33. Zhang MC, Sun JJ, Mao YY, Liu GP, Jin WQ (2019) Effect of substrate on formation and nanofiltration performance of graphene oxide membranes. J Membr Sci 574:196–204. https://doi.org/10.1016/j.memsci.2018.12.07110.1016/j.memsci.2018.12.071 ↗
34. Zhang JQ, Pan XL, Xue QZ, He DL, Zhu L, Guo QK (2017) Antifouling hydrolyzed polyacrylonitrile/graphene oxide membrane with spindle-knotted structure for highly effective separation of oil-water emulsion. J Membr Sci 532:38–46. https://doi.org/10.1016/j.memsci.2017.03.00410.1016/j.memsci.2017.03.004 ↗
35. Song S, Yang H, Su CP, Jiang ZB, Lu Z (2016) Ultrasonic-microwave assisted synthesis of stable reduced graphene oxide modified melamine foam with superhydrophobicity and high oil adsorption capacities. Chem Eng J 306:504–511. https://doi.org/10.1016/j.cej.2016.07.08610.1016/j.cej.2016.07.086 ↗
36. Lee JH, Li S, Yoo JB, Kim YJ (2021) Effects of various transition metals on the thermal oxidative stabilization of polyacrylonitrile nanofibers. J Inorg Organomet Polym Mater 31:3368–3377. https://doi.org/10.1007/s10904-021-01954-x10.1007/s10904-021-01954-x ↗
37. Lin YZ, Zhong LB, Dou S, Shao ZD, Liu Q, Zheng YM (2019) Facile synthesis of electrospun carbon nanofiber/graphene oxide composite aerogels for high efficiency oils absorption. Environ Int 128:37–45. https://doi.org/10.1016/j.envint.2019.04.01910.1016/j.envint.2019.04.019 ↗
38. Li JH, Zhang H, Zhang W, Liu WL (2019) Nanofiber membrane of graphene oxide/polyacrylonitrile with highly efficient antibacterial activity. J Biomat Sci-polym E 30:1620–1635. https://doi.org/10.1080/09205063.2019.165279310.1080/09205063.2019.1652793 ↗
39. Sanchez-Lopez L, Chico B, Llorente I, Escudero ML, Lozano RM, Garcia-Alonso MC (2022) Covalent immobilization of graphene oxide on biomedical grade CoCr alloy by an improved multilayer system assembly via silane/go bonding. Mater Chem Phys 287:126296. https://doi.org/10.1016/j.matchemphys.2022.12629610.1016/j.matchemphys.2022.126296 ↗
40. Baek GY, Lee HS, Jung JM, Hwang IT, Shin J, Jung CH, Choi JH (2018) Preparation of conductive carbon films from polyacrylonitrile/graphene oxide composite films by thermal treatment. J Ind Eng Chem 58:87–91. https://doi.org/10.1016/j.jiec.2017.09.01110.1016/j.jiec.2017.09.011 ↗
41. Mousakhani M, Sarlak N (2020) Electrospun composite nanofibre adsorbents for effective removal of Cd2+ from polluted water. Mater Chem Phys 256:123578. https://doi.org/10.1016/j.matchemphys.2020.12357810.1016/j.matchemphys.2020.123578 ↗
42. Sahoo SK, Panigrahi GK, Sahoo JK, Pradhan AK, Purohit AK, Dhal JP (2021) Electrospun magnetic polyacrylonitrile-GO hybrid nanofibers for removing Cr(VI) from water. J Mol Liq 326:115364. https://doi.org/10.1016/j.molliq.2021.11536410.1016/j.molliq.2021.115364 ↗
43. Ederer J, Ecorchard P, Slusna MS, Tolasz J, Smrzova D, Lupinkova S, Janos P (2022) A study of methylene blue dye interaction and adsorption by monolayer graphene oxide. Adsorpt Sci Technol 2022:7385541. https://doi.org/10.1155/2022/738554110.1155/2022/7385541 ↗
44. Park S, An J, Potts JR, Velamakanni A, Murali S, Ruoff RS (2011) Hydrazine-reduction of graphite- and graphene oxide. Carbon 49:3019–3023. https://doi.org/10.1016/j.carbon.2011.02.07110.1016/j.carbon.2011.02.071 ↗
45. Wang YX, Chen MN, Tao H (2020) Preparation of nested g-C3N4 fiber Surrounding graphene oxide and its photocatalytic degradation of rhodamine B. J Nanosci Nanotechnol 20:5445–5451. https://doi.org/10.1166/jnn.2020.1788010.1166/jnn.2020.17880 ↗
46. Guex LG, Sacchi B, Peuvot KF, Andersson RL, Pourrahimi AM, Strom V, Farris S, Olsson RT (2017) Experimental review: chemical reduction of graphene oxide (GO) to reduced graphene oxide (rGO) by aqueous chemistry. Nanoscale 9:9562–9571. https://doi.org/10.1039/c7nr02943h10.1039/c7nr02943h ↗
47. Yang D, Velamakanni A, Bozoklu G, Park S, Stoller M, Piner RD, Stankovich S, Jung I, Field DA, Ventrice CA, Ruoff RS (2009) Chemical analysis of graphene oxide films after heat and chemical treatments by X-ray photoelectron and Micro-Raman spectroscopy. Carbon 47:145–152. https://doi.org/10.1016/j.carbon.2008.09.04510.1016/j.carbon.2008.09.045 ↗