Heterojunction-Forming In–NiS/In₂O₃ Nanoparticles for the Photocatalytic Degradation of Tetracycline under Full Solar Spectrum Response

Zhenxing Ren; Yang Li; Qiuyu Ren; Hongbo Zhou; Xiaojie Zhang; Mengliang Wang; Xinjuan Liu; Likun Pan

doi:10.1021/acsanm.4c02460

journal article·2024-08-09

Heterojunction-Forming In–NiS/In₂O₃ Nanoparticles for the Photocatalytic Degradation of Tetracycline under Full Solar Spectrum Response

Zhenxing Ren, Yang Li, Qiuyu Ren, Hongbo Zhou, Xiaojie Zhang, Mengliang Wang, Xinjuan Liu, Likun Pan

ACS Applied Nano Materials· Volume 7· Issue 15

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Source abstract

Abstract

Exploring full solar spectrum-responsive heterojunction photocatalysts continues to pose significant challenges. In this study, In–NiS/In 2 O 3 heterojunctions are constructed by introducing a high concentration of low-coordination-vacancy atoms for photocatalytic degradation of tetracycline (TC). In–NiS/In 2 O 3 heterojunctions show a nanoparticle structure and good light absorption in the full solar spectrum with 200–2400 nm and achieve the highest degradation rate of 99.3% under infrared light irradiation, as well as favorable photostability. The improved photocatalytic activity is attributed to the enhanced light absorption range and charge separation efficiency owing to the introduction of low-coordination-vacancy atoms. Moreover, the main active species are h + and·O 2 – in the TC degradation process.

Source: openalex_inverted_index · Quality: baseline

Research context

Nanomaterials Catalysis & surfaces

OpenAlex topics: Advanced Photocatalysis Techniques · Gas Sensing Nanomaterials and Sensors · ZnO doping and properties

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, P. R. China

National & Local Joint Engineering Research Center for Mineral Salt Deep Utilization, Huaiyin Institute of Technology, Huaian 223003, P. R. China

School of Materials and Chemistry, University of Shanghai for Science and Technology, Shanghai 200093, P. R. China

Shanghai Key Laboratory of Magnetic Resonance, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, P. R. China

Funding

Shanghai Municipal Education Commission · Science and Technology Commission of Shanghai Municipality · National Natural Science Foundation of China · National & Local Joint Engineering Research Center for Deep Utilization Technology of Rock-salt Resource

References (60)

Show source-provided references

1. 10.1016/j.cej.2021.13234410.1016/j.cej.2021.132344 ↗

2. 10.1016/j.chemosphere.2023.13783410.1016/j.chemosphere.2023.137834 ↗

3. 10.1016/j.solener.2024.11234010.1016/j.solener.2024.112340 ↗

4. 10.1016/j.joule.2023.05.02210.1016/j.joule.2023.05.022 ↗

5. 10.1016/j.ijhydene.2024.02.28710.1016/j.ijhydene.2024.02.287 ↗

6. 10.1038/s41586-022-05399-110.1038/s41586-022-05399-1 ↗

7. 10.1016/S1872-2067(21)63910-410.1016/S1872-2067(21)63910-4 ↗

8. 10.1016/j.ccr.2022.21444010.1016/j.ccr.2022.214440 ↗

9. 10.1021/acsanm.3c0049410.1021/acsanm.3c00494 ↗

10. 10.1016/j.jallcom.2024.17351010.1016/j.jallcom.2024.173510 ↗

11. 10.1002/adfm.20200759110.1002/adfm.202007591 ↗

12. 10.1016/j.jcis.2021.04.06410.1016/j.jcis.2021.04.064 ↗

13. 10.1039/D1TA04614D10.1039/D1TA04614D ↗

14. 10.1039/C9RA02822F10.1039/C9RA02822F ↗

15. 10.1016/j.ijoes.2023.10043410.1016/j.ijoes.2023.100434 ↗

16. 10.1007/s10853-022-07752-110.1007/s10853-022-07752-1 ↗

17. 10.1016/j.ijhydene.2024.02.11310.1016/j.ijhydene.2024.02.113 ↗

18. 10.1016/j.jcis.2021.01.02210.1016/j.jcis.2021.01.022 ↗

19. 10.1016/j.optmat.2020.11013810.1016/j.optmat.2020.110138 ↗

20. 10.1016/j.colsurfa.2021.12700510.1016/j.colsurfa.2021.127005 ↗

21. 10.1021/acsanm.9b0077810.1021/acsanm.9b00778 ↗

22. 10.3390/nano1313190910.3390/nano13131909 ↗

23. 10.1039/D3CC05089K10.1039/D3CC05089K ↗

24. 10.1002/adfm.20210231510.1002/adfm.202102315 ↗

25. 10.1002/smll.20200455710.1002/smll.202004557 ↗

26. 10.1021/ie503241k10.1021/ie503241k ↗

27. 10.1016/j.apcatb.2017.06.00210.1016/j.apcatb.2017.06.002 ↗

28. 10.1038/s41560-023-01218-710.1038/s41560-023-01218-7 ↗

29. 10.1021/acsanm.9b0235710.1021/acsanm.9b02357 ↗

30. 10.1038/s41467-022-28995-110.1038/s41467-022-28995-1 ↗

31. 10.1039/D2NJ06217H10.1039/D2NJ06217H ↗

32. 10.1016/j.jcis.2024.06.04010.1016/j.jcis.2024.06.040 ↗

33. 10.1002/cey2.30510.1002/cey2.305 ↗

34. 10.1016/j.gee.2021.11.00210.1016/j.gee.2021.11.002 ↗

35. 10.1016/j.apmate.2021.11.00810.1016/j.apmate.2021.11.008 ↗

36. 10.1016/j.apcatb.2019.02.06110.1016/j.apcatb.2019.02.061 ↗

37. 10.1038/srep3530410.1038/srep35304 ↗

38. 10.1016/j.jcis.2016.10.07710.1016/j.jcis.2016.10.077 ↗

39. 10.1016/j.jcis.2017.09.04210.1016/j.jcis.2017.09.042 ↗

40. 10.1016/j.cattod.2018.01.02110.1016/j.cattod.2018.01.021 ↗

41. 10.1002/aoc.535410.1002/aoc.5354 ↗

42. 10.1038/s41467-023-37358-310.1038/s41467-023-37358-3 ↗

43. 10.1002/adfm.20200800810.1002/adfm.202008008 ↗

44. 10.1016/j.ccr.2024.21593610.1016/j.ccr.2024.215936 ↗

45. 10.1016/j.cej.2022.13726210.1016/j.cej.2022.137262 ↗

46. 10.1016/j.seppur.2021.11836610.1016/j.seppur.2021.118366 ↗

47. 10.1016/j.cej.2020.12783810.1016/j.cej.2020.127838 ↗

48. 10.1016/j.pnsc.2024.02.00410.1016/j.pnsc.2024.02.004 ↗

49. 10.1016/j.cej.2020.12718010.1016/j.cej.2020.127180 ↗

50. 10.1021/acscatal.8b0205610.1021/acscatal.8b02056 ↗

51. 10.1016/j.cej.2020.12526310.1016/j.cej.2020.125263 ↗

52. 10.1016/j.envres.2021.11136010.1016/j.envres.2021.111360 ↗

53. 10.1002/adma.20210766810.1002/adma.202107668 ↗

54. 10.1016/j.vacuum.2021.11006110.1016/j.vacuum.2021.110061 ↗

55. 10.1016/j.pnsc.2024.02.00310.1016/j.pnsc.2024.02.003 ↗

56. 10.1016/j.apcatb.2017.08.04610.1016/j.apcatb.2017.08.046 ↗

57. 10.1016/j.jcis.2023.04.10810.1016/j.jcis.2023.04.108 ↗

58. 10.1021/acsnano.3c0901110.1021/acsnano.3c09011 ↗

59. 10.1016/j.nantod.2023.10206610.1016/j.nantod.2023.102066 ↗

60. 10.1016/j.cej.2024.15015410.1016/j.cej.2024.150154 ↗