journal article·2023-09-22

Building CO2 Transport Channels in Mixed Matrix Membranes Using SiO2 Nanosheets

Jinpeng Hou, Libin Hu, Feng Ren, Yongli Zhao, Weiliang Tian, Yun Qin

ACS Applied Nano Materials· Volume 6· Issue 18
Publisher page

Abstract

With the use of the polyether–polyamide block copolymer (Pebax) as a polymer membrane matrix, two-dimensional silicon dioxide (SiO 2 ) nanosheets were obtained through the acid treatment of vermiculite and applied as fillers to prepare mixed matrix membranes (MMMs) with different filler amounts. Building transport channels for CO 2 transfer in the membranes and enhancing the separation performance of CO 2 /CH 4 are feasible owing to the structure of the SiO 2 nanosheets and their propensity for horizontal alignment in the MMMs. The investigation of the characteristics and gas separation capabilities of Pebax–SiO 2 MMMs revealed that the combination of SiO 2 nanosheets considerably improved the separation effect of the MMM S in the CO 2 /CH 4 system. The Pebax–SiO 2 MMMs demonstrated an excellent CO 2 separation efficiency with a CO 2 permeation coefficient of 313.24 barrer and a CO 2 /CH 4 selectivity of 31.26 at the filling quantity of 1.0 wt %.
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Research context

OpenAlex topics: Membrane Separation and Gas Transport · Muon and positron interactions and applications · Covalent Organic Framework Applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

School of Chemistry and Chemical Engineering, Tarim University, Alar, Xinjiang 843300, China

State Key Laboratory of Organic−Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

Xinjiang University of Science and Technology, Korla, Xinjiang 84100, China

Funding

National Natural Science Foundation of China · Tarim University · State Key Laboratory of Organic Inorganic Composites, Beijing University of Chemical Technology · First Division Alar Science and Technology Plan Project in Xinjiang Corps

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