LEGO-like assembly of peelable, deformable components for integrated devices
Source abstract
Abstract
The development of various technologies has led to the advent of a variety of deformable devices. Despite significant technological advancement in this area, it is still challenging to integrate different devices due to limitations such as substrate issues and differences among growth and deposition conditions. Creating an interconnection between two different devices currently requires the use of metallic wires/lines to build electrical connections. Here, we demonstrate a LEGO-like assembly of the free-standing film of individually operable components encapsulated in a polymer overcoat layer, leading to the production of an integrated architecture without additional electrical connections. The free-standing components are produced by the peeling-off process. The sticky nature of the polymer layer enables the construction of supercapacitor arrays and simple RLC circuits by interlocking the individual components. We expect that this approach will enable the fabrication of a variety of custom-built devices using a LEGO-like assembly method. We demonstrate a LEGO-like assembly of free-standing film of individually operable components encapsulated in a polymer overcoat layer, leading to the integrated architecture without additional electrical connection. The free-standing components are produced by the peeling-off process. The sticky nature of polymer layer enables the construction of supercapacitor arrays and simple RLC circuits through interlocking the individual components. In a collaboration between South Korea and the United States, John Rogers, Ungyu Paik and co-workers have developed a simple process to fabricate flexible circuits by assembling the separate components in the manner of Lego blocks. The researchers first prepared each part — for example a resistor, inductor or capacitor — by depositing metal layers on a common substrate comprising a silicon dioxide wafer. Next, they grew carbon nanotubes at locations determined to be electrodes and subsequently added a gel electrolyte layer. On drying, this gel converts to a sticky polymer that incorporates the required component and can be peeled away from the substrate. The resulting film is flexible and resistant to repeated bending, folding and stretching. Lastly, these free-standing components were simply interlocked into an integrated circuit without the need for further electrical connections. Poly(vinyl alcohol), the polymer used in the study, can also be functionalized, enabling the creation of more complex devices.
Source: openalex_inverted_index · Quality: baseline
Research context
OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Supercapacitor Materials and Fabrication · Advanced Materials and Mechanics
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (31)
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1. Kim, D. H., Ahn, J. H., Choi, W. M., Kim, H. S., Kim, T. H., Song, J. Z., Huang, Y. G. Y., Liu, Z. J., Lu, C. & Rogers, J. A. Stretchable and foldable silicon integrated circuits. Science 320, 507–511 (2008).10.1126/science.1154367 ↗
2. Kim, D. H., Kim, Y. S., Wu, J., Liu, Z. J., Song, J. Z., Kim, H. S., Huang, Y. G. Y., Hwang, K. C. & Rogers, J. A. Ultrathin silicon circuits with strain-isolation layers and mesh layouts for high-performance electronics on fabric, vinyl, leather, and paper. Adv. Mater. 21, 3703–3707 (2009).10.1002/adma.200900405 ↗
3. Kim, D. H., Viventi, J., Amsden, J. J., Xiao, J. L., Vigeland, L., Kim, Y. S., Blanco, J. A., Panilaitis, B., Frechette, E. S., Contreras, D., Kaplan, D. L., Omenetto, F. G., Huang, Y. G., Hwang, K. C., Zakin, M. R., Litt, B. & Rogers, J. A. Dissolvable films of silk fibroin for ultrathin conformal bio-integrated electronics. Nat. Mater. 9, 511–517 (2010).10.1038/nmat2745 ↗
4. Kim, D. H., Lu, N. S., Ma, R., Kim, Y. S., Kim, R. H., Wang, S. D., Wu, J., Won, S. M., Tao, H., Islam, A., Yu, K. J., Kim, T. I., Chowdhury, R., Ying, M., Xu, L. Z., Li, M., Chung, H. J., Keum, H., McCormick, M., Liu, P., Zhang, Y. W., Omenetto, F. G., Huang, Y. G., Coleman, T. & Rogers, J. A. Epidermal electronics. Science 333, 838–843 (2011).10.1126/science.1206157 ↗
5. Wu, H., Hu, L. B., Carney, T., Ruan, Z. C., Kong, D. S., Yu, Z. F., Yao, Y., Cha, J. J., Zhu, J., Fan, S. H. & Cui, Y. Low reflectivity and high flexibility of tin-doped indium oxide nanofiber transparent electrodes. J. Am. Chem. Soc. 133, 27–29 (2011).10.1021/ja109228e ↗
6. Gelinck, G. H., Huitema, H. E. A., Van Veenendaal, E., Cantatore, E., Schrijnemakers, L., Van der Putten, J. B. P. H., Geuns, T. C. T., Beenhakkers, M., Giesbers, J. B., Huisman, B. H., Meijer, E. J., Benito, E. M., Touwslager, F. J., Marsman, A. W., Van Rens, B. J. E. & De Leeuw, D. M. Flexible active-matrix displays and shift registers based on solution-processed organic transistors. Nat. Mater. 3, 106–110 (2004).10.1038/nmat1061 ↗
7. Sekitani, T., Noguchi, Y., Hata, K., Fukushima, T., Aida, T. & Someya, T. A rubberlike stretchable active matrix using elastic conductors. Science 321, 1468–1472 (2008).10.1126/science.1160309 ↗
8. Sekitani, T., Nakajima, H., Maeda, H., Fukushima, T., Aida, T., Hata, K. & Someya, T. Stretchable active-matrix organic light-emitting diode display using printable elastic conductors. Nat. Mater. 8, 494–499 (2009).10.1038/nmat2459 ↗
9. Cao, Q., Kim, H. S., Pimparkar, N., Kulkarni, J. P., Wang, C. J., Shim, M., Roy, K., Alam, M. A. & Rogers, J. A. Medium-scale carbon nanotube thin-film integrated circuits on flexible plastic substrates. Nature 454, 495–500 (2008).10.1038/nature07110 ↗
10. Sun, D. M., Timmermans, M. Y., Tian, Y., Nasibulin, A. G., Kauppinen, E. I., Kishimoto, S., Mizutani, T. & Ohno, Y. Flexible high-performance carbon nanotube integrated circuits. Nat. Nanotechnol. 6, 156–161 (2011).10.1038/nnano.2011.1 ↗
11. Kim, R. H., Bae, M. H., Kim, D. G., Cheng, H. Y., Kim, B. H., Kim, D. H., Li, M., Wu, J., Du, F., Kim, H. S., Kim, S., Estrada, D., Hong, S. W., Huang, Y. G., Pop, E. & Rogers, J. A. Stretchable, transparent graphene interconnects for arrays of microscale inorganic light emitting diodes on rubber substrates. Nano Lett. 11, 3881–3886 (2011).10.1021/nl202000u ↗
12. Lee, S. K., Kim, B. J., Jang, H., Yoon, S. C., Lee, C., Hong, B. H., Rogers, J. A., Cho, J. H. & Ahn, J. H. Stretchable graphene transistors with printed dielectrics and gate electrodes. Nano Lett. 11, 4642–4646 (2011).10.1021/nl202134z ↗
13. Kim, D. H., Xiao, J. L., Song, J. Z., Huang, Y. G. & Rogers, J. A. Stretchable, curvilinear electronics based on inorganic materials. Adv. Mater. 22, 2108–2124 (2010).10.1002/adma.200902927 ↗
14. Meitl, M. A., Zhu, Z. T., Kumar, V., Lee, K. J., Feng, X., Huang, Y. Y., Adesida, I., Nuzzo, R. G. & Rogers, J. A. Transfer printing by kinetic control of adhesion to an elastomeric stamp. Nat. Mater. 5, 33–38 (2006).10.1038/nmat1532 ↗
15. Yoon, J., Jo, S., Chun, I. S., Jung, I., Kim, H. S., Meitl, M., Menard, E., Li, X. L., Coleman, J. J., Paik, U. & Rogers, J. A. GaAs photovoltaics and optoelectronics using releasable multilayer epitaxial assemblies. Nature 465, 329–333 (2010).10.1038/nature09054 ↗
16. Sun, Y. G. & Rogers, J. A. Inorganic semiconductors for flexible electronics. Adv. Mater. 19, 1897–1916 (2007).10.1002/adma.200602223 ↗
17. Loo, Y.-L., Someya, T., Baldwin, K. W., Bao, Z., Ho, P., Dodabalapur, A., Katz, H. E. & Rogers, J. A. Soft, conformable electrical contacts for organic semiconductors: High-resolution plastic circuits by lamination. Proc. Natl. Acad. Sci. USA 99, 10252–10256 (2002).10.1073/pnas.162128299 ↗
18. Kim, J. B., Lee, S., Toney, M. F., Chen, Z., Facchetti, A., Kim, Y. S. & Loo, Y.-L. Reversible soft-contact lamination and delamination for non-invasive fabrication and characterization of bulk-heterojunction and bilayer organic solar cells. Chem. Mater. 22, 4931–4938 (2010).10.1021/cm101692a ↗
19. Wang, H., Zhang, L., Tan, X., Holt, C. M. B., Zahiri, B., Olsen, B. C. & Mitlin, D. Supercapacitive properties of hydrothermally synthesized co3o4 nanostructures. J. Phys. Chem. C 115, 17599–17605 (2011).10.1021/jp2049684 ↗
20. Croll, S. G. Origin of residual internal-stress in solvent-cast thermoplastic coatings. J. Appl. Polym. Sci. 23, 847–858 (1979).10.1002/app.1979.070230319 ↗
21. Masuda, M. in Polyvinyl Alcohol — Developments ed. Finch C. A., Ch. 12, 404–431 Wiley: New York, USA, (1992).
22. Prajapati, G. K., Roshan, R. & Gupta, P. N. Effect of plasticizer on ionic transport and dielectric properties of PVA-H3PO4 proton conducting polymeric electrolytes. J. Phys. Chem. Solids 71, 1717–1723 (2010).10.1016/j.jpcs.2010.08.023 ↗
23. Smythe, E. J., Dickey, M. D., Whitesides, G. M. & Capasso, F. A technique to transfer metallic nanoscale patterns to small and non-planar surfaces. ACS Nano 3, 59–65 (2009).10.1021/nn800720r ↗
24. Wedin, P., Lewis, J. A. & Bergström, L. Soluble organic additive effects on stress development during drying of calcium carbonate suspensions. J. Colloid Interface Sci. 290, 134–144 (2005).10.1016/j.jcis.2005.04.020 ↗
25. Pech, D., Brunet, M., Durou, H., Huang, P. H., Mochalin, V., Gogotsi, Y., Taberna, P. L. & Simon, P. Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon. Nat. Nanotechnol. 5, 651–654 (2010).10.1038/nnano.2010.162 ↗
26. Gao, W., Singh, N., Song, L., Liu, Z., Reddy, A. L. M., Ci, L. J., Vajtai, R., Zhang, Q., Wei, B. Q. & Ajayan, P. M. Direct laser writing of micro-supercapacitors on hydrated graphite oxide films. Nat. Nanotechnol. 6, 496–500 (2011).10.1038/nnano.2011.110 ↗
27. Kaempgen, M., Chan, C. K., Ma, J., Cui, Y. & Gruner, G. Printable thin film supercapacitors using single-walled carbon nanotubes. Nano Lett. 9, 1872–1876 (2009).10.1021/nl8038579 ↗
28. Lu, X. H., Zheng, D. Z., Zhai, T., Liu, Z. Q., Huang, Y. Y., Xie, S. L. & Tong, Y. X. Facile synthesis of large-area manganese oxide nanorod arrays as a high-performance electrochemical supercapacitor. Energ. Environ. Sci. 4, 2915–2921 (2011).10.1039/c1ee01338f ↗
29. Xu, S., Zhang, Y., Cho, J., Lee, J., Huang, X., Jia, L., Fan, J. A., Su, Y., Su, J., Zhang, H., Cheng, H., Lu, B., Yu, C., Chuang, C., Kim, T.-i., Song, T., Shigeta, K., Kang, S., Dagdeviren, C., Petrov, I., Braun, P. V., Huang, Y., Paik, U. & Rogers, J. A. Stretchable batteries with self-similar serpentine interconnects and integrated wireless recharging systems. Nat. Commun. 4, 1543 (2013).10.1038/ncomms2553 ↗
30. Liu, Q., Zhao, F., Dong, X. H., Yang, C. H. & Chen, F. L. Synthesis and application of porous Sm0.2Ce0.8O1.9 nanocrystal aggregates. J. Phys. Chem. C 113, 17262–17267 (2009).10.1021/jp905745w ↗
31. Adhikari, B., Howes, T., Bhandari, B. R. & Truong, V. Stickiness in foods: a review of mechanisms and test methods. Int. J. Food Prop. 4, 1–33 (2001).10.1081/JFP-100002186 ↗