journal article·2016-12Open access

Restoration of thermally reduced graphene oxide by atomic-level selenium doping

Young Soo Yun, Gabin Yoon, Min Park, Se Youn Cho, Hee-Dae Lim, Haegyeom Kim, Yung Woo Park, Byung Hoon Kim, Kisuk Kang, Hyoung-Joon Jin

NPG Asia Materials· Volume 8· Issue 12

Abstract

The use of reduced graphene oxide (rGO) suffers from irreparable damage because of topological defects and residual heteroatoms, which degrade the inherent properties of graphene. To restore its electrical transport properties, charge-transfer chemical doping with d-electron-rich heteroatoms has been proposed. Herein, we report the effects of atomic-level selenium doping in rGO. Using first-principles calculations, we found that selenium atoms could be selectively bonded in particular locations, such as the pseudo-edge sites of hole-cluster defects in the basal plane and edge defect sites of graphene; however, we found that the intrinsic topological defects of the basal plane were unfavorable for bonding. Numerous selenium atoms were introduced on the fully amorphorized rGO surface, inducing a dramatic change of its electrical transport properties by electron doping. The large metallic regions formed by the selenium atoms on rGOs led to the enhancement of electrical conductivity by 210 S cm–1 at 300 K. Moreover, the temperature-dependent conductivities (σ)/σ20K of selenium-doped rGOs (Se-rGOs) were almost constant in the temperature range of 20–300 K, indicating that the carrier mobility of Se-rGOs becomes temperature-independent after selenium doping, similar to that of pure graphene. Atomic-thin layers of selenium can turn microscale graphene oxide sheets into enhanced energy-storage devices, reports a new study. Graphene's extraordinary conductivity has attracted interest for applications such as battery anodes, but manufacturers seeking sizeable quantities often use reduced graphene oxide – chemically synthesized carbon films containing oxygen and other defects that hinder charge transport. Hyoung-Joon Jin from Inha University in South Korea and colleagues now demonstrate that heating graphene oxide with elemental selenium returns metal-like conductivity to the carbon sheet through a process called surface transfer doping. Scanning electron microscopy and first-principles calculations revealed that selenium atoms attach to surface edge defect sites and transfer electrons to graphene oxide. These dopants enabled graphene oxide to achieve a similar battery capacity and longevity as pure graphene when incorporated in a prototype lithium-ion device. Selenium atoms were selectively introduced in particular locations such as the pseudo-edge sites of hole-cluster defects in the basal plane and edge defect sites of the fully amorphorized surface of reduced graphene oxide (rGO), inducing a dramatic change of electrical transport properties of rGO by electron doping.
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OpenAlex topics: Graphene research and applications · Advancements in Battery Materials · Supercapacitor Materials and Fabrication

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