Developing elastic foamed TPU fibers for dynamically daytime radiative cooling textile with buoyancy function
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Abstract
Abstract Porous materials are widely used in various scenarios due to their advantages such as good thermal insulation, flexibility, and ultra-lightness. Foaming technology has given porous materials more application areas by introducing uniformly distributed cellular structures into the polymer collective. In the past decade, we have conducted systematic studies around the preparation of multi-component polymer microporous materials and functional applications of porous materials. In this work, we propose the preparation of foamed TPU fibers and foamed fabrics (FT-fabric) with anisotropic cell structure using TPU as substrate by micro-extrusion foaming techniques. Thanks to the multistage cell distribution of the FT-fabric and the vibrational absorption of the polymer in the MIR band, the prepared FT-fabric has a near-infrared reflectance of >97%, which enables effective radiative cooling. The porous structure of the FT-fabric endows it with an ultra-low density, which is able to provide additional buoyancy in water. As a conceptual demonstration, FT-fabric is able to function as a cooling and buoyancy support in seaside scenarios, among other functions, providing a viable avenue for new functional garments.
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Research context
OpenAlex topics: Thermal Radiation and Cooling Technologies · Building Energy and Comfort Optimization · Radiative Heat Transfer Studies
SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.
References (48)
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1. Zhai, W., Jiang, J. & Park, C. B. A review on physical foaming of thermoplastic and vulcanized elastomers. Polym. Rev. 62, 95–141 (2022).10.1080/15583724.2021.1897996 ↗
2. Zhai, W. & Jiang, J. Fundamental issues for batch foaming of thermoplastic elastomers with supercritical fluids. Acta Polym. Sin. 55, 369–395 (2024).
3. Jiang, J., Liu, H., Tian, F., Chen, B. & Zhai, W. Progress on research and applications of polymeric foams and porous functional materials (in Chinese). Chin. Sci. Bull. 69, 2964–2977 (2024).10.1016/j.scib.2024.08.002 ↗
4. Wu, G. et al. A review of thermoplastic polymer foams for functional applications. J. Mater. Sci. 56, 11579–11604 (2021).10.1007/s10853-021-06034-6 ↗
5. Jiang, S., Agarwal, S. & Greiner, A. Low‐density open cellular sponges as functional materials. Angew. Chem. Int. Ed. 56, 15520–15538 (2017).10.1002/anie.201700684 ↗
6. Li, D. et al. High-expansion open-cell polylactide foams prepared by microcellular foaming based on stereocomplexation mechanism with outstanding oil–water separation. Polymers 15, 1984 (2023).10.3390/polym15091984 ↗
7. Sahoo, M. K. & Mandal, A. Design and analysis of three-dimensional foams: a review. Arch. Comput. Method Eng 113, 1–29 (2024).
8. Zhou, Y., Tian, Y. & Zhang, M. Technical development and application of supercritical CO2 foaming technology in PCL foam production. Sci. Rep. 14, 6825 (2024).10.1038/s41598-024-57545-6 ↗
9. Zhou, Y., Tian, Y. & Peng, X. Applications and challenges of supercritical foaming technology. Polymers 15, 402 (2023).10.3390/polym15020402 ↗
10. Cuadra-Rodriguez, D., Barroso-Solares, S. & Pinto, J. Advanced nanocellular foams: perspectives on the current knowledge and challenges. Nanomaterials 11, 621 (2021).10.3390/nano11030621 ↗
11. Azdast, T. & Hasanzadeh, R. Increasing cell density/decreasing cell size to produce microcellular and nanocellular thermoplastic foams: a review. J. Cell Plast. 57, 769–797 (2021).10.1177/0021955X20959301 ↗
12. Jiang, J. et al. Evolution of ordered structure of TPU in high-elastic state and their influences on the autoclave foaming of TPU and inter-bead bonding of expanded TPU beads. Polymer 228, 123872 (2021).10.1016/j.polymer.2021.123872 ↗
13. Jiang, J. et al. Microstructure development of PEBA and its impact on autoclave foaming behavior and iner-bead bonding of EPEBA beads. Polymer 256, 125244 (2022).10.1016/j.polymer.2022.125244 ↗
14. Ge, C., Wang, S., Zheng, W. & Zhai, W. Preparation of microcellular thermoplastic polyurethane (TPU) foam and its tensile property. Polym. Eng. Sci. 58, 158–166 (2018).10.1002/pen.24813 ↗
15. Ge, C. & Zhai, W. Cellular thermoplastic polyurethane thin film: Preparation, elasticity, and thermal insulation performance. Ind. Eng. Chem. Res. 57, 4688–4696 (2018).10.1021/acs.iecr.7b05037 ↗
16. Jiang, J., Zheng, H., Liu, H. & Zhai, W. Tunable cell structure and mechanism in porous thermoplastic polyurethane micro-film fabricated by a diffusion-restricted physical foaming process. J. Supercrit. Fluids 171, 105205 (2021).10.1016/j.supflu.2021.105205 ↗
17. Li, M., Jiang, J., Hu, B. & Zhai, W. Fused deposition modeling of hierarchical porous polyetherimide assisted by an in-situ CO2 foaming technology. Compos. Sci. Technol. 200, 108454 (2020).10.1016/j.compscitech.2020.108454 ↗
18. Zhai, W., Hu, B., Li, M., Jiang, J. & Zhou, M. Dimensional accuracy control and compressive property of microcellular polyetherimide honeycomb foams manufactured by an situ foaming fused deposition modeling technology. Adv. Eng. Mater. 23, 2001449 (2021).10.1002/adem.202001449 ↗
19. Chen, B. et al. Controlling the crystal morphology of high-hardness TPU through two pre-crystallization processes and its impact on physical foaming behavior. Polymer 305, 127172 (2024).10.1016/j.polymer.2024.127172 ↗
20. Tian, F., Huang, H., Li, Y. & Zhai, W. Fabrication of soft biodegradable foam with improved shrinkage resistance and thermal stability. Materials 17, 3712 (2024).10.3390/ma17153712 ↗
21. Jiang, J., Feng, W., Zhao, D. & Zhai, W. Poly (ether imide)/epoxy foam composites with a microcellular structure and ultralow density: Bead foam fabrication, compression molding, mechanical properties, thermal stability, and flame-retardant properties. ACS Omega 5, 26784–25797 (2020).10.1021/acsomega.0c03072 ↗
22. Zhang, C. et al. Wood-cellulose-fiber-based functional materials for triboelectric nanogenerators. Nano Energy 81, 105637 (2021).10.1016/j.nanoen.2020.105637 ↗
23. Abbood, I. S., aldeen, Odaa, S., Hasan, K. F. & Jasim, M. A. Properties evaluation of fiber reinforced polymers and their constituent materials used in structures–a review. Mater. Today Proc. 43, 1003–1008 (2021).10.1016/j.matpr.2020.07.636 ↗
24. Zhu, C., Wu, J., Yan, J. & Liu, X. Advanced fiber materials for wearable electronics. Adv. Fiber Mater. 5, 12–35 (2023).10.1007/s42765-022-00212-0 ↗
25. Shen, Y. et al. Review on fiber-based thermoelectrics: materials, devices, and textiles. Adv. Fiber Mater. 5, 1105–1140 (2023).10.1007/s42765-023-00267-7 ↗
26. Chen, C. et al. Functional fiber materials to smart fiber devices. Chem. Rev. 123, 613–662 (2022).10.1021/acs.chemrev.2c00192 ↗
27. Zhou, M. et al. Porous polyetherimide fiber fabricated by a facile micro-extrusion foaming for high temperature thermal insulation. J. CO2 Util. 65, 102247 (2022).10.1016/j.jcou.2022.102247 ↗
28. Sheng, Z. et al. The rising aerogel fibers: status, challenges, and opportunities. Adv. Sci. 10, 2205762 (2023).10.1002/advs.202205762 ↗
29. Huang, Y., Xiao, C., Huang, Q., Liu, H. & Zhao, J. Progress on polymeric hollow fiber membrane preparation technique from the perspective of green and sustainable development. Chem. Eng. J. 403, 126295 (2021).10.1016/j.cej.2020.126295 ↗
30. Huang, C. & Thomas, N. L. Fabrication of porous fibers via electrospinning: strategies and applications. Polym. Rev. 60, 595–647 (2020).10.1080/15583724.2019.1688830 ↗
31. Ge, P., Wang, S., Zhang, J. & Yang, B. Micro-/nanostructures meet anisotropic wetting: from preparation methods to applications. Mater. Horiz. 7, 2566–2595 (2020).10.1039/D0MH00768D ↗
32. Shao, G., Hanaor, D. A., Shen, X. & Gurlo, A. Freeze casting: from low‐dimensional building blocks to aligned porous structures—a review of novel materials, methods, and applications. Adv. Mater. 32, 1907176 (2020).10.1002/adma.201907176 ↗
33. Dai, C., Zhang, C., Huang, W., Chang, K. & Lee, L. Thermoplastic polyurethane microcellular fibers via supercritical carbon dioxide based extrusion foaming. Poly. Eng. Sci. 53, 2360–2369 (2013).10.1002/pen.23495 ↗
34. Li, M. et al. Microextrusion foaming of polyetheretherketone fiber: mechanical and thermal insulation properties. Adv. Eng. Mater. 24, 2101110 (2022).10.1002/adem.202101110 ↗
35. Zhang, F., Si, Y., Yu, J. & Ding, B. Electrospun porous engineered nanofiber materials: a versatile medium for energy and environmental applications. Chem. Eng. J. 456, 140989 (2023).10.1016/j.cej.2022.140989 ↗
36. Shahbazi, M. A., Ghalkhani, M. & Maleki, H. Directional freeze‐casting: a bioinspired method to assemble multifunctional aligned porous structures for advanced applications. Adv. Eng. Mater. 22, 2000033 (2020).10.1002/adem.202000033 ↗
37. Yang, X. & Berglund, L. A. Structural and ecofriendly holocellulose materials from wood: microscale fibers and nanoscale fibrils. Adv. Mater. 33, 2001118 (2021).10.1002/adma.202001118 ↗
38. Chen, W. Y., Shi, X. L., Zou, J. & Chen, Z. G. Wearable fiber-based thermoelectrics from materials to applications. Nano Energy 81, 105684 (2021).10.1016/j.nanoen.2020.105684 ↗
39. Liu, Z. et al. Functionalized fiber-based strain sensors: pathway to next-generation wearable electronics. Nanomicro Lett. 14, 61 (2022).
40. Xiong, J., Chen, J. & Lee, P. S. Functional fibers and fabrics for soft robotics, wearables, and human–robot interface. Adv. Mater. 33, 2002640 (2021).10.1002/adma.202002640 ↗
41. Xiao, R., Yu, G., Xu, B. B., Wang, N. & Liu, X. Fiber surface/interfacial engineering on wearable electronics. Small 17, 2102903 (2021).10.1002/smll.202102903 ↗
42. Lu, J. T. & Ilyas, E. An overview of ultraviolet-protective clothing. Cureus 14, 7 (2022).
43. Azad, S. S. et al. Stability enhancement of perovskite solar cells using multifunctional inorganic materials with UV protective, self-cleaning, and high wear resistance properties. Sci. Rep. 14, 6466 (2024).10.1038/s41598-024-57133-8 ↗
44. Zhai, H., Fan, D. & Li, Q. Dynamic radiation regulations for thermal comfort. Nano Energy 100, 107435 (2022).10.1016/j.nanoen.2022.107435 ↗
45. Dorodnyy, A., Smajic, J. & Leuthold, J. Mie scattering for photonic devices. Laser Photonics Rev. 17, 2300055 (2023).10.1002/lpor.202300055 ↗
46. Yu, X., Chan, J. & Chen, C. Review of radiative cooling materials: performance evaluation and design approaches. Nano Energy 88, 106259 (2021).10.1016/j.nanoen.2021.106259 ↗
47. Li, N. W., Ho, C. P., Yick, K. L. & Zhou, J. Y. Influence of inlaid material, yarn and knitted structure on the net buoyant force and mechanical properties of inlaid knitted fabric for buoyant swimwear. Text. Res. J. 91, 1452–1466 (2021).10.1177/0040517520981742 ↗
48. Cavazzini, G. Archimedes’ principle and the concept of gravitation. Appl. Phys. Rev. 11, 9 (2019).