journal article·2022-12Open access

Individually addressable and flexible pressure sensor matrixes with ZnO nanotube arrays on graphene

Junbeom Park, Ramesh Ghosh, Minho S. Song, Yunjae Hwang, Youngbin Tchoe, Rajendra Kumar Saroj, Asad Ali, Puspendu Guha, Bosung Kim, Sang-Woo Kim, Miyoung Kim, Gyu-Chul Yi

NPG Asia Materials· Volume 14· Issue 1

Abstract

Abstract We report the fabrication of individually addressable, high-density, vertical zinc oxide (ZnO) nanotube pressure sensor arrays. High-sensitivity and flexible piezoelectric sensors were fabricated using dimension- and position-controlled, vertical, and free-standing ZnO nanotubes on a graphene substrate. Significant pressure/force responses were achieved from small devices composed of only single, 3 × 3, 5 × 5, and 250 × 250 ZnO nanotube arrays on graphene. An individually addressable pixel matrix was fabricated by arranging the top and bottom electrodes of the sensors in a crossbar configuration. We investigated the uniformity and robustness of pressure/force spatial mapping by considering the pixel size, the number of ZnO nanotubes in each pixel, and the lateral dimensions of individual ZnO nanotubes. A spatial resolution as high as 1058 dpi was achieved for a Schottky diode-based force/pressure sensor composed of ZnO nanotubes on a flexible substrate. Additionally, we confirmed the excellent flexibility and electrical robustness of the free-standing sensor arrays for high-resolution tactile imaging. We believe that this work opens important opportunities for 1D piezoelectric pressure/force sensor arrays with enormous applications in human-electronics interfaces, smart skin, and micro- and nanoelectromechanical systems.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Advanced Sensor and Energy Harvesting Materials · Tactile and Sensory Interactions · Conducting polymers and applications

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (37)

Show source-provided references
1. Wang, Z. L. Progress in piezotronics and piezo-phototronics. Adv. Mater. 24, 4632–4646 (2012).10.1002/adma.201104365 ↗
2. Bao, R. et al. Flexible and controllable piezo-phototronic pressure mapping sensor matrix by ZnO NW/p-polymer LED array. Adv. Funct. Mater. 25, 2884–2891 (2015).10.1002/adfm.201500801 ↗
3. Choi, M. Y. et al. Mechanically powered transparent flexible charge-generating nanodevices with piezoelectric ZnO nanorods. Adv. Mater. 21, 2185 (2009).10.1002/adma.200803605 ↗
4. Lee, K. Y., Gupta, M. K. & Kim, S. W. Transparent flexible stretchable piezoelectric and triboelectric nanogenerators for powering portable electronics. Nano Energy 14, 139–160 (2015).10.1016/j.nanoen.2014.11.009 ↗
5. Oh, H. & Dayeh, S. A. Physics-based device models and progress review for active piezoelectric semiconductor devices. Sensors 20, 3872–3909 (2020).10.3390/s20143872 ↗
6. Ha, M. et al. Bioinspired interlocked and hierarchical design of ZnO nanowire arrays for static and dynamic pressure-sensitive electronic skins. Adv. Funct. Mater. 25, 2841–2849 (2015).10.1002/adfm.201500453 ↗
7. Wang, Z. L. & Song, J. Piezoelectric nanogenerators based on zinc oxide nanowire arrays. Science 312, 242–246 (2006).10.1126/science.1124005 ↗
8. Hu, W. G., Zhang, C. & Wang, Z. L. Recent progress in piezotronics and tribotronics. Nanotechnology 30, 042001–042019 (2019).10.1088/1361-6528/aaeddd ↗
9. Ghosh, R. et al. Fabrication of piezoresistive Si nanorod-based pressure sensor arrays: A promising candidate for portable breath monitoring devices. Nano Energy 80, 105537 (2021).10.1016/j.nanoen.2020.105537 ↗
10. Peng, Y. et al. Achieving high-resolution pressure mapping via flexible GaN/ ZnO nanowire LEDs array by piezo-phototronic effect. Nano Energy 58, 633–640 (2019).10.1016/j.nanoen.2019.01.076 ↗
11. Han, X., Du, W., Yu, R., Pan, C. & Wang, Z. L. Piezo-phototronic enhanced UV sensing based on a nanowire photodetector array. Adv. Mater. 27, 7963–7969 (2015).10.1002/adma.201502579 ↗
12. Wu, W. Z., Wen, X. N. & Wang, Z. L. Taxel-addressable matrix of vertical-nanowire piezotronic transistors for active and adaptive tactile imaging. Science 340, 952–957 (2013).10.1126/science.1234855 ↗
13. Pyo, S., Lee, J., Bae, K., Sim, S. & Kim, J. Recent progress in flexible tactile sensors for human-interactive systems: from sensors to advanced applications. Adv. Mater. 33, 2005902 (2021).10.1002/adma.202005902 ↗
14. Wan, Y., Wang, Y. & Guo, C. F. Recent progresses on flexible tactile sensors. Mater. Today Phys. 1, 61–73 (2017).10.1016/j.mtphys.2017.06.002 ↗
15. Liu, S. et al. Ultrasensitive 2D ZnO piezotronic transistor array for high resolution tactile imaging. Adv. Mater. 29, 1606346 (2017).10.1002/adma.201606346 ↗
16. Song, M. et al. Flexible Li-doped ZnO piezotronic transistor array for in-plane strain mapping. Nano Energy 55, 341–347 (2019).10.1016/j.nanoen.2018.11.013 ↗
17. Chen, W. F. & Yan, X. Progress in achieving high-performance piezoresistive and capacitive flexible pressure sensors: a review. J. Mater. Sci. Technol. 43, 175–188 (2020).10.1016/j.jmst.2019.11.010 ↗
18. Oh, H., Yi, G.-C., Yip, M. & Dayeh, S. A. Scalable tactile sensor arrays on flexible substrates with high spatiotemporal resolution enabling slip and grip for closed-loop robotics. Sci. Adv. 6, eabd7795 (2020).10.1126/sciadv.abd7795 ↗
19. Gong, S. et al. A wearable and highly sensitive pressure sensor with ultrathin gold nanowires. Nat. Commun. 5, 3132 (2014).10.1038/ncomms4132 ↗
20. Lee, J. H. et al. A behavior-learned cross-reactive sensor matrix for intelligent skin perception. Adv. Mater. 32, 2000969 (2020).10.1002/adma.202000969 ↗
21. Zhong, W. et al. Ultrasensitive wearable pressure sensors assembled by surface-patterned polyolefin elastomer nanofiber membrane interpenetrated with silver nanowires. ACS Appl. Mater. Interfaces 10, 42706–42714 (2018).10.1021/acsami.8b12363 ↗
22. Tee, B. C.-K. et al. Tunable flexible pressure sensors using microstructured elastomer geometries for intuitive electronics. Adv. Funct. Mater. 24, 5427–5434 (2014).10.1002/adfm.201400712 ↗
23. Jiang, X.-Z., Sun, Y.-J., Fan, Z. & Zhang, T.-Y. Integrated flexible, waterproof, transparent, and self-powered tactile sensing panel. ACS Nano 10, 7696–7704 (2016).10.1021/acsnano.6b03042 ↗
24. Yang, J. C. et al. Microstructured porous pyramid-based ultrahigh sensitive pressure sensor insensitive to strain and temperature. ACS Appl. Mater. Interfaces 11, 19472–19480 (2019).10.1021/acsami.9b03261 ↗
25. Tao, J. et al. Self-powered tactile sensor array systems based on the triboelectric effect. Adv. Funct. Mater. 29, 1806379 (2019).10.1002/adfm.201806379 ↗
26. Pan, C. et al. High-resolution electroluminescent imaging of pressure distribution using a piezoelectric nanowire LED array. Nat. Photonics 7, 752–758 (2013).10.1038/nphoton.2013.191 ↗
27. Li, X. et al. Enhancing light emission of ZnO-nanofilm/Si-micropillar heterostructure arrays by piezo-phototronic effect. Adv. Mater. 27, 4447–4453 (2015).10.1002/adma.201501121 ↗
28. Li, X. et al. Flexible light emission diode arrays made of transferred Si microwires-ZnO nanofilm with piezo-phototronic effect enhanced lighting. ACS Nano 11, 3883–3889 (2017).10.1021/acsnano.7b00272 ↗
29. Tchoe, Y. et al. Individually addressable, high-density vertical nanotube Schottky diode crossbar array. Nano Energy 76, 104955 (2020).10.1016/j.nanoen.2020.104955 ↗
30. Lee, C.-H. et al. Flexible inorganic nanostructure light-emitting diodes fabricated on graphene films. Adv. Mater. 23, 4614–4619 (2011).10.1002/adma.201102407 ↗
31. Oh, H. et al. Vertical ZnO nanotube transistor on a graphene film for flexible inorganic electronics. Small 14, 1800240 (2018).10.1002/smll.201800240 ↗
32. Park, J. B. et al. Highly sensitive and flexible pressure sensors using position- and dimension-controlled ZnO nanotube arrays grown on graphene films. Npg Asia Mater. 13, 57 (2021).10.1038/s41427-021-00324-w ↗
33. Papageorgiou, D. G., Kinloch, I. A. & Young, R. J. Mechanical properties of graphene and graphene-based nanocomposites. Prog. Mater. Sci. 90, 75–127 (2017).10.1016/j.pmatsci.2017.07.004 ↗
34. Nela, L., Tang, J., Cao, Q., Tulevski, G. & Han, S.-J. Large-area high-performance flexible pressure sensor with carbon nanotube active matrix for electronic skin. Nano Lett. 18, 2054–−2059 (2018).10.1021/acs.nanolett.8b00063 ↗
35. Kim, Y.-J. et al. Position- and morphology-controlled ZnO nanostructures grown on graphene layers. Adv. Mater. 24, 5565–5569 (2012).10.1002/adma.201201966 ↗
36. Smit, G. D. J., Rogge, S. & Klapwijk, T. M. Scaling of nano-Schottky-diodes. Appl. Phys. Lett. 81, 3852–3854 (2002).10.1063/1.1521251 ↗
37. Vishniakou, S. et al. Tactile feedback display with spatial and temporal resolutions. Sci. Rep. 3, 2521 (2013).10.1038/srep02521 ↗