journal article·2019-12Open access

Three-dimensional ordered porous electrode materials for electrochemical energy storage

Zaichun Liu, Xinhai Yuan, Shuaishuai Zhang, Jing Wang, Qinghong Huang, Nengfei Yu, Yusong Zhu, Lijun Fu, Faxing Wang, Yuhui Chen, Yuping Wu

NPG Asia Materials· Volume 11· Issue 1

Abstract

Abstract The past decade has witnessed substantial advances in the synthesis of various electrode materials with three-dimensional (3D) ordered macroporous or mesoporous structures (the so-called “inverse opals”) for applications in electrochemical energy storage devices. This review summarizes recent advancements in 3D ordered porous (3DOP) electrode materials and their unusual electrochemical properties endowed by their intrinsic and geometric structures. The 3DOP electrode materials discussed here mainly include carbon materials, transition metal oxides (such as TiO2, SnO2, Co3O4, NiO, Fe2O3, V2O5, Cu2O, MnO2, and GeO2), transition metal dichalcogenides (such as MoS2 and WS2), elementary substances (such as Si, Ge, and Au), intercalation compounds (such as Li4Ti5O12, LiCoO2, LiMn2O4, LiFePO4), and conductive polymers (polypyrrole and polyaniline). Representative applications of these materials in Li ion batteries, aqueous rechargeable lithium batteries, Li-S batteries, Li-O2 batteries, and supercapacitors are presented. Particular focus is placed on how ordered porous structures influence the electrochemical performance of electrode materials. Additionally, we discuss research opportunities as well as the current challenges to facilitate further contributions to this emerging research frontier.
Source: crossref · Quality: baseline

Research context

OpenAlex topics: Supercapacitor Materials and Fabrication · Conducting polymers and applications · Transition Metal Oxide Nanomaterials

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

References (100+)

Show source-provided references
1. Li, W., Liu, J. & Zhao, D. Mesoporous materials for energy conversion and storage devices. Nat. Rev. Mater. 1, 16023 (2016).10.1038/natrevmats.2016.23 ↗
2. Wang, F. et al. Latest advances in supercapacitors: from new electrode materials to novel device designs. Chem. Soc. Rev. 46, 6816–6854 (2017).10.1039/C7CS00205J ↗
3. Sun, H. et al. Three-dimensional holey-graphene/niobia composite architectures for ultrahigh-rate energy storage. Science 356, 599–604 (2017).10.1126/science.aam5852 ↗
4. Wang, C. et al. A selectively permeable membrane for enhancing cyclability of organic sodium-ion batteries. Adv. Mater. 28, 9182–9187 (2016).10.1002/adma.201603240 ↗
5. Liu, J. et al. Mechanically and chemically robust sandwich-structured C@Si@C nanotube array Li-ion battery anodes. ACS Nano 9, 1985–1994 (2015).10.1021/nn507003z ↗
6. Wang, F. et al. Nanostructured positive electrode materials for post-lithium ion batteries. Energy Environ. Sci. 9, 3570–3611 (2016).10.1039/C6EE02070D ↗
7. Chodankar, N. R., Dubal, D. P., Kwon, Y. & Kim, D. H. Direct growth of FeCo2O4 nanowire arrays on flexible stainless steel mesh for high-performance asymmetric supercapacitor. NPG Asia Mater. 9, e419 (2017).10.1038/am.2017.145 ↗
8. Wang, F. et al. Electrode materials with tailored facets for electrochemical energy storage. Nanoscale Horiz. 1, 272–289 (2016).10.1039/C5NH00116A ↗
9. Bruce, P. G., Freunberger, S. A., Hardwick, L. J. & Tarascon, J. M. Li-O2 and Li-S batteries with high energy storage. Nat. Mater. 11, 19–29 (2012).10.1038/nmat3191 ↗
10. Pang, Q., Liang, X., Kwok, C. Y. & Nazar, L. F. Advances in lithium–sulfur batteries based on multifunctional cathodes and electrolytes. Nat. Energy 1, 16132 (2016).10.1038/nenergy.2016.132 ↗
11. Choi, J. W. & Aurbach, D. Promise and reality of post-lithium-ion batteries with high energy densities. Nat. Rev. Mater. 1, 16013 (2016).10.1038/natrevmats.2016.13 ↗
12. Sun, Y., Liu, N. & Cui, Y. Promises and challenges of nanomaterials for lithium-based rechargeable batteries. Nat. Energy 1, 16071 (2016).10.1038/nenergy.2016.71 ↗
13. Wei, Q. et al. Porous one-dimensional nanomaterials: design, fabrication and applications in electrochemical energy storage. Adv. Mater. https://doi.org/10.1002/adma.201602300. (2017)10.1002/adma.201602300. ↗
14. Tan, C. et al. Recent advances in ultrathin two-dimensional nanomaterials. Chem. Rev. 117, 6225–6331 (2017).10.1021/acs.chemrev.6b00558 ↗
15. Peng, L., Fang, Z., Zhu, Y., Yan, C. & Yu, G. Holey 2D nanomaterials for electrochemical energy storage. Adv. Energy Mater. https://doi.org/10.1002/aenm.201702179 (2017).10.1002/aenm.201702179 ↗
16. Zhang, J. & Li, C. M. Nanoporous metals: fabrication strategies and advanced electrochemical applications in catalysis, sensing and energy systems. Chem. Soc. Rev. 41, 7016–7031 (2012).10.1039/c2cs35210a ↗
17. Wei, J. et al. New Insight into the synthesis of large-pore ordered mesoporous materials. J. Am. Chem. Soc. 139, 1706–1713 (2017).10.1021/jacs.6b11411 ↗
18. Liu, S. et al. Dual-template synthesis of 2D mesoporous polypyrrole nanosheets with controlled pore size. Adv. Mater. 28, 8365–8370 (2016).10.1002/adma.201603036 ↗
19. Liu, S. et al. Soft‐template construction of 3D macroporous polypyrrole scaffolds. Small 13, 1604099 (2017).10.1002/smll.201604099 ↗
20. Lei, Y., Yang, S., Wu, M. & Wilde, G. Surface patterning using templates: concept, properties and device applications. Chem. Soc. Rev. 40, 1247–1258 (2011).10.1039/B924854B ↗
21. Stein, A., Wilson, B. E. & Rudisill, S. G. Design and functionality of colloidal-crystal-templated materials–chemical applications of inverse opals. Chem. Soc. Rev. 42, 2763–2803 (2013).10.1039/C2CS35317B ↗
22. Zhao, H., Zhou, M., Wen, L. & Lei, Y. Template-directed construction of nanostructure arrays for highly-efficient energy storage and conversion. Nano Energy 13, 790–813 (2015).10.1016/j.nanoen.2015.02.024 ↗
23. Zhao, H., Liu, L., Vellacheri, R. & Lei, Y. Recent advances in designing and fabricating self-supported nanoelectrodes for supercapacitors. Adv. Sci. 4, 1700188 (2017).10.1002/advs.201700188 ↗
24. Stein, A., Wilson, B. E. & Rudisill, S. G. Design and functionality of colloidal-crystal-templated materials-chemical applications of inverse opals. Chem. Soc. Rev. 42, 2763–2803 (2013).10.1039/C2CS35317B ↗
25. Zhao, Y., Liu, B., Pan, L. & Yu, G. 3D nanostructured conductive polymer hydrogels for high-performance electrochemical devices. Energy Environ. Sci. 6, 2856–2870 (2013).10.1039/c3ee40997j ↗
26. Xu, J. et al. G. Three-dimensional structural engineering for energy‐storage devices: from microscope to macroscope. ChemElectroChem 1, 975–1002 (2014).10.1002/celc.201400001 ↗
27. Rolison, D. R. & Dunn, B. Electrically conductive oxide aerogels: new materials in electrochemistry. J. Mater. Chem. 11, 963–980 (2001).10.1039/b007591o ↗
28. Long, J. W., Dunn, B., Rolison, D. R. & White, H. S. Three-dimensional battery architectures. Chem. Rev. 104, 4463–4492 (2004).10.1021/cr020740l ↗
29. Long, J. W. & Rolison, D. R. Architectural design, interior decoration, and three-dimensional plumbing en route to multifunctional nanoarchitectures. Acc. Chem. Res. 40, 854–862 (2007).10.1021/ar6000445 ↗
30. Wu, F., Bai, J., Feng, J. & Xiong, S. Porous mixed metal oxides: design, formation mechanism, and application in lithium-ion batteries. Nanoscale 7, 17211–17230 (2015).10.1039/C5NR04791A ↗
31. Fu, L. J. et al. Synthesis and electrochemical performance of novel core/shell structured nanocomposites. Electrochem. Commun. 8, 1–4 (2006).10.1016/j.elecom.2005.10.006 ↗
32. Wang, C. et al. Hollow TiO2–x porous microspheres composed of well-crystalline nanocrystals for high-performance lithium-ion batteries. Nano Res. 9, 165–173 (2016).10.1007/s12274-015-0976-7 ↗
33. Wang, F. et al. A quasi-solid-state Li-ion capacitor based on porous TiO2 hollow microspheres wrapped with graphene nanosheets. Small 12, 6207–6213 (2016).10.1002/smll.201602331 ↗
34. Fu, L., Zhang, T., Cao, Q., Zhang, H. P. & Wu, Y. P. Preparation and characterization of three-dimensionally ordered mesoporous titania microparticles as anode material for lithium ion battery. Electrochem. Commun. 9, 2140–2144 (2007).10.1016/j.elecom.2007.06.009 ↗
35. Lui, G. et al. Flexible, three-dimensional ordered macroporous TiO2 electrode with enhanced electrode–electrolyte interaction in high-power Li-ion batteries. Nano Energy 24, 72–77 (2016).10.1016/j.nanoen.2016.03.019 ↗
36. McNulty, D., Carroll, E. & O’Dwyer, C. Rutile TiO2 inverse opal anodes for Li-ion batteries with long cycle life, high-rate capability, and high structural stability. Adv. Energy Mater. https://doi.org/10.1002/aenm.201602291 (2017).10.1002/aenm.201602291 ↗
37. Petkovich, N. D., Rudisill, S. G., Wilson, B. E., Mukherjee, A. & Stein, A. Control of TiO2 grain size and positioning in three-dimensionally ordered macroporous TiO2/C composite anodes for lithium ion batteries. Inorg. Chem. 53, 1100–1112 (2014).10.1021/ic402648f ↗
38. Song, L. et al. A facile synthesis of a uniform constitution of three-dimensionally ordered macroporous TiO2–carbon nanocomposites with hierarchical pores for lithium ion batteries. J. Mater. Chem. A 3, 6862–6872 (2015).10.1039/C4TA06985D ↗
39. Wang, X. et al. Synthesis and lithium storage properties of Co3O4 nanosheet-assembled multishelled hollow spheres. Adv. Funct. Mater. 20, 1680–1686 (2010).10.1002/adfm.200902295 ↗
40. Peng, C. et al. Facile ultrasonic synthesis of CoO quantum dot/graphene nanosheet composites with high lithium storage capacity. ACS Nano 6, 1074–1081 (2012).10.1021/nn202888d ↗
41. Wang, J. et al. Accurate control of multishelled Co3O4 hollow microspheres as high‐performance anode materials in lithium-ion batteries. Angew. Chem. Int. Ed. 52, 6417–6420 (2013).10.1002/anie.201301622 ↗
42. Huang, X. et al. Carbon inverse opal entrapped with electrode active nanoparticles as high-performance anode for lithium-ion batteries. Sci. Rep. 3, 2317–2325 (2013).10.1038/srep02317 ↗
43. Liu, J. et al. Hydrothermal fabrication of three-dimensional secondary battery anodes. Adv. Mater. 26, 7096–7101 (2014).10.1002/adma.201402552 ↗
44. Liu, J. et al. Three-dimensionally scaffolded Co3O4 nanosheet anodes with high rate performance. J. Power Sources 299, 40–48 (2015).10.1016/j.jpowsour.2015.08.078 ↗
45. Reddy, M. V., Pecquenard, B., Vinatier, P. & Levasseur, A. Cyclic voltammetry and galvanostatic cycling characteristics of LiNiVO4 thin films during lithium insertion and re/de-insertion. Electrochem. Commun. 9, 409–415 (2007).10.1016/j.elecom.2006.10.011 ↗
46. Liu, Z., Mi, J., Yang, Y., Li, J. & Tan, X. Synthesis, characterization and electrochemical properties of three-dimensionally ordered macroporous α-Fe2O3. Mater. Sci. Eng. B 177, 1612–1617 (2012).10.1016/j.mseb.2012.08.013 ↗
47. Liu, H. et al. Electrochemical performance of α-Fe2O3 nanorods as anode material for lithium-ion cells. Electrochim. Acta 54, 1733–1736 (2009).10.1016/j.electacta.2008.09.071 ↗
48. Reddy, M. V. et al. α-Fe2O3 nanoflakes as an anode material for Li-ion batteries. Adv. Funct. Mater. 17, 2792–2799 (2007).10.1002/adfm.200601186 ↗
49. Wang, J., Zhou, H., Nanda, J. & Braun, P. V. Three-dimensionally mesostructured Fe2O3 electrodes with good rate performance and reduced voltage hysteresis. Chem. Mater. 27, 2803–2811 (2015).10.1021/cm504365s ↗
50. Wang, Z., Luan, D., Madhavi, S., Hu, Y. & Lou, X. W. D. Assembling carbon-coated α-Fe2O3 hollow nanohorns on the CNT backbone for superior lithium storage capability. Energy Environ. Sci. 5, 5252–5256 (2012).10.1039/C1EE02831F ↗
51. Liu, J. et al. High full-electrode basis capacity template-free 3D nanocomposite secondary battery anodes. Small 11, 6265–6271 (2015).10.1002/smll.201502538 ↗
52. Tang, Y. et al. An internal magnetic field strategy to reuse pulverized active materials for high performance: a magnetic three-dimensional ordered macroporous TiO2/CoPt/α-Fe2O3 nanocomposite anode. Chem. Commun. 53, 5298–5301 (2017).10.1039/C7CC00940B ↗
53. Zhao, N. et al. Preparation of nanowire arrays of amorphous carbon nanotube-coated single crystal SnO2. Chem. Mater. 20, 2612–2614 (2008).10.1021/cm703353y ↗
54. Zhao, N. H. et al. Polycrystalline SnO2 nanowires coated with amorphous carbon nanotube as anode material for lithium ion batteries. Mater. Lett. 64, 972–975 (2010).10.1016/j.matlet.2010.01.077 ↗
55. Huang, J. Y. et al. In-situ observation of the electrochemical lithiation of a single SnO2 nanowire electrode. Science 330, 1515–1520 (2010).10.1126/science.1195628 ↗
56. Lytle, J. C., Yan, H., Ergang, N. S., Smyrl, W. H. & Stein, A. Structural and electrochemical properties of three-dimensionally ordered macroporous tin (IV) oxide films. J. Mater. Chem. 14, 1616–1622 (2004).10.1039/b401890g ↗
57. Li, Z. et al. Three-dimensionally ordered macroporous SnO2 as anode materials for lithium ion batteries. Ceram. Int. 42, 18887–18893 (2016).10.1016/j.ceramint.2016.09.036 ↗
58. Liu, J. et al. High volumetric capacity three-dimensionally sphere-caged secondary battery anodes. Nano Lett. 16, 4501–4507 (2016).10.1021/acs.nanolett.6b01711 ↗
59. Yuan, Y., Amine, K., Lu, J. & Shahbazian-Yassar, R. Understanding materials challenges for rechargeable ion batteries with in situ transmission electron microscopy. Nat. Commun. 8, 15806 (2017).
60. Zhang, T. et al. Natural graphite coated by Si nanoparticles as anode materials for lithium ion batteries. J. Mater. Chem. 17, 1321–1325 (2007).10.1039/b612967f ↗
61. Zhang, T. et al. Core-shell Si/C nanocomposite as anode material for lithium ion batteries. Pure Appl. Chem. 78, 1889–1896 (2006).10.1351/pac200678101889 ↗
62. Zhang, T. et al. The structural evolution and lithiation behavior of vacuum-deposited Si film with high reversible capacity. Electrochim. Acta 53, 5660–5664 (2008).10.1016/j.electacta.2008.03.017 ↗
63. Park, M. H. et al. Silicon nanotube battery anodes. Nano Lett. 9, 3844–3847 (2009).10.1021/nl902058c ↗
64. Liu, H., Cho, H. M., Meng, Y. S. & Li, Q. Engineering three-dimensionally electrodeposited Si-on-Ni inverse opal structure for high volumetric capacity Li-ion microbattery anode. ACS Appl. Mater. Interfaces 6, 9842–9849 (2014).10.1021/am502277f ↗
65. Kim, D. Y. et al. An electrochemically grown three-dimensional porous Si@Ni inverse opal structure for high-performance Li ion battery anodes. J. Mater. Chem. A 2, 6396–6401 (2014).10.1039/C4TA00147H ↗
66. Jin, Y., Munakata, H., Okada, N. & Kanamura, K. Design and evaluation of a three dimensionally ordered macroporous structure within a highly patterned cylindrical Sn-Ni electrode for advanced lithium ion batteries. J. Nanomater. https://doi.org/10.1155/2013/937019 (2013).10.1155/2013/937019 ↗
67. Cho, H. H., Glazer, M. P., Xu, Q., Han, H. N. & Dunand, D. C. Numerical and experimental investigation of (de) lithiation-induced strains in bicontinuous silicon-coated nickel inverse opal anodes. Acta Mater. 107, 289–297 (2016).10.1016/j.actamat.2016.01.064 ↗
68. Glazer, M. P. et al. In operando strain measurement of bicontinuous silicon-coated nickel inverse opal anodes for Li-ion batteries. Adv. Energy Mater. 5, 1500466 (2015).10.1002/aenm.201500466 ↗
69. Wang, Z. L., Xu, D., Wang, H. G., Wu, Z. & Zhang, X. B. In-situ fabrication of porous graphene electrodes for high-performance energy storage. ACS Nano 7, 2422–2430 (2013).10.1021/nn3057388 ↗
70. Lou, S. et al. Superior performance of ordered macroporous TiNb2O7 anodes for lithium ion batteries: Understanding from the structural and pseudocapacitive insights on achieving high rate capability. Nano Energy 34, 15–25 (2017).10.1016/j.nanoen.2017.01.058 ↗
71. Deng, Z. et al. 3D ordered macroporous MoS2@C nanostructure for flexible Li-ion batteries. Adv. Mater. https://doi.org/10.1002/adma.201603020 (2017).10.1002/adma.201603020 ↗
72. Liu, X., Zhao, J., Hao, J., Su, B. L. & Li, Y. 3D ordered macroporous germanium fabricated by electrodeposition from an ionic liquid and its lithium storage properties. J. Mater. Chem. A 1, 15076–15081 (2013).10.1039/c3ta12923c ↗
73. Song, T. et al. A Ge inverse opal with porous walls as an anode for lithium ion batteries. Energy Environ. Sci. 5, 9028–9033 (2012).10.1039/c2ee22358a ↗
74. McNulty, D., Geaney, H., Buckley, D. & O’Dwyer, C. High capacity binder-free nanocrystalline GeO2 inverse opal anodes for Li-ion batteries with long cycle life and stable cell voltage. Nano Energy 43, 11–21 (2018).10.1016/j.nanoen.2017.11.007 ↗
75. Wang, J. et al. Graphene microsheets from natural microcrystalline graphite minerals: scalable synthesis and unusual energy storage. J. Mater. Chem. A 3, 3144–3150 (2015).10.1039/C4TA06332E ↗
76. Augustyn, V. et al. High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat. Mater. 12, 518–522 (2013).10.1038/nmat3601 ↗
77. Brezesinski, T., Wang, J., Tolbert, S. H. & Dunn, B. Ordered mesoporous ɑ-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors. Nat. Mater. 9, 146–151 (2010).10.1038/nmat2612 ↗
78. Kim, H. S. et al. Oxygen vacancies enhance pseudocapacitive charge storage properties of MoO3-x. Nat. Mater. 16, 454–460 (2017).10.1038/nmat4810 ↗
79. Zhou, F., Xin, S., Liang, H. W., Song, L. T. & Yu, S. H. Carbon nanofibers decorated with molybdenum disulfide nanosheets: synergistic lithium storage and enhanced electrochemical performance. Angew. Chem. Int. Ed. 53, 11552–11556 (2014).10.1002/anie.201407103 ↗
80. Yu, X. Y., Hu, H., Wang, Y., Chen, H. & Lou, X. W. Ultrathin MoS2 nanosheets supported on N-doped carbon nanoboxes with enhanced lithium storage and electrocatalytic properties. Angew. Chem. Int. Ed. 54, 7395–7398 (2015).10.1002/anie.201502117 ↗
81. Pratt, B. & Friedman, F. Diffusion of lithium into Ge and Si. J. Appl. Phys. 37, 1893 (1966).10.1063/1.1708620 ↗
82. Wang, X., Qu, Q., Hou, Y., Wang, F. & Wu, Y. An aqueous rechargeable lithium battery of high energy density based on coated Li metal and LiCoO2. Chem. Commun. 49, 6179–6181 (2013).10.1039/c3cc42676a ↗
83. Fu, L. J. et al. Q. Electrode materials for lithium secondary batteries prepared by sol–gel methods. Prog. Mater. Sci. 50, 881–928 (2005).10.1016/j.pmatsci.2005.04.002 ↗
84. Cao, Q. et al. A novel carbon-coated LiCoO2 as cathode material for lithium ion battery. Electrochem. Commun. 9, 1228–1232 (2007).10.1016/j.elecom.2007.01.017 ↗
85. Shi, Y. et al. Graphene wrapped LiFePO4/C composites as cathode materials for Li-ion batteries with enhanced rate capability. J. Mater. Chem. 22, 16465–16470 (2012).10.1039/c2jm32649c ↗
86. Xiao, S., Wang, F., Yang, Y., Chang, Z. & Wu, Y. An environmentally friendly and economic membrane based on cellulose as a gel polymer electrolyte for lithium ion batteries. RSC Adv. 4, 76–81 (2014).10.1039/C3RA46115G ↗
87. Liu, H. et al. Kinetic study on LiFePO4/C nanocomposites synthesized by solid state technique. J. Power Sources 159, 717–720 (2006).10.1016/j.jpowsour.2005.10.098 ↗
88. Ergang, N. S., Lytle, J. C., Yan, H. & Stein, A. Effect of a macropore structure on cycling rates of LiCoO2. J. Electrochem. Soc. 152, A1989–A1995 (2005).10.1149/1.2013212 ↗
89. Peng, J. et al. Synthesis and electrochemical performance of three-dimensionally ordered macroporous LiCoO2. J. Solid State Electrochem. 16, 3079–3085 (2012).10.1007/s10008-012-1752-1 ↗
90. Vu, A. & Stein, A. Multiconstituent synthesis of LiFePO4/C composites with hierarchical porosity as cathode materials for lithium ion batteries. Chem. Mater. 23, 3237–3245 (2011).10.1021/cm201197j ↗
91. Doherty, C. M., Caruso, R. A., Smarsly, B. M. & Drummond, C. J. Colloidal crystal templating to produce hierarchically porous LiFePO4 electrode materials for high power lithium ion batteries. Chem. Mater. 21, 2895–2903 (2009).10.1021/cm900698p ↗
92. Kong, F. et al. Ab initio study of doping effects on LiMnO2 and Li2MnO3 cathode materials for Li-ion batteries. J. Mater. Chem. A 3, 8489–8500 (2015).10.1039/C5TA01445J ↗
93. Ji, H., Miao, X., Wang, L., Qian, B. & Yang, G. Effects of microwave-hydrothermal conditions on the purity and electrochemical performance of orthorhombic LiMnO2. ACS Sustain. Chem. Eng. 2, 359–366 (2014).10.1021/sc400439k ↗
94. Guo, J., Cai, Y., Zhang, S., Chen, S. & Zhang, F. Core–shell structured o-LiMnO2@ Li2CO3 nanosheet array cathode for high-performance, wide-temperature-tolerance lithium-ion batteries. ACS Appl. Mater. Interfaces 8, 16116–16124 (2016).10.1021/acsami.6b04616 ↗
95. Zhang, H., Yu, X. & Braun, P. V. Three-dimensional bicontinuous ultrafast-charge and-discharge bulk battery electrodes. Nat. Nanotech. 6, 277–281 (2011).10.1038/nnano.2011.38 ↗
96. Pikul, J. H., Zhang, H. G., Cho, J., Braun, P. V. & King, W. P. High-power lithium ion microbatteries from interdigitated three-dimensional bicontinuous nanoporous electrodes. Nat. Commun. 4, 1732–1736 (2013).10.1038/ncomms2747 ↗
97. Ning, H. et al. Holographic patterning of high-performance on-chip 3D lithium-ion microbatteries. Proc. Natl Acad. Sci. USA 112, 6573–6578 (2015).10.1073/pnas.1423889112 ↗
98. Wang, F. et al. Dual-graphene rechargeable sodium battery. Small 13, 1702449 (2017).10.1002/smll.201702449 ↗
99. Yang, J. et al. Tuning structural stability and lithium-storage properties by d-orbital hybridization substitution in full tetrahedron Li2FeSiO4 nanocrystal. Nano Energy 20, 117–125 (2016).10.1016/j.nanoen.2015.12.004 ↗
100. Chakrabarti, S., Thakur, A. K. & Biswas, K. Effect of Ti modification on structural, electronic and electrochemical properties of Li2FeSiO4-A DFT study using FPLAPW approach. Electrochim. Acta 236, 288–296 (2017).10.1016/j.electacta.2017.03.185 ↗