journal article·2019-03-26

Effect of wood flour and naphthenic oil on morphology, rheological and mechanical properties of EPDM/PP/AL composite

Rui Gou, Minghui Guo

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Abstract

Abstract Thermoplastic elastomer (TPE), made from ethylene propylene diene monomer (EPDM) and polypropylene (PP) base on reactive blending, has an excellent processing performance and characteristics and a wide range of applications. In this paper, EPDM, PP and ammonium lignosulfonate (AL) were selected as raw materials, wood flour (WF) of poplar tree was used as filler, naphthenic oil was used as plasticizer, DCP vulcanization system with dynamic vulcanization was carried, to make a new kind of composite material. This research studied the influences of wood flour and naphthenic oil content on the microstructure, mechanical properties and rheological properties of the composite material. The result showed: the content of wood flour and naphthenic oil has big impact on composite material. With the increase of the wood flour content, the mechanical properties are increased firstly and then decreased. The viscosity and modulus of the composite is improved with the increase of wood flour. With of the increase of the amount of naphthenic oil, the mechanical properties, viscosity and modulus of the composites decreased. When the content of wood flour is between 30–60 parts and the content of naphthenic oil is less than 20, the EPDM/PP/AL composite is suitable for using as the core layer elastic material of composite floor.
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Research context

OpenAlex topics: Natural Fiber Reinforced Composites · Polymer Nanocomposites and Properties · Polymer composites and self-healing

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Affiliations

Key Laboratory of Bio-based Material Science and Technology (Ministry of Education) , 47820 Northeast Forestry University , Harbin , China

College of Art , Qingdao University of Science & Technology , Qingdao , China

References (40)

Show source-provided references
1. Adhikary, K.B., Pang, S., Staiger, M.P. (2008) Long-term moisture absorption and thickness swelling behaviour of recycled thermoplastics reinforced with Pinus radiata sawdust. Chem. Eng. J. 142(2):190–198.10.1016/j.cej.2007.11.024 ↗
2. Ansari, A., Pawlik, M. (2007) Floatability of chalcopyrite and molybdenite in the presence of lignosulfonates. Part I. Adsorption studies. Miner. Eng. 20(6):600–608.10.1016/j.mineng.2006.12.007 ↗
3. Ares, A., Bouza, R., Pardo, S.G., Abad, M.J., Barral, L. (2010) Rheological, mechanical and thermal behaviour of wood polymer composites based on recycled polypropylene. J. Polym. Environ. 18(3):318–325.10.1007/s10924-010-0208-x ↗
4. Areskogh, D., Henriksson, G. (2011) Immobilisation of laccase for polymerisation of commercial lignosulphonates. Process Biochem. 46(5):1071–1075.10.1016/j.procbio.2011.01.024 ↗
5. Areskogh, D., Li, J.B., Gellerstedt, G. (2010) Investigation of the molecular weight increase of commercial lignosulfonates by laccase catalysis. Biomacromolecules 11(4):904–910.10.1021/bm901258v ↗
6. Belgacem, M.N., Blayo, A., Gandini, A. (2003) Organosolv lignin as a filler in inks, varnishes and paints. Ind. Crop. Prod. 18(2):145–153.10.1016/S0926-6690(03)00042-6 ↗
7. Carrino, L., Ciliberto, S., Giorleo, G., Prisco, U. (2011) Effect of filler content and temperature on steady-state shear flow of wood/high density polyethylene composites. Polym. Compos. 32(5):796–809.10.1002/pc.21101 ↗
8. Chandra, R., Gourlay, K., Kim, C.S., Sadder, J. (2015) Enhancing hemicellulose recovery and the enzymatic hydrolysis of cellulose by adding lignosulfonates during the two-stage steam pretreatment of poplar. Acs Sustain. Chem. Eng. 3(5):150413095829006.10.1021/acssuschemeng.5b00124 ↗
9. Cheng, S.Y., Shao, Y.T., Zhou, F., Yan, H.B. (2016) Effect factors of dynamic curing rate of ethylene-propylene-diene monomer/polypropylene systems and modulus of thermoplastic elastomer. China Synth. Rubber Ind.
10. Coran, A.Y., Patel, R.P. (1981) Rubber-thermoplastic compositions. Part III. Predicting elastic moduli of melt mixed rubber-plastic blends. Rubber Chem. Technol. 54(1):91–100.10.5254/1.3535800 ↗
11. Costa, H.M.D., Ramos, V.D., Rocha, M.C.G. (2006) Analysis of thermal properties and impact strength of PP/SRT, PP/EPDM and PP/SRT/EPDM mixtures in single screw extruder. Polym. Test. 25(4):498–503.10.1016/j.polymertesting.2006.02.003 ↗
12. Fan, J., Zhan, H. (2008) Optimization of synthesis of spherical lignosulphonate resin and its structure characterization. Chin. J. Chem. Eng. 16(3):407–410.10.1016/S1004-9541(08)60097-X ↗
13. Guo, H. (1999) Influence of formulation and blending method on the property of EPDM/PP. Spec. Purp. Rubber Prod.
14. Hao, T.H., Jiang, T., Qiu, L. (2005) Development of EPDM/PP TPV with low hardness and dynamic vulcanization. China Elastom. 15(4):10–13.
15. Ismail, H., Jaffri, R.M. (1999) Physico-mechanical properties of oil palm wood flour filled natural rubber composites. Polym. Test. 18(5):381–388.10.1016/S0142-9418(98)00031-2 ↗
16. Jiang, W., Tjong, S.C., Li, R.K.Y. (2000) Brittle–tough transition in PP/EPDM blends: effects of interparticle distance and tensile deformation speed. Polymer 41(9):3479–3482.10.1016/S0032-3861(99)00747-8 ↗
17. Jin, Y., Cheng, X., Zheng, Z. (2010) Preparation and characterization of phenol-formaldehyde adhesives modified with enzymatic hydrolysis lignin. Bioresour. Technol. 101(6):2046–2048.10.1016/j.biortech.2009.09.085 ↗
18. Khanjanzadeh, H., Tabarsa, T., Shakeri, A. (2012) Morphology, dimensional stability and mechanical properties of polypropylene-wood flour composites with and without nanoclay. J. Reinf. Plast. Compos. 31(5):341–350.10.1177/0731684412438793 ↗
19. Khazieva, E.B., Naboichenko, S.S., Bolatbaev, K.N. (2015) Influence of lignosulfonates on the cementation velocity of copper with zinc. Russ. J. Non-Ferr. Met. 56(2):142–145.10.3103/S1067821215020091 ↗
20. Lyckfeldt, O., Carlström, E., Davoust, P. (2006) Dispersion mechanisms in aqueous alumina suspensions at high solids loadings. Colloids Surf. A, Physicochem. Eng. Asp. 274(1):100–109.10.1016/j.colsurfa.2005.08.039 ↗
21. Mansouri, N.E.E., Salvadó, J. (2006) Structural characterization of technical lignins for the production of adhesives: Application to lignosulfonate, kraft, soda-anthraquinone, organosolv and ethanol process lignins. Ind. Crop. Prod. 24(1):8–16.10.1016/j.indcrop.2005.10.002 ↗
22. Mohan, D., Pittman, C.U.Jr., Steele, P.H. (2006) Single, binary and multi-component adsorption of copper and cadmium from aqueous solutions on Kraft lignin–a biosorbent. J. Colloid Interface Sci. 297(2):489–504.10.1016/j.jcis.2005.11.023 ↗
23. Mu, Y.X., Yang, F., Kang, H.L., Wang, N., Fang, Q.H. (2018) Effect of naphthenic oil on the properties of Eucommia ulmoides gum/natural rubber blend. Polym. Mater. Sci. Eng. 1:89–94.
24. Pilla, S., Gong, S., O’Neill, E., Rowell, R.M. (2008) Polylactide-pine wood flour composites. Polym. Eng. Sci. 48(3):578–587.10.1002/pen.20971 ↗
25. Poletto, M., Dettenborn, J., Zeni, M., Zattera, A.J. (2011) Characterization of composites based on expanded polystyrene wastes and wood flour. Waste Manag. 31(4):779–784.10.1016/j.wasman.2010.10.027 ↗
26. Prut, E.V., Erina, N., Karger-Kocsis, J., Medintseva, T.I. (2008) Effects of blend composition and dynamic vulcanization on the morphology and dynamic viscoelastic properties of PP/EPDM Blends. J. Appl. Polym. Sci. 109(2):1212–1220.10.1002/app.28158 ↗
27. Raj, R.G., Kokta, B.V., Daneault, C. (1990) Wood flour as a low-cost reinforcing filler for polyethylene: studies on mechanical properties. J. Mater. Sci. 25(3):1851–1855.10.1007/BF01045396 ↗
28. Setterfield, H.E., Sutton, T.S. (2005) The role of calcium ions and lignosulphonate plasticiser in the hydration of cement. Cem. Concr. Res. 35(4):631–636.10.1016/j.cemconres.2004.05.048 ↗
29. Silva, A.L.N.D., Coutinho, F.M.B. (1996) Some properties of polymer blends based on EPDM/PP. Polym. Test. 15(1):45–52.10.1016/0142-9418(95)00012-7 ↗
30. Smita, R., Upendranath, D. (2008) Manipulation of lignin in plants with special reference to O-methyltransferase. Plant Sci. 174(3):264–277.10.1016/j.plantsci.2007.11.014 ↗
31. Song, S.S., Yan, B.X., Xu, Y.H., Wang, Y.Q. (2015) The Research on water-absorbing natural rubber composites filled with wood flour. Guangdong Chem. Ind. 42(23):103–105.
32. Stewart, D. (2008) Lignin as a base material for materials applications: Chemistry, application and economics. Ind. Crop. Prod. 27(2):202–207.10.1016/j.indcrop.2007.07.008 ↗
33. Tian, H.C., Liu, Y.X., Feng, Y.X., Wu, S.M., Zhang, L.Q. (2003) Structure and properties of dynamically vulcanized IIR/PP thermoplastic elastomers. I. Effect of softening and filling system on structure and properties of IIR/PP TPV. China Synth. Rubber Ind. 26(4):216–220.
34. Vishtal, A., Kraslawski, A. (2011) Challenges in industrial applications of technical lignins. Bioresources 6(3):3547–3568.10.15376/biores.6.3.3547-3568 ↗
35. Wang, F. (2016) Study of white oil filled EPDM/PP thermoplastic vulcanizate. Guangdong Chem. Ind.
36. Wang, W., He, L., Wang, D.W., Ling, T.Q., Xiao, F.P. (2016) Research progress on low temperature performances of mixture from rubber and asphalt. Highway 1:181–187.
37. Wang, Y.L., Qi, R.R., Xiong, C., Huang, M. (2011) Effects of coupling agent and interfacial modifiers on mechanical properties of poly (lactic acid) and wood flour biocomposites. Iran. Polym. J. 20(4):281–294.
38. Yao, S.S., Jiang, D., Zheng, X., Jin, F.L., Lv, F.C. (2017) Study on preparation and properties of PLA/wood flour composites. Plast. Sci. Technol. 45(5):59–63.
39. Zaini, M.J., Fuad, M., Ismail, Z., Mansor, M.S. (2015) The effect of filler content and size on the mechanical properties of polypropylene/oil palm wood flour composites. Polym. Int. 40(1):51–55.10.1002/(SICI)1097-0126(199605)40:1<51::AID-PI514>3.0.CO;2-I ↗
40. Zhang, L.M., Yin, D.Y. (2002) Preparation of a new lignosulfonate-based thinner: introduction of ferrous ions. Colloids Surf. A, Physicochem. Eng. Asp. 210(1):13–21.10.1016/S0927-7757(02)00211-X ↗