journal article·2021-03-26

Effects of lignin content and acid concentration on the preparation of lignin containing nanofibers from alkaline hydrogen peroxide mechanical pulp

Lulu Zhu, Shiwen Xue, Hao Ren, Jin Zhao, Huamin Zhai, Fangong Kong

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Abstract

Abstract The poplar alkaline hydrogen peroxide mechanical pulp (APMP) with the lignin content of 24.63 % was used as raw material, which with lignin content of 10.04 %, 6.33 %, 3.82 %, and 1.14 % were obtained by the acid sodium chlorite method for 1–4 hours respectively. Then, different lignin content APMP were micro-nano processing treated with acidolysis (6.5 M, 9.8 M) or ultra-granular grinding respectively. Afterwards, poplar bleached chemical pulp (BCP) was prepared micro-nano cellulose under the same conditions as the APMP. Then, compared the data of the particle size, specific surface area, fiber morphology and zeta potential of suspensions between micro-nano cellulose products. The results show that the presence of a small amount of lignin (1–4 %) in APMP does not affect the preparation of different scales nano cellulose under different acid concentration conditions. When the lignin content is reduced to below 2 %, the acidolysis is more uniform, stable, and well-dispersed compared to BCP products; when the APMP is processed by the ultra-granular grinding, the higher lignin content, the more obvious cutting effect in the fiber length direction. The characteristics and feasibility of the preparation of micro-nano cellulose by the acidolysis and ultra-granular grinding using APMP with varying degrees of delignification are compared.
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Research context

OpenAlex topics: Advanced Cellulose Research Studies · Lignin and Wood Chemistry · Natural Fiber Reinforced Composites

SciVX discovery tags are terminology-based. OpenAlex topics are source-provided classifications.

Affiliations

State Key Laboratory of Biobased Material and Green Papermaking , Qilu University of Technology, Shandong Academy of Sciences , Jinan , China

Jiangsu Provincial Key Lab of Pulp and Paper Science and Technology , 74584 Nanjing Forestry University , Nanjing , China

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